Skip to main content
SpringerLink
Log in

Layered double hydroxides (LDHs) for coating applications

  • Review Article
  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Layered double hydroxides (LDHs) are an emerging technology that is used as a filler in coatings due to its structural and compositional flexibility. LDHs are layered compounds composed of positive metal hydroxides and negatively charged interlayer anions. We have discussed the structures and characteristics of LDHs in this review study, as well as many processes, such as the barrier mechanism, self-healing corrosion inhibitor method, and superhydrophobic mechanism, that demonstrate how LDHs operate in anticorrosion coatings. Additionally, how the use of LDH imparts flame-retardant qualities to the coatings is covered here, along with their respective processes. LDH coatings are suitable for packaging, biomedical, water treatment, and conductive applications alone or in combination with other materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Zümreoglu-Karan, B, Ay, AN, “Layered Double Hydroxides–Multifunctional Nanomaterials.” Chem. Pap., 66 (1) 1–10 (2012)

    Article  CAS  Google Scholar 

  2. Jiang, H, “Layered Double Hydroxides/Polymer Nanocomposites.” J. Chem. Res. Appl., 1 (1) 1–12 (2018)

    Google Scholar 

  3. Manzi-Nshuti, C, Wang, D, Hossenlopp, JM, Wilkie, CA, “The Role of the Trivalent Metal in an LDH: Synthesis, Characterization and Fire Properties of Thermally Stable PMMA/LDH Systems.” Polym. Degrad. Stab., 94 (4) 705–711 (2009)

    Article  CAS  Google Scholar 

  4. Braterman, PS, Xu, ZP, Yarberry, F, “Layered Double Hydroxides (LDHs).” In: Auerbach, SM, Carrado, KA, Dutta, PK (ed.) Handbook of Layered Materials, pp. 363–457. Marcel Dekker, New York (2005)

  5. Mallakpour, S, Motirasoul, F, “Electrical and Electronic Applications of Layered Doublehydroxide Polymer Nanocomposites.” In: Thomas, S, Daniel, S (ed.) Layered Double Hydroxide Polymer Nanocomposite, pp. 565–597. Woodhead Publishing (2020)

  6. Smalenskaite, A, Kaba, MM, Grigoraviciute-Puroniene, I, Mikoliunaite, L, Zarkov, A, Ramanauskas, R, Morkan, IA, Kareiva, A, “Sol–Gel Synthesis and Characterization of Coatings of Mg-Al Layered Double Hydroxides.” Materials, 12 (22) 3738 (2019)

    Article  CAS  Google Scholar 

  7. Oriakhi, CO, Farr, IV, Lerner, MM, “Incorporation of Poly(acrylic acid), Poly(vinylsulfonate) and Poly(styrenesulfonate) Within Layered Double Hydroxides.” J. Mater. Chem., 6 (1) 103–107 (1996)

    Article  CAS  Google Scholar 

  8. Zhang, G, Zhang, X, Meng, Y, Pan, G, Ni, Z, Xia, S, “Layered Double Hydroxides-Based Photocatalyst and Visible-Light Driven Photodegradation of Organic Pollutants: A Review.” Chem. Eng. J., 392 123684 (2020)

    Article  CAS  Google Scholar 

  9. Wang, X, Chen, Q, Zheng, Y, Hong, M, Fu, H, “Study on Novel Flame Retarded LDH-TDI-HEA-VTES-Acrylate Composites and Their Flame Retardant Mechanism.” React. Funct. Polym., 147 104371 (2020)

    Article  CAS  Google Scholar 

  10. Manzi-Nshuti, C, Songtipya, P, Manias, E, Jimenez-Gasco, MM, Hossenlopp, JM, Wilkie, CA, “Polymer Nanocomposites Using Zinc Aluminum and Magnesium Aluminum Oleate Layered Double Hydroxides: Effects of LDH Divalent Metals on Dispersion, Thermal, Mechanical and Fire Performance in Various Polymers.” Polymer, 50 (15) 3564–3574 (2009)

    Article  CAS  Google Scholar 

  11. Utracki, LA, Sepehr, M, Boccaler, E, “Synthetic, Layered Nanoparticles for Polymeric Nanocomposites (PNCs).” Polym. Adv. Technol., 18 (1) 1–37 (2007)

    Article  CAS  Google Scholar 

  12. Bugatti, V, Livi, S, Hayrapetyan, S, Wang, Y, Estevez, L, Vittoria, V, Giannelis, EP, “Deposition of LDH on Plasma Treated Polylactic Acid to Reduce Water Permeability.” J. Colloid Interface Sci., 15 (396) 47–52 (2013)

    Article  CAS  Google Scholar 

  13. Cho, S, Kwag, J, Jeong, S, Baek, Y, Kim, S, “Highly Fluorescent and Stable Quantum Dot-Polymer-Layered Double Hydroxide Composites.” Chem. Mater., 25 (7) 1071–1077 (2013)

    Article  CAS  Google Scholar 

  14. Nath, J, Dolui, SK, “Synthesis of Carboxymethyl Cellulose-g-POLY(acrylic acid)/LDH Hydrogel for In Vitro Controlled Release of Vitamin B12.” Appl. Clay Sci., 155 65–73 (2018)

    Article  CAS  Google Scholar 

  15. Badar, M, Rahim, MI, Kieke, M, Ebel, T, Rohde, M, Hauser, H, Behrens, P, Mueller, PP, “Controlled Drug Release from Antibiotic-Loaded Layered Double Hydroxide Coatings on Porous Titanium Implants in a Mouse Model.” J. Biomed. Mater. Res. A., 103 (6) 2141–2149 (2015)

    Article  CAS  Google Scholar 

  16. Zhang, F, Liu, ZG, Zeng, RC, Li, SQ, Cui, HZ, Song, L, Han, EH, “Corrosion Resistance of Mg-Al-LDH Coating on Magnesium Alloy AZ31.” Surf. Coat. Tech., 258 1152–1158 (2014)

    Article  CAS  Google Scholar 

  17. Khan, SA, Baksh, EM, Akhtar, K, Khan, SB, “A Template of Cellulose Acetate Polymer-ZnAl Layered Double Hydroxide Composite Fabricated with Ni NPs: Applications in the Hydrogenation of Nitrophenols and Dyes Degradation.” Spectrochim. Acta A Mol. Biomol. Spectrosc., 241 118671 (2020)

  18. Chakraborti, M, Jackson, JK, Plackett, D, Gilchrist, SE, Burt, HM, “The Application of Layered Double Hydroxide Clay (LDH)-Poly(lactide-co-glycolic acid) (PLGA) Film Composites for the Controlled Release of Antibiotics.” J. Mater. Sci: Mater. Med., 23 1705–1713 (2012)

    CAS  Google Scholar 

  19. Chen, C, Gunawan, P, Lou, XW, Xu, R, “Silver Nanoparticles Deposited Layered Double Hydroxide Nanoporous Coatings with Excellent Antimicrobial Activities.” Adv. Funct. Mater., 22 (4) 780–787 (2012)

    Article  CAS  Google Scholar 

  20. Gorrasi, G, Bugatti, V, “Edible Bio-nano-hybrid Coatings for Food Protection Based on Pectins and LDH Salycilate: Preparation and Analysis of Physical Properties.” LWT-Food Sci. Technol., 69 139–145 (2016)

    Article  CAS  Google Scholar 

  21. Liang, R, Yan, D, Tian, R, Yu, X, Shi, W, Li, C, Wei, M, Evans, DG, Duan, X, “Quantum Dots-Based Flexible Films and Their Application as the Phosphor in White Light-Emitting Diodes.” Chem. Mater., 26 (8) 2595−2600 (2014) (8) 2595−2600 (2014)

  22. Rudica, O, Rajnovicb, D, Cjepaa, D, Vucetica, S, Ranogajec, J, “Investigation of the Durability of Porous Mineral Substrates with Newly Designed TiO2-LDH Coating.” Ceram. Int., 41 (8) 9779–9792 (2015)

