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Preparation and characterization of ultraviolet (UV) radiation curable resin from palm oil


A study on the preparation of ultraviolet (UV) curable polymers based on renewable materials (vegetable oil) has been done to improve the performance of existing polymers and compete with their corresponding petrol-based chemicals in different aspects, including environmental friendly and economic factors. In this study, a UV curable resin was prepared using palm oil and glycidyl methacrylate. Monoglyceride (MG) from palm oil was prepared using alcoholysis process. Then, the MG was treated with glycidyl methacrylate (GMA) at different ratios of GMA/MG to produce MG–GMA resin. The prepared resin was characterized using different techniques, such as hydroxyl number determination, gas chromatography (GC), and gel permeation chromatography (GPC). From the results, GMA/MG ratio influenced the properties of MG–GMA resin. The weight-average molecular weight (M w) of the resin increased as the ratio of GMA/MG was increased. However, M w decreased after exceeding a limit of GMA/MG ratio. This was probably due to homopolymerization of GMA monomer during the treatment of MG with GMA. A similar trend was also observed in the result of viscosity. It is also noticed that the hydroxyl number of MG increased as more glycerol was used in the glycerol/palm oil mixture in the alcoholysis process. From the results of GC, it was shown that the percentage of MG increased when the ratio of glycerol/palm oil increased. This indicated that most of the hydroxyl group was contributed by the presence of MG. The prepared resin was then exposed to UV radiation and the results indicated that resin could be cured by UV radiation.

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  1. 1.

    Islam, MR, Beg, MDH, Jamari, SS, “Development of Vegetable-Oil-Based Polymers.” J. Appl. Polym. Sci., 131 (18) 9016–9028 (2014)

    Article  Google Scholar 

  2. 2.

    Oprea, S, “Properties of Crosslinked Polyurethanes Obtained by Acrylic Side-Group Polymerization and of Their Blends with Various Plant Oils.” J. Appl. Polym. Sci., 129 (6) 3640–3649 (2013)

    Article  Google Scholar 

  3. 3.

    La Scala, J, Wool, RP, “Fundamental Thermo-mechanical Property Modeling of Triglyceride-Based Thermosetting Resins.” J. Appl. Polym. Sci., 127 (3) 1812–1826 (2013)

    Article  Google Scholar 

  4. 4.

    Akbas, T, Beker, UG, Güner, FS, Erciyes, AT, Yagci, Y, “Drying and Semidrying Oil Macromonomers. III. Stvrenation of Sunflower and Linseed Oils.” J. Appl. Polym. Sci., 88 (10) 2373–2376 (2003)

    Article  Google Scholar 

  5. 5.

    Aigbodion, AI, Okieimen, FE, Ikhuoria, EU, Bakare, IO, Obazee, EO, “Rubber Seed Oil Modified with Maleic Anhydride and Fumaric Acid and Their Alkyd Resins as Binders in Water-Reducible Coatings.” J. Appl. Polym. Sci., 89 (12) 3256–3259 (2003)

    Article  Google Scholar 

  6. 6.

    Ge, Q, Wang, H, She, Y, Jiang, S, Cao, M, Zhai, L, Jiang, S, “Synthesis, Characterization, and Properties of Acrylate-Modified Tung-Oil Waterborne Insulation Varnish,” J. Appl. Polym. Sci., 132(10), n/a–n/a (2015)

  7. 7.

    Johns, A, Morris, S, Edwards, K, Quirino, RL, “Asolectin from Soybeans as a Natural Compatibilizer for Cellulose-Reinforced Biocomposites from Tung Oil,” J. Appl. Polym. Sci., 132(17), n/a–n/a (2015)

  8. 8.

    Jia, P, Zhang, M, Liu, C, Hu, L, Zhou, Y-H, “Properties of Poly(vinyl chloride) Incorporated with a Novel Soybean Oil Based Secondary Plasticizer Containing a Flame Retardant Group,” J. Appl. Polym. Sci., 132(25), n/a–n/a (2015)

  9. 9.

    Temiz, A, Kose, G, Panov, D, Terziev, N, Alma, MH, Palanti, S, Akbas, S, “Effect of Bio-oil and Epoxidized Linseed Oil on Physical, Mechanical, and Biological Properties of Treated Wood.” J. Appl. Polym. Sci., 130 (3) 1562–1569 (2013)

    Article  Google Scholar 

  10. 10.

    Kolot, V, Grinberg, S, “Vernonia Oil—Based Acrylate and Methacrylate Polymers and Interpenetrating Polymer Networks with Epoxy Resins,” no. August (2003).

