Abstract
Inspired by fish scales, superhydrophilic and underwater superoleophobic alumina membranes were fabricated in this study. Dopamine deposited on the surface of alumina membranes through immersion over time, and then crosslinking reaction occurred with polyethyleneimine (PEI), which was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. It induced the modified layer coated on the membrane surface. Values of water contact angle of the modified alumina membranes were ~ 0° in air. Values of underwater oil contact angle reached 155°, which indicated it was superhydrophilic and underwater superoleophobic. More particles engendered with the increase in the reaction time with PEI, which induced the decrease in the pore sizes and permeation flux. All values of oil rejection were higher than 98.5%. No obvious deterioration of permeation flux could be found. The rejection hardly suffered a sharp decline over 800 min. It indicates that the modified layer can firmly stick to the alumina membranes. Therefore, the as-prepared alumina membrane is promising for practical oil/water separation.
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Shannon, MA, Bohn, PW, Elimelech, M, Georgiadis, JG, Mariñas, BJ, Mayes, AM, “Science and Technology for Water Purification in the Coming Decades.” Nature, 452 (7185) 301–310 (2008)
Stokstad, E, “Looking Beyond the Spill, Obama Highlights Long-Term Restoration.” Science, 328 (5986) 1618–1619 (2010)
Li, R, Zhang, G, Wang, J, Li, J, Zhang, C, Wang, P, “Superwetting pH-Responsive Polyaniline Coatings: Toward Versatile Separation of Complex Oil–Water Mixtures.” Langmuir, 36 760–768 (2020)
Zhang, H, Shen, Y, Li, M, Zhu, G, Feng, H, Li, J, “Egg Shell Powders-Coated Membrane for Surfactant-Stabilized Crude Oil-in-Water Emulsions Efficient Separation.” ACS Sustain. Chem. Eng., 7 10880–10887 (2019)
Zhang, W, Liu, N, Cao, Y, Chen, Y, Xu, L, Lin, X, Feng, L, “A Solvothermal Route Decorated on Different Substrates: Controllable Separation of an Oil/Water Mixture to a Stabilized Nanoscale Emulsion.” Adv. Mater., 27 (45) 7349–7355 (2015)
Oh, S, Ki, S, Ryu, S, Shin, MC, Lee, J, Lee, C, Nam, Y, “Performance Analysis of Gravity-Driven Oil-Water Separation Using Membranes with Special Wettability.” Langmuir, 35 7769–7782 (2019)
Gao, H, Liu, Y, Wang, G, Li, S, Han, Z, Ren, L, “Switchable Wettability Surface with Chemical Stability and Antifouling Properties for Controllable Oil–Water Separation.” Langmuir, 35 4498–4508 (2019)
Adhikari, S, Fernando, S, “Hydrogen Membrane Separation Techniques.” Ind. Eng. Chem. Res., 45 (3) 875–881 (2006)
Jiang, J, Zhang, Q, Zhan, X, Chen, F, “Renewable, Biomass-Derived, Honeycomblike Aerogel as a Robust Oil Absorbent with Two-Way Reusability.” ACS Sustain. Chem. Eng., 5 (11) 10307–10316 (2017)
Liu, X, Ge, L, Li, W, Wang, X, Li, F, “Layered Double Hydroxide Functionalized Textile for Effective Oil/Water Separation and Selective Oil Adsorption.” ACS Appl. Mater. Inter., 7 (1) 791–800 (2015)
Cui, J, Zhou, Z, Xie, A, Meng, M, Cui, Y, Liu, S, Dong, H, “Bio-inspired Fabrication of Superhydrophilic Nanocomposite Membrane Based on Surface Modification of SiO2 Anchored by Polydopamine Towards Effective Oil–Water Emulsions Separation.” Sep. Purif. Technol., 209 434–442 (2019)
Cui, J, Xie, A, Zhou, S, Liu, S, Wang, Q, Wu, Y, Yan, Y, “Development of Composite Membranes With Irregular Rod-Like Structure via Atom Transfer Radical Polymerization for Efficient Oil–Water Emulsion Separation.” J. Colloid Interface Sci., 533 278–286 (2019)
Ge, M, Cao, C, Huang, J, Zhang, X, “Rational Materials Interface Design at Nanoscale Towards Intelligent Oil–Water Separation.” Nanoscale Horiz., 3 235–260 (2018)
Sadeghi, I, Govinna, N, Cebe, P, Asatekin, A, “Superoleophilic, Mechanically Strong Electrospun Membranes for Fast and Efficient Gravity-Driven Oil/Water Separation.” ACS Appl. Polym. Mater., 1 765–776 (2019)