    Article  CAS  Google Scholar 

  23. Motlagh, PY, Khataee, A, Hassani, A, Rad, TS, “ZnFe-LDH/GO Nanocomposite Coated on the Glass Support as a Highly Efficient Catalyst for Visible Light Photodegradation of an Emerging Pollutant.” J. Mol. Liq., 302 112532 (2020)

    Article  CAS  Google Scholar 

  24. Yao, W, Li, L, Li, OL, Cho, YW, Jeong, MY, Cho, YR, “Robust, Self-Cleaning, Amphiphobic Coating with Flower-like Nanostructure on Micro-Patterned Polymer Substrate.” Chem. Eng. J., 352 173–181 (2018)

    Article  CAS  Google Scholar 

  25. Mao, L, Liu, Y, Wu, H, Chen, J, Yao, J, “Poly(ε-caprolactone) Filled with Polydopamine-Coated High Aspect Ratio Layered Double Hydroxide: Simultaneous Enhancement of Mechanical and Barrier Properties.” Appl. Clay Sci., 150 (15) 202–209 (2017)

    Article  CAS  Google Scholar 

  26. Fayomi, OSI, Akande, IG, Odigie, S, “Economic Impact of Corrosion in Oil Sectors and Prevention: An Overview.” J. Phys.: Conf. Ser., 1378 022037 (2019)

  27. Hang, TTX, Truc, TA, Duong, NT, “Preparation and Characterization of Nanocontainers of Corrosion Inhibitor Based on Layered Double Hydroxides.” Appl. Clay Sci., 67–68 18–25 (2012)

    Article  CAS  Google Scholar 

  28. Khanna, AS, “Nanotechnology in High Performance Paint Coatings.” Asian J. Exp. Sci., 21 25–32 (2008)

    Google Scholar 

  29. Guo, X, Zhang, F, Evans, DG, Duan, X, “Layered Double Hydroxide Films: Synthesis, Properties and Applications.” Chem. Commun, 46 5197–5210 (2010)

    Article  CAS  Google Scholar 

  30. Bukhtiyarova, MV, “A Review on Effect of Synthesis Conditions on the Formation of Layered Double Hydroxides.” J. Solid State Chem., 269 494–506 (2019)

    Article  CAS  Google Scholar 

  31. Barik, S, Badamali, SK, “Layer Double Hydroxide Reinforced Polymer Bionanocomposites for Packaging Applications.” In: Jawaid M, Swain S, (eds) Bionanocomposites for Packaging Applications, pp. 269–290, Springer International Publishing AG (2018)

  32. Kovanda, F, Jindová, E, Doušová, B, Koloušek, D, Pleštil, J, Sedláková, Z, “Layered Double Hydroxides Intercalated with Organic Anions and Their Application in Preparation of LDH/Polymer Nanocomposites.” Acta Geodyn. Geomater., 6 (1) 111–119 (2009)

    CAS  Google Scholar 

  33. Basu, D, Das, A, Stockelhuber, KW, Wagenknecht, U, Heinrich, G, “Advances in Layered Double Hydroxide (LDH)-based Elastomer Composites.” Prog. Polym. Sci., 39 (3) 594–626 (2014)

    Article  CAS  Google Scholar 

  34. Arizaga, GGC, Satyanarayana, KG, Wypych, F, “Layered Hydroxide Salts: Synthesis, Properties and Potential Applications.” Solid State Ion., 178 (15–18) 1143–1162 (2007)

    Article  CAS  Google Scholar 

  35. Lu, J, Jianzhong, M, Dangge, G, Bin, L, “Layered Double Hydroxide/Polymer Nanocomposite.” Prog. Chem., 30 (2–3) 295–303 (2018)

    Google Scholar 

  36. Park, DH, Hwang, SJ, Oh, JM, Yang, JH, Choy, JH, “Polymer–Inorganic Supramolecular Nanohybrids for Red, White, Green, and Blue Applications.” Prog. Polym. Sci., 38 (10–11) 1442–1486 (2013)

    Article  CAS  Google Scholar 

  37. Khan, AI, O’Hare, D, “Intercalation Chemistry of Layered Double Hydroxides: Recent Developments and Applications.” J. Mater. Chem., 12 3191–3198 (2002)

    Article  CAS  Google Scholar 

  38. Prévot, V, Bourgeat-Lami, E, "Recent Advances in Layered Double Hydroxide/Polymer Latexes Nanocomposites: From Assembly to In Situ Formation.” In: Thomas, S, Daniel, S (ed.) Layered Double Hydroxide Polymer Nanocomposite, pp. 461–489. Woodhead Publishing (2020)

  39. Taviot-Guého, C, Leroux, F, “In Situ Polymerization and Intercalation of Polymers in Layered Double Hydroxides.” In: Duan X, Evans, DG, (eds) Layered Double Hydroxides. Structure and Bonding, pp. 121–159. vol 119. Springer, Berlin, Heidelberg (2006)

  40. Salak, AN, Tedim, J, Kuznetsova, AI, Ribeiro, JL, Vieira, LG, Zheludkevich, ML, Ferreira, MGS, “Comparative X-ray Diffraction and Infrared Spectroscopy Study of Zn–Al Layered Double Hydroxides: Vanadate vs Nitrate.” Chem. Phy., 397 102–108 (2012)

    Article  CAS  Google Scholar 

  41. Costa, FR, Leuteritz, A, Meinl, J, Wagenknecht, U, Heinrich, G, “LDH as Nanofiller: Organic Modification and Dispersion in Polymers.” Macromol. Symp., 301 (1) 46–54 (2011)

    Article  CAS  Google Scholar 

  42. Taviot-Guého, C, Prévot, V, Forano, C, Renaudin, G, Mousty, C, Leroux, F, “Tailoring Hybrid Layered Double Hydroxides for the Development of Innovative Applications.” Adv. Funct. Mater., 28 (27) 1703868 (2018)

    Article  CAS  Google Scholar 

  43. Chen, W, Qu, B, “Structural Characteristics and Thermal Properties of PE-g-MA/MgAl-LDH Exfoliation Nanocomposites Synthesized by Solution Intercalation.” Chem. Mater., 15 (16) 3208–3213 (2003)

    Article  CAS  Google Scholar 

  44. Evans, DG, Duan, X, “Preparation of Layered Double Hydroxides and Their Applications as Additives in Polymers, as Precursors to Magnetic Materials and in Biology and Medicine.” Chem. Commun., 5 485–496 (2006)

    Article  Google Scholar 

  45. Bini, M, Monteforte, F, “Layered Double Hydroxides (LDHs): Versatile and Powerful Hosts for Different Applications.” J. Anal. Pharm. Res., 7 (1) 00206 (2018)

    Article  Google Scholar 

  46. Jamil, S, Alvi, AR, Khan, SR, Janjua, MRSA, “Layered Double Hydroxides (LDHs): Synthesis and Applications.” Prog. Chem., 31 (2-3) 394–412 (2019)

    Google Scholar 

  47. Peng, D, Wei, C, Baojun, Q, “Recent Progress in Polymer Layered Double Hydroxide Nanocomposites.” Prog. Nat. Sci., 16 573–579 (2006)

    Article  Google Scholar 

  48. Leroux, F, “Organo-Modified Anionic Clays into Polymer Compared to Smectite-Type Nanofiller: Potential Applications of the Nanocomposites.” J. Nanosci. Nanotechnol., 6 (2) 303–315 (2006)

    Article  CAS  Google Scholar 

  49. Wong, F, Buchheit, RG, “Utilizing the Structural Memory Effect of Layered Double Hydroxides for Sensing Water Uptake in Organic Coatings.” Prog. Org. Coat., 51 (2) 91–102 (2004)