  11. 11.

    La Scala, J, Wool, RP, “Rheology of Chemically Modified Triglycerides.” J. Appl. Polym. Sci., 95 (3) 774–783 (2005)

    Article  Google Scholar 

  12. 12.

    Li, F, Hanson, M, Larock, R, “Soybean Oil-Divinylbenzene Thermosetting Polymers: Synthesis, Structure, Properties and Their Relationships.” Polymer (Guildf), 42 (4) 1567–1579 (2001)

    Article  Google Scholar 

  13. 13.

    Malaysian Palm Oil Council (MPOC), (2015)

  14. 14.

    Malaysian Palm Oil Board (MPOB), Malaysia Palm Oil Statistic: Economics and Industry Development Division, 2009, Accessed 4 August 2015

  15. 15.

    Basiron, Y, “Palm Oil Production Through Sustainable Plantations,” Eur. J. Lipid Sci. Technol., 109, 289–295 (2007).

  16. 16.

    Tan, SG, Chow, WS, “Biobased Epoxidized Vegetable Oils and Its Greener Epoxy Blends: A Review.” Polym. Plast. Technol. Eng., 49 (15) 1581–1590 (2010)

    Article  Google Scholar 

  17. 17.

    Hong, BT, Shin, KS, Kim, DS, “Ultraviolet-Curing Behavior of an Epoxy Acrylate Resin System.” J. Appl. Polym. Sci., 98 (3) 1180–1185 (2005)

    Article  Google Scholar 

  18. 18.

    Cui, J, Yu, G, Pan, C, “A Novel UV-Curable Epoxy Acrylate Resin Containing Arylene Ether Sulfone Linkages: Preparation, Characterization, and Properties,” J. Appl. Polym. Sci., 131(22), n/a–n/a (2014)

  19. 19.

    Rozman, HD, Tai, NL, Tay, GS, “Ultra-Violet Curable Resin Based on Palm Oil: Determination of Reaction Condition and Characterization of the Resin.” J. Appl. Polym. Sci., 127 (4) 3040–3046 (2013)

    Article  Google Scholar 

  20. 20.

    Khot, SN, Lascala, JJ, Can, E, Morye, SS, Williams, GI, Palmese, GR, Kusefoglu, SH, Wool, RP, “Development and Application of Triglyceride-Based Polymers and Composites.” J. Appl. Polym. Sci., 82 (3) 703–723 (2001)

    Article  Google Scholar 

  21. 21.

    Wool, RP, Can, E, Ku, S, “Rigid, Thermosetting Liquid Molding Resins From Renewable Resources. I. Synthesis and Polymerization of Soy Oil Monoglyceride Maleates.” J. Appl. Polym. Sci., 81 69–77 (2001)

    Article  Google Scholar 

  22. 22.

    Cheong, MY, Lye-Ooi, T, Ahmad, S, Yunus, WMZW, Kuang, D, “Synthesis and Characterization of Palm-Based Resin for UV Coating.” Appl. Polym. Sci., 111 2353 (2009)

    Article  Google Scholar 

  23. 23.

    Saravari, O, Phapant, P, Pimpan, V, “Synthesis of Water-Reducible Acrylic-Alkyd Resins Based on Modified Palm Oil.” J. Appl. Polym. Sci., 96 (4) 1170–1175 (2005)

    Article  Google Scholar 

  24. 24.

    Tajau, R, Ibrahim, MI, Yunus, NM, Mahmood, MH, Salleh, MZ, Salleh, NGN, “Development of Palm Oil-Based UV-Curable Epoxy Acrylate and Urethane Acrylate Resins for Wood Coating Application.” AIP Conf. Proc., 164 164–169 (2014)

    Article  Google Scholar 

  25. 25.

    Salih, A, Ahmad, M, Ibrahim, N, Dahlan, K, Tajau, R, Mahmood, M, Yunus, W, “Synthesis of Radiation Curable Palm Oil-Based Epoxy Acrylate: NMR and FTIR Spectroscopic Investigations.” Molecules, 20 (8) 14191–14211 (2015)

    Article  Google Scholar 

  26. 26.

    Fregolente, L, Batistella, C, Filho, R, Wolf Maciel, M, “Optimization of distilled monoglycerides production.” Appl. Biochem. Biotechnol., 131 (1) 680–693 (2006)

    Article  Google Scholar 

  27. 27.

