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Synthesis and properties of phosphorus-containing cardanol-based acrylates for flame-retardant UV/EB-cured coatings

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Abstract

In this article, two kinds of phosphorus-containing cardanol-based acrylates were designed and synthesized. Firstly, a pre-polymer (PT-HCE) with three arms was synthesized using hydroxyethyl cardanol ether (HCE) and phosphorus oxychloride (POCl3) as raw materials. Then, the PT-HCE was acrylated to synthesize phosphate tris-hydroxyethyl cardanol epoxy acrylate resin (AEPT-HCE) and phosphate tris-hydroxyethyl cardanol photosensitive resin (APT-HCE). The structures of PT-HCE, AEPT-HCE and APT-HCE were characterized and the results showed that the photosensitive resins were successfully synthesized. In addition, AEPT-HCE and APT-HCE were used to prepare the flame-retardant UV/EB curing coatings. The properties of the coatings were tested, and the results revealed that different structures have a certain effect on Tg and tensile properties of the coatings. The cured films demonstrated excellent flame-retardant properties, showing flammability rating of V-0 in UL-94 test.

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Authors and Affiliations

  1. International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, People’s Republic of China

    Zhuoyuan Gu, Yinpeng Nan, Yue Zhang, Jiafeng Huang & Jingcheng Liu

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  1. Zhuoyuan Gu
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Gu, Z., Nan, Y., Zhang, Y. et al. Synthesis and properties of phosphorus-containing cardanol-based acrylates for flame-retardant UV/EB-cured coatings. J Coat Technol Res 18, 1353–1364 (2021). https://doi.org/10.1007/s11998-021-00500-1

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