Skip to main content
Log in

Traditional science in pigments and recipe of painting woodcarving in medieval Assam, India

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

A painting tradition of medieval Assam, popularly known as Hengul-Hāitāl, has been studied with an aim of restoring and conserving centuries-old woodcarvings and Sāncipat manuscripts for preserving in ordinary open conditions at villages and Vaishnavite monasteries. The pigments, their combinations for producing various shades and the resulting colors have been characterized using various physicochemical techniques. The study unravels some interesting traditional science, such as, using red Hengul (cinnabar), yellow Hāitāl (yellow orpiment) and blue Nīl (Indigo or Prussian blue) as primary colors to produce any desired shade, inclusion of either or both of Hengul and Hāitāl in every shade to repel fungi and insects, applying Kharimāti (a clay) as a wood-primer for better painting effects, choosing of Bael gum as a robust non-staining natural adhesive and finally varnishing with Lā (a natural lac) to protect the pigments from natural erosion and protect the woodcarving from humidity and contaminating hands touching them. The findings provide clues to develop an appropriate method of restoration of partially worn-out woodcarvings for preserving them in ordinary open conditions, based on the traditional method of preparation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Explore related subjects

Discover the latest articles, news and stories from top researchers in related subjects.

Availability of data and materials

On request, data is made available.

References

  1. Li, Z, Wang, L, Ma, Q, Mei, J, “A Scientific Study of the Pigments in the Wall Paintings at Jokhang Monastery in Lhasa.” Herit. Sci., 2 (1) 1–6 (2014)

    Article  Google Scholar 

  2. Carlyle, LA, Barrett, S, Stulik, DC, Glanville, H, Massing, A, Woodcock, SA, et al., Historical Painting Techniques, Materials, and Studio Practice. Getty Publications, University of Leiden, Netherlands (1995)

    Google Scholar 

  3. Costantini, I, Castro, K, Madariaga, JM, “Portable and Laboratory Analytical Instruments for the Study of Materials, Techniques and Environmental Impacts in Mediaeval Mural Paintings.” Anal. Methods, 10 (40) 4854–4870 (2018)

    Article  Google Scholar 

  4. Sharma, A, Singh, MR, “A Review on Historical Earth Pigments Used in India’s Wall Paintings.” Heritage, 4 (3) 1970–1994 (2021)

    Article  Google Scholar 

  5. Britannica, T, “Editors of Encyclopaedia, ‘Mural’.” Encyclopedia Britannica, November 15, (2021), https://www.britannica.com/art/mural-painting; 2021 [accessed 13 September 2021]

  6. Gullick, TJ, Timbs, J, Painting Popularly Explained: Including Fresco, Water-glass, Oil, Tempera, Mosais, Encaustic, Water-colour, Miniature, Painting on Ivory, Vellum, Pottery, Porcelain, Enamel, Glass, & c, with Historical Sketches of the Progress of the Art. Lockwood, London (1864)

    Google Scholar 

  7. Samson, AV, Wrapson, LJ, Cartwright, CR, Sahy, D, Stacey, RJ, Cooper, J, “Artists Before Columbus: A Multi-method Characterization of the Materials and Practices of Caribbean Cave Art.” J. Arch. Sci., 88 24–36 (2017)

    Article  CAS  Google Scholar 

  8. Lahanier, C, Preusser, FD, Van Zelst, L, “Study and Conservation of Museum Objects: Use of Classical Analytical Techniques.” Nucl. Inst. Methods Phys. Res. Sect. B Beam Interac. Mat. Atoms., 14 (1) 1–9 (1986)

    Article  Google Scholar 

  9. Unger, A, Schniewind, A, Unger, W, Conservation of Wood Artifacts: A Handbook. Springer (2001)

    Book  Google Scholar 

  10. Dutta, RK, “The Science in the Traditional Manuscript-Writing Aids of Assam: Sāncipāt, Mahi and Hengul-Haital.” In: Nath, D (ed.) Religious Traditions and Social Practices in Assam, pp. 239–261. DVS Publication (2015)

    Google Scholar 

  11. Ali, AA, Goswami, BR, Ligira, N, Dutta, RK, “Sāncipāt: A Popular Writing-base of Manuscript of Early Assam, North East India.” Curr. Sci., 123 (11) 1359–1364 (2022)

    Article  CAS  Google Scholar 

  12. Sivaramamurti, C, Indian Painting: National Book Trust. India (2006)

  13. Royle, JF, An Essay on the Antiquity of Hindoo Medicine: Including an Introductory Lecture to the Course of Materia Medica and Therapeutics Delivered at King’s College. WH Allen (1837)

