Combustion Characteristics, Kinetics, and Thermodynamics of Pine Wood Through Thermogravimetric Analysis

Abstract

The thermal conversion of woody biomass is increasingly critical for the development of the energy processing technologies and fire safety engineering. The combustion characteristics, kinetics, and thermodynamics of pine wood were characterized through a thermogravimetric analyzer in the air atmosphere. There were two apparent peaks in the derivative TG curves for pine wood. The combustion process of pine wood was divided into two stages. Therein, the first stage occurring in the conversion degree range of 0–0.6 may be considered a one-step reaction. It was easier for pine wood to decompose under air than under nitrogen. Moreover, the first stage of pine wood combustion may be characterized by the diffusion model g(α) = [1 − (1 − α)1/3]2. The kinetic modeling showed a good agreement between the predicted and experimental conversion degree curves. In addition, the high comprehensive combustion index of pine wood at 10 K min-1 (6.73 × 10-7 %2 min-2 K-3) showed its great potential for bioenergy generation. Besides, both the value of ΔH and ΔS exhibited similar patterns with the activation energy value versus conversion degree, while the ΔG value almost remained at a positive constant with conversion degree. The average ΔH, ΔG, and ΔS value was nearly equal under different heating rates.

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Data Availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Acknowledgments

The authors would like to thank Huaping Bai for technical assistance.

Funding

This work was supported by the National Natural Science Foundation of China (no. 51806106) and the Science and Technology Department of Jiangsu Province, China (no: BK20170838).

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All authors contributed to the study conception and design. All authors contributed to the manuscript. Xiaokang Xu wrote the first draft of the manuscript. Renming Pan and Ruiyu Chen contributed to the revisions and the final draft of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Ruiyu Chen.

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Xu, X., Pan, R. & Chen, R. Combustion Characteristics, Kinetics, and Thermodynamics of Pine Wood Through Thermogravimetric Analysis. Appl Biochem Biotechnol 193, 1427–1446 (2021). https://doi.org/10.1007/s12010-020-03480-x

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Keywords

  • Combustion
  • Bioenergy
  • Woody biomass
  • Sustainable feedstock
  • Thermochemical conversion