Skip to main content
Log in

Effect on wear resistance of nanoparticles addition to a powder polyester coating through ball milling

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

The wear properties of a textured polyester powder coating with pyrogenic silica nanoparticles addition were evaluated. Raw powders of a commercial, textured polyester organic coating were mixed with low amounts of SiO2 nanoparticles (0.5–3 wt%) using ball milling, a simple and economical method. Nanoparticles were mixed into the powder of thermoset organic coating for 10 min in a two-body planetary ball mill. Particle size distribution of the powder was measured to evaluate the milling effect. The coatings were applied and cured in an industrial installation on aluminum substrates. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) images of the coatings were taken to analyze the homogeneity of the organic coating. Roughness, gloss and color were measured in order to evaluate their appearance. The effect of nanoparticles on abrasive and erosion wear performances was measured. Pin-on-disk wear tests were carried out. Erosion measurements were performed with free fall of sand on the samples, a test based on ASTM D968 standard. The results showed that the milling process provides a good distribution of nanoparticles as no agglomerates were found. The addition of 0.5 wt% silica nanoparticles allows for improvement of the wear resistance of the coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Shi, Q, Huang, W, Zhang, Y, Zhang, Y, Xu, Y, Guo, G, “Curing of Polyester Powder Coating Modified with Rutile Nano-Sized Titanium Dioxide Studied by DSC and Real-Time FT-IR.” J. Therm. Anal. Calorim., 108 (3) 1243–1249 (2012)

    Article  Google Scholar 

  2. Mirabedini, SM, Kiamanesh, A, “The Effect of Micro and Nano-Sized Particles on Mechanical and Adhesion Properties of a Clear Polyester Powder Coating.” Prog. Org. Coat., 76 (11) 1625–1632 (2013)

    Article  Google Scholar 

  3. Huang, Q, Zhang, H, Zhu, J, “Flow Properties of Fine Powders in Powder Coating.” Particuology, 8 (1) 19–27 (2010)

    Article  Google Scholar 

  4. Barletta, M, Gisario, A, Trovalusci, F, Vesco, S, “Visual Appearance and Scratch Resistance of High Performance Thermoset and Thermoplastic Powder Coatings.” Prog. Org. Coat., 76 (1) 244–256 (2013)

    Article  Google Scholar 

  5. Jarka, P, Tański, T, Matysiak, W, Krzemiński, Ł, Hajduk, B, Bilewicz, M, “Manufacturing and Investigation of Surface Morphology and Optical Properties of Composite Thin Films Reinforced by TiO2, Bi2O3 and SiO2 Nanoparticles.” Appl. Surf. Sci., 424 206–212 (2017)

    Article  Google Scholar 

  6. Yu, H, Wang, L, Shi, Q, Jiang, S, Jiang, G, “Preparation of Epoxy Resin/CaCO3 Nanocomposites and Performance of Resultant Powder Coatings.” J. Appl. Polym. Sci., 101 (4) 2656–2660 (2006)

    Article  Google Scholar 

  7. Kalaee, M, Akhlaghi, S, Nouri, A, Mazinani, S, Mortezaei, M, Afshari, M, Mostafanezhad, D, Dehaghi, HA, Amirsadri, A, Gohari, DP, “Effect of Nano-Sized Calcium Carbonate on Cure Kinetics and Properties of Polyester/Epoxy Blend Powder Coatings.” Prog. Org. Coat., 71 (2) 173–180 (2011)

    Article  Google Scholar 

  8. Jawahar, P, Gnanamoorthy, R, Balasubramanian, M, “Tribological Behaviour of Clay—Thermoset Polyester Nanocomposites.” Wear, 261 (7–8) 835–840 (2006)

    Article  Google Scholar 

  9. Sierros, KA, Kukureka, SN, “Tribological Investigation of Thin Polyester Substrates for Displays.” Wear, 263 (7–12) 992–999 (2007)

    Article  Google Scholar 

  10. Palraj, S, Selvaraj, M, Maruthan, K, Rajagopal, G, “Corrosion and Wear Resistance Behavior of Nano-Silica Epoxy Composite Coatings.” Prog. Org. Coat., 81 132–139 (2015)