    Google Scholar 

  14. Finlay, V, The Brilliant History of Color in Art. J. Paul Getty Museum, Los Angeles (2014)

    Google Scholar 

  15. Dimand, MS, “Mughal Painting Under Akbar the Great.” Metrop. Mus. Art Bull., 12 (2) 46–51 (1953)

    Google Scholar 

  16. Ravindran, T, Arora, A, Ramya, S, Subba, RR, Raj, B, “Raman Spectroscopic Study of Medieval Indian Art of 17th Century.” J. Raman Spect., 42 (4) 803–807 (2011)

    Article  CAS  Google Scholar 

  17. Verma, SP, “Margin-Painting in Medieval Indian Art.” Proc. of the Indian History Congress, Indian History Congress, pp. 460–466 (1979)

  18. Herrmann, G, “Lapis Lazuli: The Early Phases of Its Trade.” Iraq., 30 (1) 21–57 (2014)

    Article  Google Scholar 

  19. Khare, M, “The Wine-Cup in Mughal Court Culture—From Hedonism to Kingship.” Medi. Hist. J., 8 (1) 143–188 (2005)

    Google Scholar 

  20. Saxena, S, Raja, A, Natural Dyes: Sources, Chemistry, Application and Sustainability Issues. Roadmap to Sustainable Textiles and Clothing, Springer, pp. 37–80 (2014)

    Google Scholar 

  21. Zhang, G, Gong, C, Gu, J, Katayama, Y, Someya, T, Gu, J-D, “Biochemical Reactions and Mechanisms Involved in the Biodeterioration of Stone World Cultural Heritage Under the Tropical Climate Conditions.” Int. Biodeterio. Biodeg., 143 104723 (2019)

    Article  CAS  Google Scholar 

  22. Adeel, S, Abrar, S, Kiran, S, Farooq, T, Gulzar, T, Jamal, M, “Sustainable Application of Natural Dyes in Cosmetic Industry.” In: Handbook of Renewable Materials for Coloration and Finishing, pp. 189 (2018)

  23. Bhushan, C, Assam: Its Heritage and Culture, Gyan Publishing House, p. 236 (2005)

    Google Scholar 

  24. Jayachandran, K, Sekar, I, Parthiban, K, Amirtham, D, Suresh, K, “Analysis of Different Grades of Agarwood (Aquilaria malaccensis Lamk.) Oil Through GC-MS.” Ind. J. Nat. Prod. Resour., 5 (1) 44–47 (2015)

    Google Scholar 

  25. Takemoto, H, Ito, M, Shiraki, T, Yagura, T, Honda, G, “Sedative Effects of Vapor Inhalation of Agarwood Oil and Spikenard Extract and Identification of Their Active Components.” J. Nat. Medi., 62 (1) 41–46 (2008)

    Article  CAS  Google Scholar 

  26. Neog, M, Sankaradeva and His Times-Early History of the Vaisnava Faith and Movement in Assam. Lawyer’s Book Stall, Guwahati (1965)

    Google Scholar 

  27. Cui, L, Newcombe, C, Urgast, DS, Raab, A, Krupp, EM, Feldmann, J, “Assessing the Toxicity of Arsenic-Bearing Sulfide Minerals with the Bio-indicator Corophium Volutator.” Environ. Chemis., 8 (1) 52–61 (2011)

    Article  CAS  Google Scholar 

  28. Gogoi, M, “Exotic Natural Dye of North East India.” India:New Delhi:Sarv Bhasha Trust (2021)

  29. Kalita, N, Asomor Puthisitro. Asom prokakhon porikhod (1996)

    Google Scholar 

  30. Spink, W, Ajanta: History and Development: Volume 5 Cave by Cave. University of Michigan (2006)

    Google Scholar 

  31. Dutta, RK, “Sāncipāt, Māhi aru Hengul-Hāitāl r rakhayonik dikhtu (Assamese) (Sāncipāt, Māhi and Chemical Sites of the Hengul-Hāitāl).” In: Kalita N, (ed.) Hengul-Hāitāl, Kolong Kola Kendra, pp. 59–72, (2019)

  32. Kalita N, “Bardowār Shilpabastu.” Nagaon: Git-pad: Senchowā (1985)

  33. Ali, AA, Dutta RK, “Scientific Conservation of Sāncipāt Manuscript: A Unique Type of Traditional Manuscript Written on Sānci-bark in Medieval Assam.” (2022) (under communication)