Wu, J, Li, H, Lai, X, Chen, Z, Zeng, X, “Superhydrophobic Polydimethylsiloxane@Multiwalled Carbon Nanotubes Membrane for Effective Water-in-Oil Emulsions Separation and Quick Deicing.” Ind. Eng. Chem. Res., 58 8791–8799 (2019)
Cai, Y, Chen, D, Li, N, Xu, Q, Li, H, He, J, Lu, J, “Superhydrophobic Metal-Organic Framework Membrane with Self-Repairing for High-Efficiency Oil/Water Emulsion Separation.” ACS Sustain. Chem. Eng., 7 2709–2717 (2018)
Lu, J, Yu, Y, Zhou, J, Song, L, Hu, X, Larbot, A, “FAS Grafted Superhydrophobic Ceramic Membrane.” Appl. Surf. Sci., 255 (22) 9092–9099 (2009)
Khemakhem, M, Khemakhem, S, Amar, RB, “Emulsion Separation Using Hydrophobic Grafted Ceramic Membranes.” Colloid. Surface A, 436 402–407 (2013)
Kujawski, W, Kujawa, J, Wierzbowska, E, Cerneaux, S, Bryjak, M, Kujawski, J, “Influence of Hydrophobization Conditions and Ceramic Membranes Pore Size on Their Properties in Vacuum Membrane Distillation of Water–Organic Solvent Mixtures.” J. Membr. Sci., 499 442–451 (2016)
Su, X, Li, H, Lai, X, “Vapor–Liquid Sol–Gel Approach to Fabricating Highly Durable and Robust Superhydrophobic Polydimethylsiloxane@Silica Surface on Polyester Textile for Oil–Water Separation.” ACS Appl. Mater. Inter., 9 28089 (2017)
Huang, W, Zhang, L, Lai, X, “Highly Hydrophobic F-rGO@Wood Sponge for Efficient Clean-Up of Viscous Crude Oil.” Chem. Eng. J., 386 123994 (2019)
Zhang, L, Li, H, Lai, X, “Thiolated Graphene-Based Superhydrophobic Sponges for Oil–Water Separation.” Chem. Eng. J., 316 736–743 (2017)
Liu, H, Huang, J, Chen, Z, “Robust Translucent Superhydrophobic PDMS/PMMA Film by Facile One-Step Spray for Self-cleaning and Efficient Emulsion Separation.” Chem. Eng. J., 330 26–35 (2017)
Cheng, Y, Zhu, T, Li, S, Huang, J, “A Novel Strategy for Fabricating Robust Superhydrophobic Fabrics by Environmentally-Friendly Enzyme Etching.” Chem. Eng. J., 355 290–298 (2019)
Cui, M, Mu, P, Shen, Y, Zhu, G, Luo, L, Li, J, “Three-Dimensional Attapulgite with Sandwich-Like Architecture Used for Multifunctional Water Remediation.” Sep. Purif. Technol., 235 116210 (2020)
Tang, HY, He, J, Hao, LT, Wang, F, Zhang, HP, Guo, YH, “Developing Nanofiltration Membrane Based on Microporous Poly(Tetrafluoroethylene) Substrates by Bi-Stretching Process.” J. Membr. Sci., 524 612–622 (2017)
Tang, HY, Hao, LT, Chen, JC, Wang, F, Zhang, HP, Guo, YH, “Surface Modification to Fabricate Superhydrophobic and Superoleophilic Alumina Membranes for Oil/Water Separation.” Energy Fuel., 32 (3) 3627–3636 (2018)
Xie, A, Dai, J, Ma, C, Cui, J, Chen, Y, Lang, J, Yan, Y, “Construction of Caterpillar-Like Cobalt-Nickel Hydroxide/Carbon Cloth Hierarchical Architecture with Reversible Wettability Towards On-demand Oil–Water Separation.” Appl. Surf. Sci., 462 659–668 (2018)
Gao, X, Xu, LP, Xue, Z, Feng, L, Peng, J, Wen, Y, Zhang, X, “Dual-Scaled Porous Nitrocellulose Membranes with Underwater Superoleophobicity for Highly Efficient Oil/Water Separation.” Adv. Mater., 26 (11) 1771–1775 (2014)
Jin, M, Wang, J, Yao, X, Liao, M, Zhao, Y, Jiang, L, “Underwater Oil Capture by a Three-Dimensional Network Architectured Organosilane Surface.” Adv. Mater., 23 (25) 2861–2864 (2011)
Zhao, J, Li, D, Han, H, Lin, J, Yang, J, Wang, Q, Chen, L, “Hyperbranched Zwitterionic Polymer-Functionalized Underwater Superoleophobic Microfiltration Membranes for Oil-in-Water Emulsion Separation.” Langmuir, 35 2630–2638 (2019)
Huang, KT, Yeh, SB, Huang, CJ, “Surface Modification for Superhydrophilicity and Underwater Superoleophobicity: Applications in Antifog, Underwater Self-Cleaning, and Oil–Water Separation.” ACS Appl. Mater. Interf., 7 (38) 21021–21029 (2015)
Chen, X, Zhai, Y, Han, X, Liu, H, Hu, Y, “Surface Chemistry-Dominated Underwater Superoleophobic Mesh with Mussel-Inspired Zwitterionic Coatings for Oil/Water Separation and Self-cleaning.” Appl. Surf. Sci., 483 399–408 (2019)
Rana, D, Kim, Y, Matsuura, T, Arafat, HA, “Development of Antifouling Thin-Film-Composite Membranes for Seawater Desalination.” J. Membr. Sci., 367 (1–2) 110–118 (2011)
Rana, D, Scheier, B, Narbaitz, RM, Matsuura, T, Tabe, S, Jasim, SY, Khulbe, KC, “Comparison of Cellulose Acetate (CA) Membrane and Novel CA Membranes Containing Surface Modifying Macromolecules to Remove Pharmaceutical and Personal Care Product Micropollutants from Drinking Water.” J. Membr. Sci., 409–410 346–354 (2012)
Zhao, X, Jia, N, Cheng, L, Wang, R, Gao, C, “Constructing Antifouling Hybrid Membranes with Hierarchical Hybrid Nanoparticles for Oil-in-Water Emulsion Separation.” ACS Omega, 4 2320–2330 (2019)
Chen, Y, Xie, A, Cui, J, Lang, J, Yan, Y, Li, C, Dai, J, “UV-Driven Antifouling Paper Fiber Membranes for Efficient Oil–Water Separation.” Ind. Eng. Chem. Res., 58 5186–5194 (2019)
Hu, X, Yu, Y, Zhou, J, Wang, Y, Liang, J, Zhang, X, Song, L, “The Improved Oil/Water Separation Performance of Graphene Oxide Modified Al2O3 Microfiltration Membrane.” J. Membr. Sci., 476 200–204 (2015)
You, Q, Ran, G, Wang, C, “Facile Fabrication of Superhydrophilic and Underwater Superoleophobic Chitosan–Polyvinyl Alcohol-TiO2 Coated Copper Mesh for Efficient Oil/Water Separation.” J. Coat. Technol. Res., 15 1013 (2018)
Shi, G, Shen, Y, Mu, P, “Effective Separation of Surfactant-Stabilized Crude Oil-in-Water Emulsions by Using Waste Brick Powder-Coated Membranes Under Corrosive Conditions.” Green Chem., 22 1345–1352 (2020)
Yu, H, Zhong, QZ, Liu, TG, Qiu, WZ, Wu, BH, Xu, ZK, Wan, LS, “Surface Deposition of Juglone/FeIII on Microporous Membranes for Oil/Water Separation and Dye Adsorption.” Langmuir, 35 3643–3650 (2019)
Li, H, Zhu, L, Zhang, J, Guo, T, Li, X, Xing, W, Xue, Q, “High-Efficiency Separation Performance of Oil–Water Emulsions of Polyacrylonitrile Nanofibrous Membrane Decorated with Metal–Organic Frameworks.” Appl. Surf. Sci., 476 61–69 (2019)
Tan, L, Han, N, Qian, Y, Zhang, H, Gao, H, Zhang, L, Zhang, X, “Superhydrophilic and Underwater Superoleophobic Poly(Acrylonitrile-co-Methyl Acrylate) Membrane for Highly Efficient Separation of Oil-in-Water Emulsions.” J. Membr. Sci., 564 712–721 (2018)
Liu, S, Zhou, Z, Zhou, S, Cui, J, Wang, Q, Zhang, Y, Yan, Y, “Fabrication of Acrylamide Decorated Superhydrophilic and Underwater Superoleophobic Poly(Vinylidene Fluoride) Membranes for Oil/Water Emulsion Separation.” J. Taiwan Inst. Chem. E, 95 300–307 (2019)
Huang, Y, Li, H, Wang, L, Qiao, Y, Tang, C, Jung, C, Yu, M, “Ultrafiltration Membranes with Structure-Optimized Graphene-Oxide Coatings for Antifouling Oil/Water Separation.” Adv. Mater. Interfaces, 2 (2) 1400433 (2015)
Kota, AK, Kwon, G, Choi, W, Mabry, JM, Tuteja, A, “Hygro-responsive Membranes for Effective Oil–Water Separation.” Nat. Commun., 3 (1) 1–8 (2012)
Yu, B, Wang, DA, Ye, Q, Zhou, F, Li, WM, “Robust Polydopamine Nano/Micro Capsules and Their Loading and Release Behaviour.” Chem. Commun., 44 6789–6791 (2009)
Zuo, JH, Cheng, P, Chen, XF, Yan, X, Guo, YJ, Lang, WZ, “Ultrahigh Flux of Polydopamine-Coated PVDF Membranes Quenched in Air via Thermally Induced Phase Separation for Oil/Water Emulsion Separation.” Sep. Purif. Technol., 192 348–359 (2018)
Acknowledgments
The authors were financially supported by Zhejiang Natural Science Foundation (No. LY19B060016. The authors were also grateful to Pingxiang Bocent Advanced Ceramic Co., Ltd. (Jiangxi, China) for supplying alumina (Al2O3) membranes.
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Zhou, W., Zhou, M., Zhang, H. et al. Bio-inspired fabrication of superhydrophilic and underwater superoleophobic alumina membranes for highly efficient oil/water separation. J Coat Technol Res 18, 361–372 (2021). https://doi.org/10.1007/s11998-020-00406-4
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DOI: https://doi.org/10.1007/s11998-020-00406-4