    Article  Google Scholar 

  11. Zhou, S, Wu, L, Sun, J, Shen, W, “The Change of the Properties of Acrylic-Based Polyurethane Via Addition of Nano-Silica.” Prog. Org. Coat., 45 (1) 33–42 (2002)

    Article  Google Scholar 

  12. Sabzi, M, Mirabedini, SM, Zohuriaan-Mehr, J, Atai, M, “Surface Modification of TiO2 Nano-Particles with Silane Coupling Agent and Investigation of its Effect on the Properties of Polyurethane Composite Coating.” Prog. Org. Coat., 65 (2) 222–228 (2009)

    Article  Google Scholar 

  13. Maganty, S, Roma, MPC, Meschter, SJ, Starkey, D, Gomez, M, Edwards, DG, Ekin, A, Elsken, K, Cho, J, “Enhanced Mechanical Properties of Polyurethane Composite Coatings Through Nanosilica Addition.” Prog. Org. Coat., 90 243–251 (2016)

    Article  Google Scholar 

  14. Golgoon, A, Aliofkhazraei, M, Toorani, M, Moradi, MH, Rouhaghdam, AS, “Corrosion and Wear Properties of Nanoclay-Polyester Nanocomposite Coatings Fabricated by Electrostatic Method.” Proc. Mater. Sci., 11 536–541 (2015)

    Article  Google Scholar 

  15. Chen, C, Qiu, S, Cui, M, Qin, S, Yan, G, Zhao, H, Wang, L, Xue, Q, “Achieving High Performance Corrosion and Wear Resistant Epoxy Coatings Via Incorporation of Noncovalent Functionalized Graphene.” Carbon, 114 356–366 (2017)

    Article  Google Scholar 

  16. Piazza, D, Baldissera, AF, Kunst, SR, Rieder, ES, Scienza, LC, Ferreira, CA, Zattera, AJ, “Influence of the Addition of Montmorillonite in an Epoxy Powder Coating Applied on Carbon Steel.” Mater. Res., 18 (5) 897–903 (2015)

    Article  Google Scholar 

  17. Sharifi, M, Ebrahimi, M, Jafarifard, S, “Preparation and Characterization of a High Performance Powder Coating Based on Epoxy/Clay Nanocomposite.” Prog. Org. Coat., 106 69–76 (2017)

    Article  Google Scholar 

  18. Piazza, D, Silveira, DS, Lorandi, NP, Birriel, EJ, Scienza, LC, Zattera, AJ, “Polyester-Based Powder Coatings with Montmorillonite Nanoparticles Applied on Carbon Steel.” Prog. Org. Coat., 73 (1) 42–46 (2012)

    Article  Google Scholar 

  19. Moradi, MH, Aliofkhazraei, M, Toorani, M, Golgoon, A, Rouhaghdam, AS, “SiAlON–Epoxy Nanocomposite Coatings Corrosion and Wear Behavior.” J. Appl. Polym. Sci., 133 (35) 1–13 (2016)

    Article  Google Scholar 

  20. Zhou, S, Gu, G, “Study on the Morphology and Tribological Properties of Acrylic Based Polyurethane/Fumed Silica Composite Coatings.” J. Mater. Sci., 39 (5) 1593–1600 (2004)

    Article  Google Scholar 

  21. Hikku, GS, Jeyasubramanian, K, Vignesh Kumarb, S, “Nanoporous MgO as Self-Cleaning and Anti-Bacterial Pigment for Alkyd Based Coating.” J. Ind. Eng. Chem., 52 168–178 (2017)

    Article  Google Scholar 

  22. Kiil, S, “Mathematical Modeling of Pigment Dispersion Taking into Account the Full Agglomerate Particle Size Distribution.” J. Coat. Technol. Res., 14 (1) 69–84 (2017)

    Article  Google Scholar 

  23. Halász, L, Belina, K, “An Investigation into the Curing of Epoxy Powder Coating Systems.” J. Therm. Anal. Calorim., 119 (3) 1971–1980 (2015)

    Article  Google Scholar 

  24. Belder, EG, Rutten, HJJ, Perera, DY, “Cure Characterization of Powder Coatings.” Prog. Org. Coat., 42 (3–4) 142–149 (2001)

