Abstract
Dirt pick-up is a long-standing issue for exterior architectural coatings. Dirt pick-up resistance (DPR) is highly sought by end users, and significant resources have been committed by paint manufacturers to improve it. The task is complicated by the multitude of regional and local factors such as seasonal weather, intensity of economic activity, or atmospheric particle burden. Typically, paint manufacturers try to control DPR via careful selection of additives and formula optimization. Testing the new formulas in real time is long and, therefore, there is a clear need for a faster and more reliable test that takes into account the key elements of the dirt pick-up mechanism: particle transport, adhesion, and release to/from the surface. Our team has developed an accelerated test that focuses on thermally driven adhesion and takes a fraction of the time necessary for outdoor exposure testing. The test correlates well with early outdoor exposure results when formulation parameters are controlled and when there are moderate-to-large performance differences among paint formulas. The test was used to improve the accelerated DPR of a paint formula, which subsequently was verified against real-time outdoor exposure in three geographic regions with different climates and airborne particulate pollution levels.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
Vyorkka, J, Vandezande, G, Salminen, P, Ruh, B, Fogden, A, Corkery, R, “Hydrophobic Coatings.” US 2008/02452273
Huang, Y, Wang, D, Huang, Q, “Solar Reflectance Coating.” WO201329252 (2013)
Huang, Q, Rokowski, JM, Zhang, Y, “Infrared Reflective Coating Compositions.” US Patent Application 2012121886, 2012
Denotta, HT, Chia-Chen, L, Verona, JL, “Aqueous Coating Compositions.” US Patent Application 2012129974A1, 2012
Hanrahan K, Wood K, Hedhli L, Gupta R, Skilton W, “Highly Weatherable Roof Coatings Containing Aqueous Fluoropolymer Dispersions.” US Patent 7803867 B2, 2010
Zheng, M, Amin-Sanayei, R, Li, Q, Du, A, “Stable Aqueous Fluoropolymer Coating Composition.” WO2016003748 A1, 2016
Mitina, V, Peter, W, “Modified Silica Particles and Dirt Repellent Polymer Compositions Comprising Them.” US Patent Application 2010288963 A1, 2010
Peter, W, Schacht, HT, Mitina, VK, Lamatsch, B, Powell, K, “Compositions with Improved Dirt Pickup Resistance Comprising Layered Double Hydroxide Particles.” WO201122175 (2011)
Balk, R, Dersch, R, Roller, S, Schuler, B, “Organic-Inorganic Composite Particles.” US Patent Application 2012142850 A1, 2012
Muehlebach, A, Muehlebach, M, Muehlebach, F, Rime, F, Peter, W, Powell, K, “Aqueous Emulsion Polymers, Their Preparation and Use.” US Patent 9150732B2, 2015
Chailloux, L, Clamen, G, Greyson, EC, Haigh, J, Pollet, B, “Durable Aqueous Compositions for Use in Making Traffic Markings Having Good Dirt Pickup Resistance and Traffic Markings Made Therewith.” US 2016/0319501 A1
Li, S, Gu, G, Zhou, S, “Dependence of Dirt Resistance of Steel Topcoats on Their Surface Characteristics.” J. Coat. Technol. Res., 10 (3) 339–346 (2013)
Khanjani, J, Pazokifard, S, Zohuriaan-Mehr, MJ, “Improving Dirt Pickup Resistance in Waterborne Coatings Using Latex Blends of Acrylic/PDMS Polymers.” Prog. Org. Coat., 102 151–166 (2017)
Zhou, S, Yang, Y, Wang, T, Chen, H, Bohling, J, Maurice, AM, Wu, L, “A Novel Adsorption Method to Simulate the Dirt Pickup Performance of Organic Coatings.” J. Coat. Technol. Res., 15 (1) 175–184 (2018)
G Monahan, Proc. Future Coat! Symposium, Chicago, IL, Oct. 2008
Zahn, F, Zheng, B, Hua, Z, Li, Y, Yang, Y, “Shelf-Stable Aqueous Compositions and Process of Making the Same.” WO2017/054156A1
Lauer, RP, Evan, RC, Grecian, DS, Solomon, RD, “Polymeric Nanoparticle Formulations and Their Use for Improving Dirt Pick-up Resistance of a Coating.” US Patent 7,138,438 B2, 2006
Wagner, O, Baumstark, R, “How to Control Dirt Pick-up of Exterior Coatings.” Macromol. Symp., 187 447 (2002)
Smith, A, Wagner, O, “Factors Affecting Dirt Pick-up in Latex Coatings.” J. Coat. Technol., 68 862 (1996)
Jie, H, Dongnan, W, “Method for Rapidly Detecting Film Coating Stain Resistance of Emulsion Paint.” CN Patent 103018212B, 2016
Wang, L, Zhu, X, Xiong, S, Tang, L, Gao, J, Gu, M, Wang, X, Liu, Y, Lin, Y, Wang, Y, Ma, X, Tian, H, Sun, Y, “Modified Silica Sol and Purpose Thereof.” CN Patent 104844792B, 2017
Xuanyi, L, “Dirt Pickup on Latex Paint Films.” European Coatings Journal, editorial Dec 01, 2002
Brown, SC, Diebold, MP, Kraiter, DC, Jernakoff, P, Velez, CA, “Process and Apparatus for Quantifying Solid Residue on a Substrate.” US Patent Application 62933712, 2020
Loera-Toledo, F, Kraiter, DC, “Evaluation of Dirt Pickup Resistance (DPR) in Exterior Architectural Paints: Global Paint Benchmark Results and Analysis.” Proc. Abrafati International Coatings Congress, Sao Paulo, Brazil, October 2019
Brown, SC, Diebold, MP, Kraiter, DC, Velez, CA, Jernakoff, P, “Towards a Comprehensive Understanding of DPR.” JCT CoatingsTech, 17 (6) 31–43 (2020)
World Air Pollution: Real-time Air Quality Index, www.waqi.com
Diebold, MP, Kraiter, DC, “Effect of Exposure Conditions on Dirt Pickup Resistance.” J. Coat. Technol. Res., 17 (3) 597–611 (2020)
Holbrow, GL, “Soiling of Paint Films.” Paint Research Association, June 1981
ASTM D3363-00 Standard Test Method for Film Hardness by Pencil Test
Patton, TC, Paint Flow and Pigment Dispersion. Wiley (1979)
Acknowledgments
The authors acknowledge the skillful contribution of Roman Larichev for the synthesis of polymeric binders used in this study, the thorough expertise of Carlos Velez and Kenneth Tarburton in setting up and running the accelerated DPR testing device, and Felipe Loera-Toledo for enabling paint making and testing in Mexico City.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kraiter, D.C., Brown, S.C., Diebold, M.P. et al. Development of an accelerated test method for dirt pick-up resistance. J Coat Technol Res 18, 1413–1430 (2021). https://doi.org/10.1007/s11998-021-00506-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-021-00506-9