    Article  CAS  Google Scholar 

  50. Klemkaite, K, Prosycevas, I, Taraskevicius, R, Khinsky, A, Kareiva, A, “Synthesis and Characterization of Layered Double Hydroxides with Different Cations (Mg Co, Ni, Al), Decomposition and Reformation of Mixed Metal Oxides to Layered Structures.” Cent. Eur. J. Chem., 9 (2) 275–282 (2011)

    CAS  Google Scholar 

  51. Guo, L, Wu, W, Zhou, Y, Zhang, F, Zeng, R, Zeng, J, “Layered Double Hydroxide Coatings on Magnesium Alloys: A Review.” J. Mater. Sci. Technol., 34 (9) 1455–1466 (2018)

    Article  CAS  Google Scholar 

  52. Tabish, M, Yasin, G, Anjum, MJ, Malik, MU, Zhao, J, Yang, Q, Manzoor, S, Murtaza, H, Khan, WQ, “Reviewing the Current Status of Layered Double Hydroxide-Based Smart Nanocontainers for Corrosion Inhibiting Applications.” J. Mater. Res. Technol., 10 390–421 (2021)

    Article  CAS  Google Scholar 

  53. Othmana, MR, Helwania, Z, Martunusa, Fernando, WJN, “Synthetic Hydrotalcites from Different Routes and Their Application as Catalysts and Gas Adsorbents: A Review.” Appl. Organometal. Chem., 23 (9) 335–346 (2009)

    Article  CAS  Google Scholar 

  54. Joy, M, Iyengar, SJ, Chakraborty, J, Ghosh, S, “Layered Double Hydroxide Using Hydrothermal Treatment: Morphology Evolution, Intercalation and Release Kinetics of Diclofenac Sodium.” Front. Mater. Sci., 11 395–408 (2017)

    Article  Google Scholar 

  55. Inayat, A, Klumpp, M, Schwieger, W, “The Urea Method for the Direct Synthesis of ZnAl Layered Double Hydroxides with Nitrate as the Interlayer Anion.” Appl. Clay Sci., 51 (4) 452–459 (2011)

    Article  CAS  Google Scholar 

  56. Iqbal, MA, Sun, L, Barrett, AT, Fedel, M, “Layered Double Hydroxide Protective Films Developed on Aluminum and Aluminum Alloys: Synthetic Methods and Anti-corrosion Mechanisms.” Coatings, 10 (4) 428 (2020)

    Article  CAS  Google Scholar 

  57. Leroux, F, Besse, JP, “Polymer Interleaved Layered Double Hydroxide: A New Emerging Class of Nanocomposites.” Chem. Mater., 13 (10) 3507–3515 (2001)

    Article  CAS  Google Scholar 

  58. Smalenskaitea, A, Vieira, DEL, Salak, AN, Ferreira, MGS, Katelnikovas, A, Kareiva, A, “A Comparative Study of Co-precipitation and Sol-Gel Synthetic Approaches to Fabricate Cerium-Substituted Mg-Al Layered Double Hydroxides with Luminescence Properties.” Appl. Clay Sci., 143 175–183 (2017)

    Article  CAS  Google Scholar 

  59. Jitianu, M, Zaharescu, M, Asoiu, MB, Jitianu, A, “The Sol-Gel Route in Synthesis of Cr(III)-Containing Clays. Comparison Between Mg-Cr and Ni-Cr Anionic Clays.” J. Solgel Sci. Technol., 26 217–221 (2003)

    Article  CAS  Google Scholar 

  60. Naseem, S, Gevers, B, Boldt, R, Labuschagne, FJWJ, Leuteritz, A, “Comparison of Transition Metal (Fe, Co, Ni, Cu, and Zn) Containing Tri-metal Layered Double Hydroxides (LDHs) Prepared by Urea Hydrolysis.” RSC Adv. 9 3030 (2019)

  61. Zheludkevich, ML, Tedim, J, Ferreira, MGS, “‘Smart’ Coatings for Active Corrosion Protection Based on Multi-functional Micro and Nanocontainers.” Electrochim. Acta, 82 314–323. https://doi.org/10.1016/J.ELECTACTA.2012.04.095 (2012)

    Article  CAS  Google Scholar 

  62. Tedim, J, Zheludkevich, ML, Salak, AN, Lisenkov, A, Ferreira, MGS, “Nanostructured LDH-Container Layer with Active Protection Functionality.” J. Mater. Chem., 21 15464–15470. https://doi.org/10.1039/C1JM12463C (2011)

    Article  CAS  Google Scholar 

  63. Hu, J, Gan, M, Ma, L, Zhang, J, Xie, S, Xu, F, Shen, JYZX, Yin, H, “Preparation and Enhanced Properties of Polyaniline/Grafted Intercalated ZnAl-LDH Nanocomposites.” Appl. Surf. Sci., 328 (2015) 325–334 (2015)

    Article  CAS  Google Scholar 

  64. Acharya, H, Srivastava, SK, Bhowmick, AK, “Synthesis of Partially Exfoliated EPDM/LDH Nanocomposites by Solution Intercalation: Structural Characterization and Properties.” Compos. Sci. Technol., 67 (13) 2807–2816 (2007)

    Article  CAS  Google Scholar 

  65. Du, L, Qu, B, Meng, Y, Zhu, Q, “Structural Characterization and Thermal and Mechanical Properties of Poly(propylene carbonate)/MgAl-LDH Exfoliation Nanocomposite via Solution Intercalation.” Comp. Sci. Technol., 66 (7–8) 913–918 (2006)

    Article  CAS  Google Scholar 

  66. Costa, FR, Abdel-Goad, M, Wagenknecht, U, Heinrich, G, “Nanocomposites Based on Polyethylene and Mg–Al Layered Double Hydroxide. I. Synthesis and Characterization.” Polymer, 46 (12) 4447–4453 (2005)

    Article  CAS  Google Scholar 

  67. Ding, P, Qu, B, “Synthesis and Characterization of Exfoliated Polystyrene/ZnAl Layered Double Hydroxide Nanocomposite via Emulsion Polymerization.” J. Colloid Interface Sci., 291 (1) 13–18 (2005)

    Article  CAS  Google Scholar 

  68. Ding, P, Qu, B, “Synthesis of Exfoliated PP/LDH Nanocomposites via Melt-Intercalation: Structure, Thermal Properties, and Photo-Oxidative Behavior in Comparison With PP/MMT Nanocomposites.” Polym. Eng. Sci., 46 (9) 1153–1159 (2006)

    Article  CAS  Google Scholar 

  69. Hajibeygi, M, Shabanian, M, Khonakdar, HA, “Zn–AL LDH Reinforced Nanocomposites Based on New Polyamide Containing Imide Group: From Synthesis to Properties.” Appl. Clay Sci., 114 256–264 (2015)

    Article  CAS  Google Scholar 

  70. Karamia, Z, Jouyandeha, M, Alic, JA, Ganjalia, MR, Aghazadeh, M, Paran, SMR, Naderi, G, Puglia, D, Saeb, MR, “Epoxy/Layered Double Hydroxide (LDH) Nanocomposites: Synthesis, Characterization, and Excellent Cure Feature of Nitrate Anion Intercalated ZnAl LDH.” Prog. Org. Coat., 136 105218 (2019)

    Article  CAS  Google Scholar 

  71. Lv, S, Zhou, W, Miao, H, Shi, W, “Preparation and Properties of Polymer/LDH Nanocomposite Used for UV Curing Coatings.” Prog. Org. Coat., 65 (4) 450–456 (2009)

    Article  CAS  Google Scholar 

  72. Wang, Q, Zhang, X, Zhu, J, Guo, Z, O’Hare, D, “Preparation of Stable Dispersions of Layered Double Hydroxides (LDHs) in Nonpolar Hydrocarbons: New Routes to Polyolefin/LDH Nanocomposites.” Chem. Commun., 48 7450–7452 (2012)

    Article  CAS  Google Scholar 

  73. Whilton, NT, Vickers, PJ, Mann, S, “Bioinorganic Clays: Synthesis and Characterization of Amino- and Polyamino Acid Intercalated Layered Double Hydroxides.” J. Mater. Chem., 7 1623–1629 (1997)

    Article  CAS  Google Scholar 

  74. Kaseem, M, Ko, YG, “A Novel Composite System Composed of Zirconia and LDHs Film Grown on Plasma Electrolysis Coating: Towards a Stable Smart Coating.” Ultrason. Sonochem., 49 316–324 (2018)

    Article  CAS  Google Scholar 

  75. Ding, C, Tai, Y, Wang, D, Tan, L, Fu, J, “Superhydrophobic Composite Coating with Active Corrosion Resistance for AZ31B Magnesium Alloy Protection.” Chem. Eng. J., 357 518–532 (2019)

    Article  CAS  Google Scholar 

  76. Wu, L, Ding, X, Zheng, Z, Ma, Y, Atrens, A, Chen, X, Xie, Z, Sun, D, Pan, F, “Fabrication and Characterization of an Actively Protective Mg-Al LDHs/Al2O3 Composite Coating on Magnesium Alloy AZ31.” Appl. Surf. Sci., 487 558–568 (2019)

    Article  CAS  Google Scholar 

  77. Yang, H, “Preparation and Corrosion Resistance of ZIF-8-(5, 6-dimethylbenzimidazole)/LDHs Composite Film on Magnesium Alloy.” Int. J. Electrochem. Sci., 15 12203–12219 (2020)

    Article  CAS  Google Scholar 

  78. Ding, X, Wu, L, Chen, J, Zhang, G, Xie, Z, Sun, D, Jiang, B, Atrens, A, Pan, F, "Enhanced Protective Nanoparticle-Modified MgAl-LDHs Coatings on Titanium Alloy.” Surf. Coat. Tech., 404 126449 (2020)

  79. Wu, F, Liang, J, Peng, Z, Liu, B, “Electrochemical Deposition and Characterization of ZnAl Layered Double Hydroxides (LDHs) Films on Magnesium Alloy.” Appl. Surf. Sci., 313 834–840 (2014)

    Article  CAS  Google Scholar 

  80. Zhang, F, Sun, M, Xu, S, Zhao, L, Zhang, B, “Fabrication of Oriented Layered Double Hydroxide Films by Spin Coating and Their Use in Corrosion Protection.” Chem. Eng. J., 141 (1–3) 362–367 (2008)

    Article  CAS  Google Scholar 

  81. Hang, TTX, Truc, TA, Duong, NT, Pébére, N, Olivier, MG, “Layered Double Hydroxides as Containers of Inhibitors in Organic Coatings for Corrosion Protection of Carbon Steel.” Prog. Org. Coat., 74 (2) 343–348 (2012)

    Article  CAS  Google Scholar 

  82. Wang, N, Gao, H, Zhang, J, Li, L, Fan, X, Diao, X, “Anticorrosive Waterborne Epoxy (EP) Coatings Based on Sodium Tripolyphosphate-Pillared Layered Double Hydroxides (STPP-LDHs).” Prog. Org. Coat., 135 74–81 (2019)

    Article  CAS  Google Scholar 

  83. Dong, Y, Wang, F, Zhou, Q, “Protective Behaviors of 2-Mercaptobenzothiazole Intercalated Zn–Al-Layered Double Hydroxide Coating.” J. Coat. Technol. Res., 11 793–803 (2014)

  84. Farkas, FK, “The Industrial Paint-Making Process.” In: Lambourne, R, Strivens, TA (eds.) Paint and Surface Coatings Theory and Practice, pp. 286–329. Woodhead Publishing, England (1999)

    Chapter  Google Scholar 

  85. Manoj, A, Ramachandran, R Menezes, PL, “Self-Healing and Superhydrophobic Coatings for Corrosion Inhibition and Protection.” Int. J. Adv. Manuf. Technol., 106 2119–2131 (2020)

  86. Ghazi, A, Ghasemi, E, Mahdavian, M, Ramezanzadeh, B, Rostami, M, “The Application of Benzimidazole and Zinc Cations Intercalated Sodium Montmorillonite as Smart Ion Exchange Inhibiting Pigments in the Epoxy Ester Coating.” Corros. Sci., 94 207–217 (2015)

    Article  CAS  Google Scholar 

  87. Grigoriev, D, “Anticorrosion Coatings with Self Recovering Ability Based on Damage Triggered Micro and Nanocontainers.” In: Tiwari, A, Rawlins J, Hihara, LH, (eds.) Intelligent Coating for Corrosion Control. pp. 283–333. Butterworth-Heinemann (2015)

  88. Zhong, F, He, Y, Wang, P, Chen, C, Xie, P, Li, H, Chen, J, “One-Step Hydrothermal Synthesis of Reduced Graphene Oxide/Aspartic Acid Intercalated Layered Double Hydroxide for Enhancing Barrier and Self-healing Properties of Epoxy Coating.” React. Funct. Polym., 145 104380 (2019)

  89. Mei, Y, Xu, J, Jiang, L, Tan, Q, “Enhancing Corrosion Resistance of Epoxy Coating on Steel Reinforcement by Aminobenzoate Intercalated Layered Double Hydroxides.” Prog. Org. Coat., 134 288–296 (2019)

    Article  CAS  Google Scholar 

  90. Su, Y, Qiu, S, Yang, D, Liu, S, Zhao, H, Wang, L, Xue, Q, “Active Anti-corrosion of Epoxy Coating by Nitrite Ions Intercalated MgAl LDH.” J. Hazard. Mater., 391 122215 (2020)

  91. Hao, L, Yan, T, Zhang, Y, Zhao, X, Lei, X, Xu, S, Zhang, F, “Fabrication and Anticorrosion Properties of Composite Films of Silica/Layered Double Hydroxide.” Surf. Coat. Tech., 326 (Part A) 200-206 (2017)

  92. Zhang, F, Sun, M, Xu, S, Zhao, L, Zhang, B, “Fabrication of Oriented Layered Double Hydroxide Films by Spin Coating and Their Use in Corrosion Protection.” Chem. Eng. J., 141 (1–3) 362–367 (2008)

    Article  CAS  Google Scholar 

  93. Alibakhshi, E, Ghasemi, E, Mahdavian, M, Ramezanzadeh, B, Farashi, S, “Active Corrosion Protection of Mg-Al-PO43− LDH Nanoparticle in Silane Primer Coated with Epoxy on Mild Steel.” J. Taiwan Inst. Chem. Eng., 75 248–262 (2017)

    Article  CAS  Google Scholar 

  94. Zhang, F, Zhao, L, Chen, H, Xu, S, Evans, DG, Duan, X, “Corrosion Resistance of Superhydrophobic Layered Double Hydroxide Films on Aluminum.” Angew. Chem. Int. Ed. Engl., 120 (13) 2500–2503 (2008)

    Article  Google Scholar 

  95. Sun, W, Wu, T, Wang, L, Dong, C, Liu, G, “Controlled Preparation of MgAl-Layered Double Hydroxide/Graphene Hybrids and Their Applications for Metal Protection.” Ind. Eng. Chem. Res., 58 (36) 16516–16525 (2019)

    Article  CAS  Google Scholar 

  96. Stimpfling, T, Leroux, F, Hintze-Bruening, H, “Unraveling EDTA Corrosion Inhibition When Interleaved into Layered Double Hydroxide Epoxy Filler System Coated onto Aluminum AA 2024.” Appl. Clay. Sci., 83–84 32–41 (2013)

    Article  CAS  Google Scholar 

  97. Chen, J, Feng, J, Yan, L, Li, H, Xiong, C, Ma, S, “In Situ Growth Process of Mg–Fe Layered Double Hydroxide Conversion Film on MgCa Alloy.” J. Magnes. Alloy. (2020).

  98. Imanieh, I, Afshar, A "Corrosion Protection of Aluminum by Smart Coatings Containing Layered Double Hydroxide (LDH) Nanocontainers." J. Mater. Res. Technol., 8 (3) 3004–3023 (2019)

  99. Iqbal, MA, Fedel, M, “Effect of Operating Parameters on the Structural Growth of ZnAl Layered Double Hydroxide on AA6082 and Corresponding Corrosion Resistance Properties.” J. Coat. Technol. Res., 16 (5) 1423–1433 (2019)

    Article  CAS  Google Scholar 

  100. Buchheit, RG, Guan, H, Mahajanam, S, Wong, F, “Active Corrosion Protection and Corrosion Sensing in Chromate-Free Organic Coatings.” Prog. Org. Coat., 47 174–182. https://doi.org/10.1016/J.PORGCOAT.2003.08.003 (2003)

    Article  CAS  Google Scholar 

  101. Williams, G., McMurray, H.N. “Inhibition of Filiform Corrosion on Polymer Coated AA2024-T3 by Hydrotalcite-like Pigments Incorporating Organic Anions.” Electrochem. Solid-State Lett., 7 (2004). https://doi.org/10.1149/1.1691529/META.

  102. Zn–Al Layered Double Hydroxides as Chloride Nanotraps in Active Protective Coatings, (n.d.). https://www.infona.pl/resource/bwmeta1.element.elsevier-ef8c05ce-54ac-38ba-8f1b-6ea3a58940d1 (accessed December 9, 2021).

  103. Bakhtaoui, N, Benali, O, Mazarío, E, Recio, FJ, Herrasti, P, “Layered Double Hydroxides Intercalated with Methyl Orange as a Controlled-Release Corrosion Inhibitor for Iron in Chloride Media.” Nano Express, 2 010017. https://doi.org/10.1088/2632-959X/ABE2B6 (2021)

    Article  Google Scholar 

  104. Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Möhwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-Healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 402–411. https://doi.org/10.1021/CM062066K (2007)

    Article  CAS  Google Scholar 

  105. Bouali, AC, Serdechnova, M, Blawert, C, Tedim, J, Ferreira, MGS, Zheludkevich, ML, “Layered Double Hydroxides (LDHs) as Functional Materials for the Corrosion Protection of Aluminum Alloys: A Review.” Appl. Mater. Today, 21 100857. https://doi.org/10.1016/J.APMT.2020.100857 (2020)

    Article  Google Scholar 

  106. Tedim, J, Kuznetsova, A, Salak, A, Montemor, NF, Snihirova, D, Pilz, M, Zheludkevich, ML, Ferreira, MGS, "Zn–Al Layered Double Hydroxides as Chloride Nanotraps in Active Protective Coatings." Corros. Sci.,55 1–4. https://doi.org/10.1016/J.CORSCI.2011.10.003 (2012)

    Article  CAS  Google Scholar 

  107. Lin, JK, Hsia, CL, Uan, JY, “Characterization of Mg, Al-Hydrotalcite Conversion Film on Mg Alloy and Cl− and CO32- Anion-Exchangeability of the Film in a Corrosive Environment.” Scr. Mater., 11 927–930. https://doi.org/10.1016/J.SCRIPTAMAT.2007.02.020 (2007)

    Article  Google Scholar 

  108. Uan, JY, Lin, JK, Tung, YS, “Direct Growth of Oriented Mg–Al Layered Double Hydroxide Film on Mg Alloy in Aqueous HCO3−/CO32− Solution.” J. Mater. Chem., 20 761–766. https://doi.org/10.1039/B917177K (2010)

    Article  CAS  Google Scholar 

  109. Zhang, F, Zhao, L, Chen, H, Xu, S, Evans, DG, Duan, X, “Corrosion Resistance of Superhydrophobic Layered Double Hydroxide Films on Aluminum.” Angew. Chem. Int. Ed., 47 2466–2469. https://doi.org/10.1002/ANIE.200704694 (2008)

    Article  CAS  Google Scholar 

  110. Kagunya, W, Hassan, Z, Jones, W, “Catalytic Properties of Layered Double Hydroxides and Their Calcined Derivatives.” Inorg. Chem., 35 5970–5974. https://doi.org/10.1021/IC960047E (1996)

    Article  CAS  Google Scholar 

  111. Zhang, W, Buchheit, RG, “Hydrotalcite Coating Formation on Al-Cu-Mg Alloys from Oxidizing Bath Chemistries.” Corros., 58 591–600. https://doi.org/10.5006/1.3277650 (2002)

    Article  CAS  Google Scholar 

  112. Karami, Z, Jouyandeh, M, Ali, JA, Ganjali, MR, Aghazadeh, M, Paran, SMR, Naderi, G, Puglia, D, Saeb, MR, “Epoxy/Layered Double Hydroxide (LDH) Nanocomposites: Synthesis, Characterization, and Excellent Cure Feature of Nitrate Anion Intercalated Zn-Al LDH.” Prog. Org. Coat., 136 105218. https://doi.org/10.1016/J.PORGCOAT.2019.105218 (2019)

    Article  CAS  Google Scholar 

  113. Karami, Z, Jouyandeh, M, Ali, JA, Ganjali, MR, Aghazadeh, M, Maadani, M, Rallini, M, Luzi, F, Torre, L, Puglia, D, Akbari, V, Saeb, MR, “Cure Index for Labeling Curing Potential of Epoxy/LDH Nanocomposites: A Case Study on Nitrate Anion Intercalated Ni-Al-LDH.” Prog. Org. Coat., 136 105228. https://doi.org/10.1016/J.PORGCOAT.2019.105228 (2019)

    Article  CAS  Google Scholar 

  114. Karami, Z, Jouyandeh, M, Ali, JA, Ganjali, MR, Aghazadeh, M, Maadani, M, Rallini, M, Luzi, F, Torre, L, Puglia, D, Saeb, MR, “Development of Mg-Zn-Al-CO3 Ternary LDH and its Curability in Epoxy/Amine System.” Prog. Org. Coat., 136 105264. https://doi.org/10.1016/J.PORGCOAT.2019.105264 (2019)

    Article  CAS  Google Scholar 

  115. Karami, Z, Jouyandeh, M, Hamad, SM, Ganjali, MR, Aghazadeh, M, Torre, L, Puglia, D, Saeb, MR, “Curing Epoxy with Mg-Al LDH Nanoplatelets Intercalated with Carbonate Ion.” Prog. Org. Coat., 136 105278. https://doi.org/10.1016/J.PORGCOAT.2019.105278 (2019)

    Article  CAS  Google Scholar 

  116. Karami, Z, Aghazadeh, M, Jouyandeh, M, Zarrintaj, P, Vahabi, H, Ganjali, MR, Torre, L, Puglia, D, Saeb, MR, “Epoxy/Zn-Al-CO3 LDH Nanocomposites: Curability Assessment.” Prog. Org. Coat., 138 105355. https://doi.org/10.1016/J.PORGCOAT.2019.105355 (2020)

    Article  CAS  Google Scholar 

  117. Karami, Z, Jouyandeh, M, Ghiyasi, S, Ali, JA, Ganjali, MR, Aghazadeh, M, Maadani, M, Rallini, M, Luzi, F, Torre, L, Puglia, D, Saeb, MR, “Exploring Curing Potential of Epoxy Nanocomposites Containing Nitrate Anion Intercalated Mg–Al–LDH with Cure Index.” Prog. Org. Coat., 139 105255. https://doi.org/10.1016/J.PORGCOAT.2019.105255 (2020)

    Article  CAS  Google Scholar 

  118. Karami, Z, Paran, SMR, Poornima, VP, Ganjali, MR, Jouyandeh, M, Esmaeili, A, Habibzadeh S, Stadler FJ, Saeb MR, “A Comparative Study on Cure Kinetics of Layered Double Hydroxide (LDH)/Epoxy Nanocomposites.” J. Compos. Sci., 4 111 (2020). https://doi.org/10.3390/JCS4030111

    Article  CAS  Google Scholar 

  119. Li, Y, Li, S, Zhang, Y, Yu, M, Liu, J, “Enhanced Protective Zn–Al Layered Double Hydroxide Film Fabricated on Anodized 2198 Aluminum Alloy.” J. Alloys Compd., 630 29–36 (2015)

    Article  CAS  Google Scholar 

  120. Dong, Y, Ma, L, Zhou, Q, “Effect of the Incorporation of Montmorillonite-Layered Double Hydroxide Nanoclays on the Corrosion Protection of Epoxy Coating.” J. Coat. Technol. Res., 10 909–921 (2013)

    Article  CAS  Google Scholar 

  121. Chhetri, S, Samanta, P, Murmu, NC, Kuila, T, “Anticorrosion Properties of Epoxy Composite Coating Reinforced by Molybdate-Intercalated Functionalized Layered Double Hydroxide.” J. Compos. Sci., 3 (1) 11 (2019)

    Article  CAS  Google Scholar 

  122. Zheludkevich, ML, Poznyak, SK, Rodrigues, LM, Raps, D, Hack, T, Dick, LF, Nunes, T, Ferreira, MGS, “Active Protection Coatings with Layered Double Hydroxide Nanocontainers of Corrosion Inhibitor.” Corros. Sci., 52 (2) 602–611 (2010)

    Article  CAS  Google Scholar 

  123. Li, D, Wang, F, Yu, X, Wang, J, Liu, Q, Yang, P, He, Y, Wang, Y, Zhang, M, “Anticorrosion Organic Coating with Layered Double Hydroxide Loaded with Corrosion Inhibitor of Tungstate.” Prog. Org. Coat., 71 (3) 302–309 (2011)

    Article  CAS  Google Scholar 

  124. Alibakhshi, E, Ghasemi, E, Mahdavian, M, Ramezanzadeh, B, “Fabrication and Characterization of Layered Double Hydroxide/Silane Nanocomposite Coatings for Protection of Mild Steel.” J. Taiwan Inst. Chem. Eng., 80 924–934 (2017)

    Article  CAS  Google Scholar 

  125. Dong, Y, Wang, F, Zhou, Q, “Protective Behaviors of 2-Mercaptobenzothiazole Intercalated Zn–Al-layered Double Hydroxide Coating.” J. Coat. Technol. Res., 11 (5) 793–803 (2014)

    Article  CAS  Google Scholar 

  126. de Luna, MS, Buonocore, GG, Giuliani, C, Messina, E, Carlo, GD, Lavorgna, M, Ambrosio, L, Ingo, GM, “Long-Lasting Efficacy of Coatings for Bronze Artwork Conservation: The Key Role of Layered Double Hydroxide Nanocarriers in Protecting Corrosion Inhibitors from Photodegradation.” Angew. Chem. Int. Ed. Engl., 57 (25) 7380–7384 (2018)

    Article  CAS  Google Scholar 

  127. Hayatdavoudi, H, Rahsepar, M, “Smart Inhibition Action of Layered Double Hydroxide Nanocontainers in Zinc-Rich Epoxy Coating for Active Corrosion Protection of Carbon Steel Substrate.” J. Alloys Compd., 711 560–567 (2017)

    Article  CAS  Google Scholar 

  128. Wang, X, Li, L, Xie, ZH, Yu, G, “Duplex Coating Combining Layered Double Hydroxide and 8-Quinolinol Layers on Mg Alloy for Corrosion Protection.” Electrochim. Acta, 283 1845–1857 (2018)

    Article  CAS  Google Scholar 

  129. Anjum, MJ, Zhao, JM, Asl, VZ, Malik, MU, Yasin, G, Khan, WQ “Green Corrosion Inhibitors Intercalated Mg: Al Layered Double Hydroxide Coatings to Protect Mg Alloy.” Rare Met. 40 2254–2265 (2021)

  130. Hang, TTX, Truc, TA, Duong, NT, Pébère, N, Olivier, MG, “Layered Double Hydroxides as Containers of Inhibitors in Organic Coatings for Corrosion Protection of Carbon Steel.” Prog. Org. Coat., 74 (2) 343–348 (2012)

    Article  CAS  Google Scholar 

  131. Song, Y, Tang, Y, Fang, L, Wu, F, Zeng, XG, Hu, J, Zhang, SF, Jiang, B, Luo, HJ, “Enhancement of Corrosion Resistance of AZ31 Mg Alloys by One-step In Situ Synthesis of ZnAl-LDH Films Intercalated with Organic Anions (ASP, La).” J. Magnes. Alloy., 9 (2) 658–667 (2021)

    Article  CAS  Google Scholar 

  132. Cao, Y, Zheng, D, Li, X, Lin, J, Wang, C, Dong, S, Lin, C, “Enhanced Corrosion Resistance of Superhydrophobic Layered Double Hydroxide Films with Long-Term Stability on Al Substrate.” ACS Appl. Mater. Interfaces, 10 (17) 15150–15162 (2018)

    Article  CAS  Google Scholar 

  133. Wen, T, Yan, R, Wang, N, Li, Y, Chen, T, Ma, H, "PPA-Containing Layered Double Hydroxide (LDH) Films for Corrosion Protection of a Magnesium Alloy." Surf. Coat. Tech. 383 125255 (2020)

    Article  CAS  Google Scholar 

  134. Zhang, C, Luo, X, Pan, X, Liao, L, Wu, X, Liu, Y, “Self-healing Li-Al Layered Double Hydroxide Conversion Coating Modified with Aspartic Acid for 6N01 Al Alloy.” Appl. Surf. Sci., 394 275–281 (2017)

    Article  CAS  Google Scholar 

  135. Lin, K, Luo, X, Pan, X, Zhang, C, Liu, Y, “Enhanced Corrosion Resistance of LiAl-Layered Double Hydroxide (LDH) Coating Modified with a Schiff Base Salt on Aluminum Alloy by One Step In-situ Synthesis at Low Temperature.” Appl. Surf. Sci., 463 1085–1096 (2019)

    Article  CAS  Google Scholar 

  136. Stimpfling, T, Leroux, F, Hintze-Bruening, H, “Organo-Modified Layered Double Hydroxide in Coating Formulation to Protect AA2024 from Corrosion.” Colloids Surf. A Physicochem. Eng. Asp., 458 147–154 (2014)

    Article  CAS  Google Scholar 

  137. Subasri, R, Raju, KRCS, Reddy, DS, Jyothirmayi, A, Ijeri, VS, Prakash, O, Gaydos, SP, “Environmentally Friendly Zn–Al Layered Double Hydroxide (LDH)-Based Sol–Gel Corrosion Protection Coatings on AA 2024–T3.” J. Coat. Technol. Res., 16 (5) 1447–1463 (2019)

    Article  CAS  Google Scholar 

  138. Aghaziarati, M, Yamini, Y, Shamsayei, M, “An Electrodeposited Terephthalic Acid-Layered Double Hydroxide (Cu-Cr) Nanosheet Coating for In-tube Solid-Phase Microextraction of Phthalate Esters.” Microchim. Acta, 187 (2) 1–10 (2020)

    Article  CAS  Google Scholar 

  139. Du, P, Qiu, S, Liu, C, Liu, G, Zhao, H, Wang, L, “In situ Polymerization of Sulfonated Polyaniline in Layered Double Hydroxide Host Matrix for Corrosion Protection.” New J. Chem., 42 (6) 4201–4209 (2018)

    Article  CAS  Google Scholar 

  140. Wu, W, Sun, X, Zhu, CL, Zhang, F, Zeng, RC, Zou, YH, Li, SQ, “Biocorrosion Resistance and Biocompatibility of Mg–Al Layered Double Hydroxide/POLY-L-glutamic Acid Hybrid Coating on Magnesium Alloy AZ31.” Prog. Org. Coat., 147 105746 (2020)

  141. Zeng, RC, Li, XT, Liu, ZG, Zhang, F, Li, SQ, Cui, HZ, “Corrosion Resistance of Zn–Al Layered Double Hydroxide/Poly(lactic acid) Composite Coating on Magnesium Alloy AZ31.” Front. Mater. Sci., 9 (4) 355–365 (2015)

    Article  Google Scholar 

  142. Cao, K, Yu, Z, Zhu, L, Yin, D, Chen, L, Jiang, Y, Wang, J “Fabrication of Superhydrophobic Layered Double Hydroxide Composites to Enhance the Corrosion-Resistant Performances of Epoxy Coatings on Mg Alloy.” Surf. Coat. Tech., 407 126763 (2021)

  143. Yao, QS, Zhang, F, Song, L, Zeng, RC, Cui, LY, Li, SQ, Wang, ZL, Han, EH, “Corrosion Resistance of a Ceria/Polymethyltrimethoxysilane Modified Mg-Al-Layered Double Hydroxide on AZ31 Magnesium Alloy.” J. Alloys Compd., 764 913–928 (2018)

    Article  CAS  Google Scholar 

  144. Cao, Y, Zheng, D, Luo, J, Zhang, F, Wang, C, Dong, S, Ma, Y, Liang, Z, Lin, C, “Enhanced Corrosion Protection by Al Surface Immobilization of In-situ Grown Layered Double Hydroxide Films Co-intercalated with Inhibitors and Low Surface Energy Species.” Corros. Sci., 164 108340 (2020)

    Article  CAS  Google Scholar 

  145. Syu, JH, Uan, JY, Lin, MC, Lin, ZY, “Optically Transparent Li–Al–CO3 Layered Double Hydroxide Thin Films on an AZ31 Mg Alloy Formed by Electrochemical Deposition and Their Corrosion Resistance in a Dilute Chloride Environment.” Corros. Sci., 68 238–248 (2013)

    Article  CAS  Google Scholar 

  146. Zhang, F, Zhang, C, Zeng, R, Song, L, Guo, L, Huang, X, “Corrosion Resistance of the Superhydrophobic Mg(OH)2/Mg-Al Layered Double Hydroxide Coatings on Magnesium Alloys.” Met., 6 (4) 85 (2016)

    CAS  Google Scholar 

  147. Yao, QS, Li, ZC, Qiu, ZM, Zhang, F, Chen, XB, Chen, DC, Guan, SK, Zeng, RC, “Corrosion Resistance of Mg(OH)2/Mg–Al-Layered Double Hydroxide Coatings on Magnesium Alloy AZ31: Influence of Hydrolysis Degree of Silane.” Rare Met., 38 (7) 629–641 (2019)

    Article  CAS  Google Scholar 

  148. Wang, ZH, Zhang, JM, Yan, LI, Bai, LJ, Zhang, GJ, “Enhanced Corrosion Resistance of Micro-Arc Oxidation Coated Magnesium Alloy by Superhydrophobic Mg−Al Layered Double Hydroxide Coating.” Trans. Nonferrous Met. Soc. China, 29 (10) 2066–2077 (2019)

    Article  CAS  Google Scholar 

  149. Li, H, Peng, F, Wang, D, Qiao, Y, Xu, D, Liu, X, “Layered Double Hydroxide/Poly-dopamine Composite Coating with Surface Heparinization on Mg Alloys: Improved Anticorrosion, Endothelialization and Hemocompatibility.” Biomater. Sci., 6 (7) 1846–1858 (2018)

    Article  CAS  Google Scholar 

  150. Kalali, EN, Wang, X, Wang, DY, “Functionalized Layered Double Hydroxide-Based Epoxy Nanocomposites with Improved Flame Retardancy and Mechanical Properties.” J. Mater. Chem. A, 3 (13) 6819–6826 (2013)

    Article  CAS  Google Scholar 

  151. Kalali, EN, Wang, X, Wang, DY, “Synthesis of Fe3O4 Nano-Sphere@MgAl Layered Double Hydroxide Hybrid and Application in Fabricating Multifunctional Epoxy Nanocomposites.” Ind. Eng. Chem. Res., 55 (23) 6634–6664 (2016)

    Article  CAS  Google Scholar 

  152. Shanmuganathan, K, Ellison, CJ, “Layered Double Hydroxides: An Emerging Class of Flame Retardants.” In: Papaspyrides, CD, Kiliaries, P, (eds.) Polymer Green Flame Retardants. pp. 675–707. Elsevier (2017)

  153. Jiang, SD, Bai, ZM, Tang, G, Song, L, Stec, AA, Hull, TR, Hu, Y, Hu, WZ, “Synthesis of Mesoporous Silica@Co−Al Layered Double Hydroxide Spheres: Layer-by-Layer Method and Their Effects on the Flame Retardancy of Epoxy Resins.” ACS Appl. Mater. Interfaces, 6 (16) 14076–14086 (2014)

    Article  CAS  Google Scholar 

  154. Becker, CM, Gabbardo, AD, Wypych, F, Amico, SC, “Mechanical and Flame-Retardant Properties of Epoxy/Mg–Al LDH Composites.” Compos. PART A-Appl. Sci. Manuf., 42 (2) 196–202 (2011)

    Article  CAS  Google Scholar 

  155. Guo, S, Zhang, C, Peng, H, Wang, W, Liu, T, “Structural Characterization, Thermal and Mechanical Properties of Polyurethane/CoAl Layered Double Hydroxide Nanocomposites Prepared via In Situ Polymerization.” Compos. Sci. Technol., 71 (6) 791–796 (2011)

    Article  CAS  Google Scholar 

  156. Kong, Q, Wu, T, Tang, Y, Xiong, L, Liu, H, Zhang, J, Guo, R, Zhang, F, “Improving Thermal and Flame Retardant Properties of Epoxy Resin with Organic NiFe-Layered Double Hydroxide-Carbon Nanotubes Hybrids.” Chin. J. Chem., 35 (12) 1–6 (2017)

    Article  CAS  Google Scholar 

  157. Liu, Y, Gao, Y, Wang, Q, Lin, W, “Synergistic Effect of Layered Double Hydroxides with Other Flame Retardant Additives for Polymer Nanocomposites: A Critical Review.” Dalton Trans., 47 14827–14840 (2018)

    Article  CAS  Google Scholar 

  158. Kaul, PK, Samson, AJ, Selvan, GT, Enoch, IVMV, Selvakumar, PM, “Synergistic Effect of LDH in the Presence of Organophosphate on Thermal and Flammable Properties of an Epoxy Nanocomposite.” Appl. Clay Sci., 135 234–243 (2017)

    Article  CAS  Google Scholar 

  159. Mahdavi, R, Goodarzi, V, Ali Khonakdar, H, Hassan Jafari, S, Reza Saeb, M, Shojaei, S, “Experimental Analysis and Prediction of Viscoelastic Creep Properties of PP/EVA/LDH Nanocomposites Using Master Curves Based on Time–Temperature Superposition.” J. Appl. Polym. Sci., 135 46725 (2018). https://doi.org/10.1002/APP.46725.

    Article  CAS  Google Scholar 

  160. Rastin, H, Saeb, MR, Nonahal, M, Shabanian, M, Vahabi, H, Formela, K, Gabrion, X, Seidi, F, Zarrintaj, P, Sari, MG, Laheurte, P, “Transparent Nanocomposite Coatings Based on Epoxy and Layered Double Hydroxide: Nonisothermal Cure Kinetics and Viscoelastic Behavior Assessments.” Prog. Org. Coat., 113 126–135. https://doi.org/10.1016/J.PORGCOAT.2017.09.003 (2017)

    Article  CAS  Google Scholar 

  161. Karami, Z, Ganjali MR, Dehaghani MZ, Aghazadeh M, Jouyandeh M, Esmaeili A, Habibzadeh S, Mohaddespour A, Inamuddin, Formela K, Haponiuk, JY, Saeb MR “Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides.” Polymers, 12 (2020) 1157. https://doi.org/10.3390/POLYM12051157

    Article  Google Scholar 

  162. Li, C, Wan, J, Fan, H, Wang, DY, “Synthesis and Characterization of Functional Eugenol Derivative Based Layered Double Hydroxide and Its Use as Nano Flame-Retardant in Epoxy Resin.” J. Mater. Chem. A, 3 3471–3479 (2015)

    Article  CAS  Google Scholar 

  163. Pan, H, Wang, W, Shen, Q, Pan, Y, Song, L, Hu, Y, Lu, Y, “Fabrication of Flame Retardant Coating on Cotton Fabric by Alternate Assembly of Exfoliated Layered Double Hydroxides and Alginate.” RSC Adv., 6 111950 (2016)

  164. Norouzi, M, Zare, Y, Kiany, P, “Nanoparticles as Effective Flame Retardants for Natural and Synthetic Textile Polymers: Application, Mechanism, and Optimization.” Polym. Rev., 55 (3) 1–30 (2015)

    Article  CAS  Google Scholar 

  165. Chu, F, Xu, Z, Mu, X, Cai, W, Zhou, X, Hu, W, Song, L, “Construction of Hierarchical Layered Double Hydroxide/ Poly(dimethylsiloxane) Composite Coatings on Ramie Fabric Surfaces for Oil/Water Separation and Flame Retardancy.” Cellulose, 27 3485–3499 (2020)

    Article  CAS  Google Scholar 

  166. Wang, Z, Shen, X, Qian, T, Xu, K, Sun, Q, Jin, C, “Fabrication of Superhydrophobic Mg/Al Layered Double Hydroxide (LDH) Coatings on Medium Density Fiberboards (MDFs) with Flame Retardancy.” Materials, 11 (7) 1113 (2018)

    Article  CAS  Google Scholar 

  167. Li, YC, Yang, YH, Shields, JR, Davis, RD, “Layered Double Hydroxide-Based Fire-Resistant Coatings for Flexible Polyurethane Foam.” Polymer, 56 284–292 (2015)

    Article  CAS  Google Scholar 

  168. Yu, J, Buffet, JC, O’Hare, D, “Aspect Ratio Control of Layered Double Hydroxide Nanosheets and Their Application for High Oxygen Barrier Coating in Flexible Food Packaging.” ACS Appl. Mater. Interfaces, 12 (9) 10973–10982 (2020)

    Article  CAS  Google Scholar 

  169. Madhusha, C, Munaweera, I, Karunaratne, V, Kottegoda, N, “Facile Mechanochemical Approach to Synthesizing Edible Food Preservation Coatings Based on Alginate/Ascorbic Acid-Layered Double Hydroxide Bio-Nanohybrids.” J. Agric. Food Chem., 68 (33) 8962–8975 (2020)

    Article  CAS  Google Scholar 

  170. Han, J, Dou, Y, Wei, M, Evans, DG, Duan, X, “Antireflection/Antifogging Coatings Based on Nanoporous Films Derived from Layered Double Hydroxide.” Chem. Eng. J., 169 (1–3) 371–378 (2011)

    Article  CAS  Google Scholar 

  171. Vulic, T, Rudic, O, Vucetic, S, Lazar, D, Ranogajec, J, “Photocatalytic Activity and Stability of TiO2/ZnAl Layered Double Hydroxide Based Coatings on Mortar Substrates.” Cem. Concr. Compos., 58 50–58 (2015)

    Article  CAS  Google Scholar 

  172. Iqbal, MA, Asghar, H, Fedel, M, “Double Doped Cerium-Based Superhydrophobic Layered Double Hydroxide Protective Films Grown on Anodic Aluminium Surface.” J. Alloys Compd., 844 156112 (2020)

  173. Lu, H, Chen, J, Tian, Q, “Wearable High-Performance Supercapacitors Based on Ni-coated Cotton Textile with Low-Crystalline Ni-Al Layered Double Hydroxide Nanoparticles.” J. Colloid Interface Sci., 513 342–348 (2018)

    Article  CAS  Google Scholar 

  174. Qi, J, Chen, Y, Li, Q, Sui, Y, He, Y, Meng, Q, Wei, F, Ren, Y, Liu, J, “Hierarchical NiCo Layered Double Hydroxide on Reduced Graphene Oxide-Coated Commercial Conductive Textile for Flexible High-Performance Asymmetric Supercapacitors.” J. Power Sources, 445 227342 (2020)

  175. Xie, Y, Gu, YH, Meng, J, Yan, X, Chen, Y, Guo, XJ, Lang, WZ, “Ultrafast Separation of Oil/Water Mixtures with Layered Double Hydroxide Coated Stainless Steel Meshes (LDH-SSMs)." J. Hazard. Mater., 398 122862 (2020)

    Article  CAS  Google Scholar 

  176. Zhang, X, Guo, Lu, Wang, Y, Ruan, C, “Removal of Oxygen Demand and Nitrogen Using Different Particle-Sizes of Anthracite Coated with NINE Kinds of LDHs for Wastewater Treatment.” Sci. Rep., 5 15146 (2015)

  177. Yu, X, Wen, T, Cao, P, Shan, L, Li, L, “Alginate-Chitosan Coated Layered Double Hydroxide Nanocomposites for Enhanced Oral Vaccine Delivery.” J. Colloid Interface Sci., 556 258–265 (2019)

    Article  CAS  Google Scholar 

  178. Peng, F, Wang, D, Tian, Y, Cao, H, Qiao, Y, Liu, X, “Sealing the Pores of PEO Coating with Mg-Al Layered Double Hydroxide: Enhanced Corrosion Resistance, Cytocompatibility and Drug Delivery Ability.” Sci. Rep., 7 (1) 1–12 (2017)

    CAS  Google Scholar 

  179. Zhang, F, Zhang, CL, Song, L, Zeng, RC, Cui, LY, Cui, HZ, “Corrosion Resistance of Superhydrophobic Mg–Al Layered Double Hydroxide Coatings on Aluminum Alloys.” Acta Metall. Sin-Engl., 28 (11) 1373–1381 (2015)

    Article  CAS  Google Scholar 

  180. Chen, C, Gunawan, P, Lou, XW, Xu, R, “Silver Nanoparticles Deposited Layered Double Hydroxide Nanoporous Coatings with Excellent Antimicrobial Activities.” Adv. Funct. Mater., 22 (4) 780–787 (2012)

    Article  CAS  Google Scholar 

  181. Chu, F, Xu, Z, Mu, X, Cai, W, Zhou, X, Hu, W, Song, L, “Construction of Hierarchical Layered Double Hydroxide/Poly(dimethylsiloxane) Composite Coatings on Ramie Fabric Surfaces for Oil/Water Separation and Flame Retardancy.” Cellulose, 27 (6) 3485–3499 (2020)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Polymer and Surface Engineering, Institute of Chemical Technology, Mumbai, Maharashtra, India

    Ameya Jagtap, Pareena G. Wagle, Ekta Jagtiani & Aarti P. More

Authors
  1. Ameya Jagtap
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pareena G. Wagle
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ekta Jagtiani
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Aarti P. More
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aarti P. More.

Ethics declarations

Conflict of interest

All authors certify that they have no affiliations with or involvement in any organization or entity with any financial interest or nonfinancial interest in the subject matter or materials discussed in this manuscript.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jagtap, A., Wagle, P.G., Jagtiani, E. et al. Layered double hydroxides (LDHs) for coating applications. J Coat Technol Res 19, 1009–1032 (2022). https://doi.org/10.1007/s11998-022-00624-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-022-00624-y

Keywords

Search

Navigation