    Article  Google Scholar 

  25. Gioia, C, Minesso, A, Cavalieri, R, Marchese, P, Celli, A, Colonna, M, “Powder Coatings for Indoor Applications from Renewable Resources and Recycled Polymers.” J. Coat. Technol. Res., 12 (3) 555–562 (2015)

    Article  Google Scholar 

  26. Carvalho, RM, de Tavares, LM, “Predicting the Effect of Operating and Design Variables on Breakage Rates Using the Mechanistic Ball Mill Model.” Miner. Eng., 43 (1) 91–101 (2013)

    Article  Google Scholar 

  27. Barrios, GKP, Carvalho, RM, de Tavares, LM, “Modeling Breakage of Monodispersed Particles in Unconfined Beds.” Miner. Eng., 24 (3–4) 308–318 (2011)

    Article  Google Scholar 

  28. Valdesueiro, D, Hettinga, H, Drijfhout, JP, Lips, P, Meesters, GMH, Kreutzer, MT, van Ommen, JR, “Tuning Roughness and Gloss of Powder Coating Paint by Encapsulating the Coating Particles with Thin Al2O3 Films.” Powder Technol., 318 401–410 (2017)

    Article  Google Scholar 

  29. Pantoja, M, Abenojar, J, Martinez, MA, “Influence of the Type of Solvent on the Development of Superhydrophobicity from Silane-Based Solution Containing Nanoparticles.” Appl. Surf. Sci., 397 (1) 87–94 (2017)

    Article  Google Scholar 

  30. Biris, AS, Mazumder, MK, Yurteri, CU, Sims, RA, Snodgrass, J, De, S, “Gloss and Texture Control of Powder Coated Films.” Part. Sci. Technol., 19 (3) 199–217 (2001)

    Article  Google Scholar 

  31. Gonnet, J, “Colour Effects of Co-Pigmentation of Anthocyanins Revisited-2. A Colorimetric Look at the Solucions of Cyanin Co-Pigmented by Rutin Using the CIELAB Scale.” Food Chem., 66 (3) 387–394 (1999)

    Article  Google Scholar 

  32. Franceschi, E, Letardi, P, Luciano, G, “Colour Measurements on Patinas and Coatings System for Outdoor Bronze Monument.” J. Cult. Herit., 7 (3) 166–170 (2006)

    Article  Google Scholar 

  33. ST, D, Johansson, M, “Properties of Powder Coatings in Load Carrying Construction.” J. Coat. Technol. Res., 2 (6) 473–481 (2005)

    Article  Google Scholar 

  34. Xing, XS, Li, RKY, “Wear Behavior of Epoxy Matrix Composites Filled with Uniform Sized Sub-Micron Spherical Silica Particles.” Wear, 256 (1–2) 21–26 (2004)

    Article  Google Scholar 

  35. Malaki, M, Hashemzadeh, Y, Karevan, M, “Effect of Nano-Silica on the Mechanical Properties of Acrylic Polyurethane Coatings.” Prog. Org. Coat., 101 477–485 (2016)

    Article  Google Scholar 

  36. Zhou, SX, Wu, LM, Sun, J, Shen, WD, “Effect of Nanosilica on the Properties of Polyester-Based Polyurethane.” J. Appl. Polym. Sci., 88 (1) 189–193 (2003)

    Article  Google Scholar 

  37. Domun, N, Hadavinia, H, Zhang, T, Sainsbury, T, Liaghat, GH, Vahid, S, “Improving the Fracture Toughness and the Strength of Epoxy Using Nanomaterials—A Review of the Current Status.” Nanoscale, 7 (23) 10294–10329 (2015)

    Article  Google Scholar 

Download references

Acknowledgments

The authors acknowledge the financial support of Interreg SUDOE, through KrEaTive Habitat project (Ref. SOE1/P1/E0307), as well as Cubson International Consulting for their help with the coating process.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to María Fernández-Álvarez.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fernández-Álvarez, M., Velasco, F. & Bautista, A. Effect on wear resistance of nanoparticles addition to a powder polyester coating through ball milling. J Coat Technol Res 15, 771–779 (2018). https://doi.org/10.1007/s11998-018-0106-z

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-018-0106-z

Keywords

Navigation