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Sol–gel preparation and characterization of antibacterial and self-cleaning hybrid nanocomposite coatings

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Abstract

ZnO–TiO2, SiO2–TiO2, and SiO2–TiO2–ZnO hybrid nanocomposite coatings were synthesized based on sol–gel precursors including tetramethoxysilane (TMOS), 3-glycidoxypropyl trimethoxysilane (GPTMS), tetra(n-butyl orthotitanate) (TBT), and zinc acetate dihydrate. The hybrid network was characterized by FTIR, FESEM, and EDAX techniques. Results indicated that inorganic particles’ size was of nanoorder (20–30 nm), with very uniform distribution and dispersion. Photocatalytic and self-cleaning activities of these coatings were further investigated by degradation of methylene blue in an aqueous solution (20 ppm) at visible light irradiation, indicating photocatalytic performance of the coatings containing ZnO and TiO2 nanoparticles. The antibacterial effect of the coatings was investigated for inhibition and inactivation of cell growth, with the results showing the same antibacterial activity for ZnO–TiO2 and SiO2–TiO2–ZnO coatings against Escherichia coli and Staphylococcus aureus; the activity was, however, higher than that of SiO2–TiO2 hybrid nanocomposite coatings.

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References

  1. Dalrymple, OK, Stefanakos, E, Trotz, MA, Goswami, DY, “A Review of the Mechanisms and Modeling of Photocatalytic Disinfection.” Appl. Catal. B Environ., 98 27–38 (2010)

    Article  Google Scholar 

  2. Foster, HA, Ditta, IB, Varghese, S, Steele, A, “Photocatalytic Disinfection Using Titanium Dioxide: Spectrum and Mechanism of Antimicrobial Activity.” Appl. Microbiol. Biotechnol., 90 1847–1868 (2011)

    Article  Google Scholar 

  3. Radtke, A, Piszczek, P, Topolski, A, Lewandowska, Z, Talik, E, Andersen, IH, Nielsen, LP, Heikkila, D, Leskela, M, “The Structure and the Photocatalytic Activity of Titania Based Nanotube and Nanofiber Coatings.” Appl. Surf. Sci., 368 165–172 (2016)

    Article  Google Scholar 

  4. Tung, WS, Daoud, WA, “Photocatalytic Self-cleaning Keratins: A Feasibility Study.” Acta Biomater., 5 50–56 (2009)

    Article  Google Scholar 

  5. Tung, WS, Daoud, WA, Leung, SK, “Understanding Photocatalytic Behavior on Biomaterials: Insights from TiO2 Concentration.” J. Colloid Interface Sci., 339 424–433 (2009)

    Article  Google Scholar 

  6. Kaleji, B, Mousaeia, M, Halakouie, H, Ahmadi, A, “Sol–Gel Synthesis of ZnO Nanoparticles and ZnO–TiO2–SiO2 Nanocomposites and Their Photo-catalyst Investigation in Methylene Blue Degradation.” J. Nano Struct., 5 219–225 (2015)

    Google Scholar 

  7. Tian, J, Chen, L, Dai, J, Wang, X, Yin, Y, Wu, P, “Preparation and Characterization of TiO2, ZnO, and TiO2/ZnO nanofilms Via Sol-Gel Process.” Ceram. Int., 35 2261–2270 (2009)

    Article  Google Scholar 

  8. Rahimi, A, Amiri, S, “Sol–Gel Technology and Various Hybrid Nanocomposite Coatings Applications.” Iran. Polym. J., (2016). doi:10.1007/s13726-016-0440-x

    Google Scholar 

  9. Amiri, S, Rahimi, A, “Preparation of Supramolecular Corrosion Inhibitor Nanocontainers for Self-protective Hybrid Nanocomposite Coatings.” J. Polym. Res., (2014). doi:10.1007/s10965-014-0566-5

    Google Scholar 

  10. Amiri, S, Rahimi, A, “Self-healing Hybrid Nanocomposite Coatings Containing Encapsulated Organic Corrosion Inhibitors Nanocontainers.” J. Polym. Res., (2014). doi:10.1007/s10965-014-0624-z