  34. Hunter, RS, Harold, RW, The Measurement of Appearance, Wiley, p. 411 (1987)

    Google Scholar 

  35. Pointer, M, “A Comparison of the CIE 1976 Colour Spaces.” Col. Res. Appli., 6 (2) 108–118 (1981)

    Article  Google Scholar 

  36. Khurshida, S, Deka, SC, “Application of Microwave and Hydrothermal Treatments for Modification of Cassava Starch of Manipur Region, India and Development of Cookies.” J. Food Sci. Tech., 59 1–11 (2021)

    Google Scholar 

  37. Adi, H, Larson, I, Stewart, P, “Laser Diffraction Particle Sizing of Cohesive Lactose Powders.” Pow. Tech., 179 (1–2) 90–94 (2007)

    Article  CAS  Google Scholar 

  38. Silva, CE, Silva, LP, Edwards, HG, de Oliveira, LFC, “Diffuse Reflection FTIR Spectral Database of Dyes and Pigments.” Analy. Bioanaly. Chemis., 386 (7) 2183–2191 (2006)

    Article  CAS  Google Scholar 

  39. Keune, K, Mass, J, Meirer, F, Pottasch, C, Van Loon, A, Hull, A, et al. “Tracking the Transformation and Transport of Arsenic Sulfide Pigments in Paints: Synchrotron-Based X-ray Micro-analyses.” J. Anal. Atomic Spectro, 30 (3) 813–827 (2015)

    Article  CAS  Google Scholar 

  40. “IR Spectrum Table & Chart. Merck.” https://www.sigmaaldrich.com/IN/en/technical-documents/technical-article/analytical-chemistry/photometry-and-reflectometry/irspectum-table, [accessed 12 August 2022]

  41. Jia, Y, Xu, L, Wang, X, Demopoulos, GP, “Infrared Spectroscopic and X-ray Diffraction Characterization of the Nature of Adsorbed Arsenate on Ferrihydrite.” Geochi. Cosmo. Acta., 71 (7) 1643–1654 (2007)

    Article  CAS  Google Scholar 

  42. Vermeulen, M, Janssens, K, Sanyova, J, Rahemi, V, McGlinchey, C, De Wael, K, “Assessing the Stability of Arsenic Sulfide Pigments and Influence of the Binding Media on Their Degradation by Means of Spectroscopic and Electrochemical Techniques.” Micro. J., 138 82–91 (2018)

    CAS  Google Scholar 

  43. Canty, A, Kishimoto, R, Deacon, G, Farquharson, G, “Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols.” Inorg. Chim. Acta., 20 161–166 (1976)

    Article  CAS  Google Scholar 

  44. Rogerio-Candelera, MÁ, Herrera, LK, Miller, AZ, García Sanjuán, L, Mora Molina, C, Wheatley, DW, et al. “Allochthonous Red Pigments Used in Burial Practices at the Copper Age Site of Valencina de la Concepción (Sevilla, Spain): Characterisation and Social Dimension.” J. Archaeo. Sci., 40 (1) 279–290 (2013)

    Article  CAS  Google Scholar 

  45. Wahyuningsih, S, Ramelan, A, Wardani, D, Aini, F, Sari, P, Tamtama, B, et al, “Indigo Dye Derived from Indigofera tinctoria as Natural Food Colorant.” Proc. IOP Conference Series: Materials Science and Engineering: IOP Publishing, p. 012048 (2017)

  46. Kumar, A, Lingfa, P, “Sodium Bentonite and Kaolin Clays: Comparative Study on their FT-IR, XRF, and XRD.” Mat. Today: Proc., 22 737–742 (2020)

    CAS  Google Scholar 

  47. Košařová, V, Hradil, D, Němec, I, Bezdička, P, Kanický, V, “Microanalysis of Clay-based Pigments in Painted Artworks by the Means of Raman Spectroscopy.” J. Raman Spectro., 44 (11) 1570–1577 (2013)

    Article  Google Scholar 

  48. Carmody, O, Kristóf, J, Frost, RL, Makó, É, Kloprogge, JT, Kokot, S, “A Spectroscopic Study of Mechanochemically Activated Kaolinite with the Aid of Chemometrics.” J. Colloid Interface Sci., 287 (1) 43–56 (2005)

    Article  CAS  Google Scholar 

  49. Goswami, BR, Chamuah, N, Dutta, RK, “A Physicochemical Characterisation of a Medieval Herbal Ink, Mahī, of Assam.” India. Col. Tech., 134 (6) 450–463 (2018)

    Article  CAS  Google Scholar 

  50. Yvon, HJ. “Raman Data and Analysis: Raman Spectroscopy for Analysis and Monitoring.” (2005)

  51. Garcia, DV, Da Silva Filho, JI, Silveira, L, Pacheco, MTT, Abe, JM, Carvalho, A, et al. “Analysis of Raman Spectroscopy Data with Algorithms Based on Paraconsistent Logic for Characterization of Skin Cancer Lesions.” Vibra. Spect., 103 102929 (2019)