    Zhao, Y, Liu, J, Deng, L, Wang, F, Tan, T, “Optimization of Candida sp. 99-125 Lipase Catalyzed Esterification for Synthesis of Monoglyceride and Diglyceride in Solvent-Free System.” J. Mol. Catal. B Enzym., 72 (3–4) 157–162 (2011)

    Article  Google Scholar 

  28. 28.

    Han, TL, Kumar, R, Rozman, H, Noor, MAM, “GMA Grafted Sago Starch as a Reactive Component in Ultra Violet Radiation Curable Coatings.” Carbohydr. Polym., 54 (4) 509–516 (2003)

    Article  Google Scholar 

  29. 29.

    Najafi, N, Heuzey, MC, Carreau, PJ, Wood-Adams, PM, “Control of Thermal Degradation of Polylactide (PLA)-Clay Nanocomposites Using Chain Extenders.” Polym. Degrad. Stab., 97 (4) 554–565 (2012)

    Article  Google Scholar 

  30. 30.

    Lin, OH, Kumar, RN, Rozman, HD, Noor, MMA, “Grafting of sodium carboxymethylcellulose (CMC) with glycidyl methacrylate and development of UV curable coatings from CMC-g-GMA induced by cationic photoinitiators.” Carbohydr. Chem., 59 (1) 57–69 (2005)

    Article  Google Scholar 

  31. 31.

    Vallo, CI, Schroeder, WF, “Properties of Acrylic Bone Cements Formulated with Bis-GMA.” J. Biomed. Mater. Res. B, 74 (2) 676–685 (2005)

    Article  Google Scholar 

  32. 32.

    de la Fuente, JL, Cañamero, PF, Fernández-García, M, “Synthesis and characterization of glycidyl methacrylate/butyl acrylate copolymers obtained at a low temperature by atom transfer radical polymerization.” J. Polym. Sci. A Polym. Chem., 44 (6) 1807–1816 (2006)

    Article  Google Scholar 

  33. 33.

    Tan, Z, Li, W, Liu, Q, Zhang, H, “Study on Modification of Polylactide by Functional Polymer,” In: 2011 International Conference on Remote Sensing, Environment and Transportation Engineering (RSETE) (2011)

  34. 34.

    Teke, AB, Baysal, SH, “Immobilization of urease using glycidyl methacrylate grafted nylon-6-membranes.” Process Biochem., 42 (3) 439–443 (2007)

    Article  Google Scholar 

  35. 35.

    Fregolente, L, Martins, PF, “Effect of Reaction Parameters in the Synthesis of Monoglycerides from Soybean Oil,” In: 2nd Mercosur Congress on Chemical Engineering & 4th Mercosur Congress on Process Systems Engineering, p. 7. Enpromer, Brasil, 2005

  36. 36.

    Shahidi, F, Edible Oil and Fat Products: Specialty Oils and Oil Products, in Bailey’s Industrial Oil and Fat Products. John Wiley & Sons, Inc., Hoboken, NJ, 2005

    Book  Google Scholar 

  37. 37.

    Wang, X-L, Huang, J, Chen, X-Z, Yu, X-H, “Graft polymerization of N-isopropylacrylamide into a microporous polyethylene membrane by the plasma method: technique and morphology.” Desalination, 146 (1–3) 337–343 (2002)

    Google Scholar 

  38. 38.

    Kiatsimkul, P-P, Suppes, GJ, Hsieh, F-H, Lozada, Z, Tu, Y-C, “Preparation of High Hydroxyl Equivalent Weight Polyols from Vegetable Oils.” Industrial Crops and Products, 27 (3) 257–264 (2008)

    Article  Google Scholar 

  39. 39.

    La Scala, J, Wool, RP, “Rheology of Chemically Modified Triglycerides.” Journal of Applied Polymer Science, 95 (3) 774–783 (2005)

    Article  Google Scholar 

  40. 40.

    Bikiaris, DN, Karayannidis, GP, “Synthesis and Characterisation of Branched and Partially Crosslinked Poly(ethylene terephthalate).” Polymer International, 52 (7) 1230–1239 (2003)

    Article  Google Scholar 

  41. 41.

    Dhoke, SK, Sinha, TJM, Dutta, P, Khanna, AS, “Formulation and Performance Study of Low Molecular Weight, Alkyd-Based Waterborne Anticorrosive Coating on Mild Steel.” Prog. Org. Coat., 62 (2) 183–192 (2008)

    Article  Google Scholar 

  42. 42.

    Baştürk, E, İnan, T, Güngör, A, “Flame Retardant UV-Curable Acrylated Epoxidized Soybean Oil Based Organic-Inorganic Hybrid Coating.” Prog. