Abstract
The incorporation of nanoparticles (NPs) into textile fabrics can transform ordinary products to endow the new functional characteristics owing to their interesting surface characteristics. The surface functionalization of NPs can play a key role in controlling the colloidal stability followed by interactions between substrate and NPs leading to enhanced functional characteristics. Here, the synthesis of ZnO NPs was carried out through hydrothermal method. The surface of NPs was modified using silanol and tertiary amine-based coupling agents. The functionalized NPs were characterized using zeta potential, size distribution, XRD, EDX, and FTIR. The size of prepared NPs was observed as 34 nm. The disperse stability of functionalized NPs was studied by varying the concentration of coupling agent and assessed through the ultraviolet protection factor (UPF) and antibacterial activity of the fabrics treated with functionalized NPs. The functionalized NPs exhibited stable dispersion with higher zeta potential and have a smaller size. A significant improvement in the UPF value and antibacterial activity of treated cotton fabrics was observed.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
Rivero, PJ, Urrutia, A, Goicoechea, J, Arregui, FJ, “Nanomaterials for Functional Textiles and Fibers.” Nanoscale Res. Lett., 10 501 (2015)
Rimbu, C, Vrinceanu, N, Broasca, G, Farima, D, Ciocoiu, M, Campagne, C, Petruta, MS, Nistor, A, “Zinc Oxide Application in the Textile Industry: Surface Tailoring and Water Barrier Attributes as Parameters with Direct Implication in Comfort Performance.” Text. Res. J., 83 2142–2151 (2013)
Simoncic, B, Tomsic, B, “Structures of Novel Antimicrobial Agents for Textiles—A Review.” Text. Res. J., 80 1721–1737 (2010)
Marsalek, R, “Particle Size and Zeta Potential of ZnO.” APCBEE Procedia, 9 13–17 (2014)
Água, RB, Branquinho, R, Duarte, MP, Maurício, E, Fernando, AL, Martins, R, Fortunato, E, “Efficient Coverage of ZnO Nanoparticles on Cotton Fibres for Antibacterial Finishing Using a Rapid and Low Cost In Situ Synthesis.” New J. Chem., 42 1052–1060 (2018)
Sirelkhatim, A, Mahmud, S, Seeni, A, Kaus, NHM, Ann, LC, Bakhori, SKM, Hasan, H, Mohamad, D, “Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism.” Nano-Micro Lett., 7 219–242 (2015)
Pimentel, A, Ferreira, SH, Nunes, D, Calmeiro, T, Martins, R, Fortunato, E, “Microwave Synthesized ZnO Nanorod Arrays for UV Sensors: A Seed Layer Annealing Temperature Study.” Materials, 9 299–314 (2016)
Rafique, S, Kasi, AK, Aminullah, JK, Bokhari, M, Sha, Z, “Fabrication of Silver-doped Zinc Oxide Nanorods Piezoelectric Nanogenerator on Cotton Fabric to Utilize and Optimize the Charging System.” Nanomater. Nanotechnol., 10 1–12 (2020)
Hariharan, C, Appl. Catal. A Gen., 304 55 (2006)
Li, M, Liu, F, Wang, S, Cheng, X, Zhang, H, Huang, T, Liu, G, “Phototransformation of Zinc Oxide Nanoparticles and Coexisting Pollutant: Role of Reactive Oxygen Species.” Sci. Total Environ., 728 138335 (2020)
Neena, D, Kondamareddy, KK, Bin, H, Lu, D, Kumar, P, Dwivedi, RK, Pelenovich, VO, Zhao, X-Z, Gao, W, Fu, D, “Enhanced Visible Light Photodegradation Activity of RhB/MB from Aqueous Solution Using Nanosized Novel Fe-Cd Co-Modifed ZnO.” Sci. Rep., 8 10691 (2018)
Cao, G, Nanostructures and Nanomaterials: Synthesis, Properties & Applications. Imperial College Press, London (2004)
Birdi, KS, Handbook of Surface and Colloid Chemistry, 4th edn. CRC Press, Boca Raton (2015)
Chai, MHH, Amir, N, Yahya, N, Saaid, IM, “Characterization and Colloidal Stability of Surface Modified Zinc Oxide Nanoparticle.” J. Phys. Conf. Ser., 1123 012007 (2018)
Qiao, Z, Yao, Y, Song, S, Yin, M, Luo, J, “Silver Nanoparticles with pH Induced Surface Charge Switchable Properties for Antibacterial and Antibiofilm Applications.” J. Mater. Chem. B, 7 830–884 (2019)
Malvern Instruments. Zeta Potential: An Introduction in 30 min. Zetasizer Nano Serles Tech Note MRK654-01 2011; 2: 1–6.