    Google Scholar 

  11. Rahimi, A, Amiri, S, “Anti-corrosion Hybrid Nanocomposite Coatings with Encapsulated Organic Corrosion Inhibitors.” J. Coat. Technol. Res., (2015). doi:10.1007/s11998-014-9652-1

    Google Scholar 

  12. Rahimi, A, Amiri, S, “Self-healing Anticorrosion Coating Containing 2-Mercaptobenzothiazole and 2-Mercaptobenzimidazole Nanocapsules.” J. Polym. Res., (2015). doi:10.1007/s11998-014-9652-1

    Google Scholar 

  13. Rahimi, A, Amiri, S, “Anti-corrosion Hybrid Nanocomposite Coatings with Encapsulated Organic Corrosion Inhibitors.” J. Polym. Res., (2016). doi:10.1007/s10965-016-0973-x

    Google Scholar 

  14. Wang, Y, Ma, J, Xu, Q, Zhang, J, “Fabrication of Antibacterial Casein-Based ZnO Nanocomposite for Flexible Coatings.” Mater. Des., 113 240–245 (2017)

    Article  Google Scholar 

  15. Radulescu, M, Andronescu, E, Cirja, A, Holban, AM, Mogoanta, L, Balşeanu, TA, Catalin, B, Neagu, TP, Lascar, I, Florea, DA, Grumezescu, AM, Ciubuca, B, Lazar, V, Chifiriuc, MC, Bolocan, A, “Antimicrobial Coatings Based on Zinc Oxide and Orange Oil for Improved Bioactive Wound Dressings and Other Applications.” Rom. J. Morphol. Embryol., 57 107–114 (2016)

    Google Scholar 

  16. Celebioglu, A, Umu, OC, Tekinay, T, Uyar, T, “Antibacterial Electrospun Nanofibers from Triclosan/Cyclodextrin Inclusion Complexes.” Colloids Surf. B Biointerfaces, 116 612–619 (2014)

    Article  Google Scholar 

  17. Dhoke, SK, Rajgopalan, N, Khanna, AS, “Effect of Nano-Zinc Oxide Particles on the Performance Behavior of Waterborne Polyurethane Composite Coatings.” Int. J. Mater. Sci., 2 47–55 (2012)

    Google Scholar 

  18. Liao, DL, Badour, CA, Liao, BQ, “Preparation of Nanosized TiO2/ZnO Composite Catalyst and Its Photocatalytic Activity for Degradation of Methyl Orange.” J. Photochem. Photobiol. A, 194 11–19 (2008)

    Article  Google Scholar 

  19. Tian, J, Chen, L, Yin, Y, “Photocatalyst of TiO2/ZnO Nano Composite Film: Preparation, Characterization, and Photodegradation Activity of Methyl Orange.” Surf. Coat. Technol., 204 205–214 (2009)

    Article  Google Scholar 

  20. Prasad, D, Girija, CR, Jagannatha Reddy, A, Nagabhushana, H, Nagabhushana, BM, Venkatesha, TV, Arun Kumar, ST, “A Study on the Antibacterial Activity Of ZnO Nanoparticles Prepared by Combustion Method Against E. coli.” J. Eng. Res. Appl., 4 84–89 (2014)

    Google Scholar 

  21. Jiang, Y, Wu, M, Wu, X, Sun, Y, Yin, H, “Low-Temperature Hydrothermal Synthesis of Flower-Like ZnO Microstructure and Nanorod Array on Nanoporous TiO2 Film.” Mater. Lett., 63 275–278 (2009)

    Article  Google Scholar 

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Correspondence to Sahar Amiri.

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Estekhraji, S.A.Z., Amiri, S. Sol–gel preparation and characterization of antibacterial and self-cleaning hybrid nanocomposite coatings. J Coat Technol Res 14, 1335–1343 (2017). https://doi.org/10.1007/s11998-017-9932-7

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