    Article  CAS  Google Scholar 

  52. Grundmann, G, Ivleva, N, Richter, M, Stege, H, Haisch, C, “The Rediscovery of Sublimed Arsenic Sulphide Pigments in Painting and Polychromy: Applications of Raman Microspectroscopy.” In: Proc. Studying Old Master Paintings: Technology and Practice, The National Gallery Technical Bulletin 30th Anniversary Conference Postprints, pp. 269–275 (2011)

  53. Hill, I, Chang, W, Lau, W, “Raman Analysis of Anodic Films on Mercury Cadmium Telluride.” J. App. Phys., 68 (11) 5621–5624 (1990)

    Article  CAS  Google Scholar 

  54. Billinge, SJ, McKimmy, EJ, Shatnawi, M, Kim, H, Petkov, V, Wermeille, D, et al. “Mercury Binding Sites in Thiol-Functionalized Mesostructured Silica.” J. Am. Chem. Soci., 127 (23) 8492–8498 (2005)

    Article  CAS  Google Scholar 

  55. Alotaibi, FSS, The Synthesis of Teallite (PbSnS2) from Molecular Precursors. The University of Manchester, p. 69 (2018)

    Google Scholar 

  56. Mullen, D, Nowacki, W, “Refinement of the Crystal Structures of Realgar, AsS and Orpiment, As2S3.” Zeits. Kristall. Cryst. Mat., 136 (1–6) 48–65 (1972)

    CAS  Google Scholar 

  57. Larsen, ES, Berman, H, The Microscopic Determination of the Nonopaque Minerals. US Government Printing Office. p. 234 (1934)

  58. Mullen, D, Nowacki, W, “Sulfides and Sulfo Salts. 65. Refinement of the Crystal Structures of Realgar, AsS, and Orpiment, As2S3.” Z Kristallog. Kristallge. Kristallphy. Kristallchem., 136 48–65 (1972)

    Article  CAS  Google Scholar 

  59. Auvray, P, Genet, F, “Affinement de la Structure Cristalline du Cinabre ot-HgS.” Bull. Soc. Fr. Min. Crist., 96 218–219 (1973)

    CAS  Google Scholar 

  60. Joni, I, Nulhakim, L, Vanitha, M, Panatarani, C, “Characteristics of Crystalline Silica (SiO2) Particles Prepared by Simple Solution Method Using Sodium Silicate (Na2SiO3) Precursor.” Proc. Journal of Physics: Conference Series: IOP Publishing, p. 012006 (2018)

  61. Nechitayilo, V, Styopkin, V, Tkachenko, Z, Goltsov, YG, Sherstyuk, V, Zhilinskaya, V, “Structure and Electrochromic Properties of Ferric Aquapentacyanoferrate—A New Analogue of Prussian Blue.” Electrochim. Acta, 40 (15) 2501–2504 (1995)

    Article  CAS  Google Scholar 

  62. Lee, RE, “The Size of Suspended Particulate Matter in Air: Size Distributions of Ambient Aerosols Must be Studied in Order to Determine Their Effects on the Environment.” Science, 178 (4061) 567–575 (1972)

    Article  Google Scholar 

  63. Ruh, R, Wadsley, A, “The Crystal Structure of ThTi2O6 (Brannerite).” Acta Crystall., 21 (6) 974–978 (1966)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Authors thank INSA, New Delhi for a financial assistance (HS/RC568) under its history of science research program. AAA thanks Tezpur University for an Innovation Research Grant and an Institutional fellowship.

Funding

This work was supported by Tezpur University. Author Asadulla Asraf Ali has received research support from Tezpur University and thanks Tezpur University for an Innovation Research Grant (No. DoRD/RIG/10-73/1544-A) and an Institutional fellowship (No. F.14-5/3/2003(Acad)/375-A). The authors also thank SAIC, Tezpur University for providing instrumentation facilities.

Author information

Authors and Affiliations

Authors

Contributions

All the authors certify that they have participated sufficiently in the work to take public responsibility for the content, including participation in the concept, design, analysis, and writing and there are no conflicts to declare. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Robin K. Dutta.

Ethics declarations

Competing interests

The authors have no relevant financial or non-financial interests to disclose.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ali, A.A., Dutta, R.K. Traditional science in pigments and recipe of painting woodcarving in medieval Assam, India. J Coat Technol Res 20, 1595–1609 (2023). https://doi.org/10.1007/s11998-023-00765-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-023-00765-8

Keywords

Navigation