Halbus, AF, Horozov, TS, Paunov, VN, “Surface-Modified Zinc Oxide Nanoparticles for Antialgal and Antiyeast Applications.” ACS Appl. Nano Mater., 3 440–451 (2020)
Zhang, D, Chen, L, Fang, D, Toh, GW, Yue, X, Chen, Y, Lin, H, “In Situ Generation and Deposition of Nano-ZnO on Cotton Fabric by Hyperbranched Polymer for Its Functional Finishing.” Text. Res. J., 83 1625–1633 (2013)
Ying, KL, Hsieh, TE, Hsieh, YF, “Colloidal Dispersion of Nano-Scale ZnO Powders Using Amphibious and Anionic Polyelectrolytes.” Ceram. Int., 35 1165–1171 (2009)
Água, RB, Branquinho, R, Duarte, MP, Maurício, E, Fernando, AL, Martins, R, Fortunato, E, “Efficient Coverage of ZnO Nanoparticles on Cotton Fibres for Antibacterial Finishing Using a Rapid and Low Cost In Situ Synthesis.” New J. Chem., 42 1052–1060 (2018)
Baddar, ZE, Matocha, CJ, Unrine, JM, “Surface coating effects on the sorption and dissolution of ZnO nanoparticles in soil.” Environ. Sci. Nano, 6 2495–2507 (2019)
Verbi, A, Gorjanc, M, Simon, B, “Zinc Oxide for Functional Textile Coatings: Recent Advances.” Coatings, 9 550 (2019)
Mousa, MA, Khairy, M, “Synthesis of Nano-Zinc Oxide with Different Morphologies and Its Application on Fabrics for UV Protection and Microbe-Resistant Defense Clothing.” Tex. Res. J., 90 2492–2503 (2020)
Pal, S, Mondal, S, Maity, J, “Synthesis, Characterization and Photocatalytic Properties of ZnO Nanoparticles and Cotton Fabric Modified with ZnO Nanoparticles via In-situ Hydrothermal Coating Technique: Dual Response.” Mater. Technol., 14 884–891 (2018)
Shaban, M, Mohamed, F, Abdallah, S, “Production and Characterization of Superhydrophobic and Antibacterial Coated Fabrics Utilizing ZnO Nanocatalyst.” Sci. Rep., 8 2925 (2018)
Aneesh, PM, Vanaja, KA, Jayaraj, MK, “Synthesis of ZnO Nanoparticles by Hydrothermal Metho.” Proc. SPIE 6639, Nanophotonic Materials IV, 66390J (2007).
Ahmed, D, Osman, M, Mustafa, MA, “Synthesis and Characterization of Zinc Oxide Nanoparticles using Zinc Acetate Dihydrate and Sodium Hydroxide.” J. Nanosci. Nanoeng., 1 248–251 (2015)
Meulenkamp, EA, “Synthesis and Growth of ZnO Nanoparticles.” J. Phys. Chem. B, 5647 5566 (1998)
Hong, R, Pan, T, Qian, J, Li, H, “Synthesis and Surface Modification of ZnO Nanoparticles.” Chem. Eng. J., 119 71–81 (2006)
Gopi, D, Kavitha, L, Rajeswari, D, Handbook of Nanoparticles. Synthesis of Pure and Substituted Hydroxyapatite Nanoparticles by Cost Effective Facile Methods, 4th edn. Springer, Cham, pp. 167–190 (2016)
Kolodziejczak-Radzimska, A, Jesionowski, AT, “Zinc Oxide—From Synthesis to Application: A Review.” Materials, 7 2833–2881 (2014)
Riaz, S, Rehman, A, Ashraf, A, Hussain, T, Hussain, TM, “Development of Functional Alginate Fibers for Medical Applications.” J. Text., I (108) 2197–2204 (2017)
Siddiqi, KS, Rahman, A, Tajuddin, T, Husen, A, “Properties of Zinc Oxide Nanoparticles and Their Activity Against Microbe.” Nanoscale Res. Lett., 13 141 (2018)
Riaz, S, Ashraf, M, Hussain, T, Hussain, MT, “Modification of Silica Nanoparticles to Develop Highly Durable Superhydrophobic and Antibacterial Cotton Fabrics.” Cellulose, 8 5159–5175 (2019)
Riaz, S, Ashraf, M, Hussain, T, Hussain, MT, Younus, A, “Fabrication of Robust Multifaceted Textiles by Application of Functionalized TiO2 Nanoparticles.” Colloids Surf. Physicochem. Eng. Aspects, 581 123799 (2019)
Acknowledgments
Grant for this research work was provided by the Higher Education Commission of Pakistan [NRPU Grant No. 6074].
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Munir, M.U., Ashraf, M., Abid, H.A. et al. Coating of modified ZnO nanoparticles on cotton fabrics for enhanced functional characteristics. J Coat Technol Res 19, 467–475 (2022). https://doi.org/10.1007/s11998-021-00533-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-021-00533-6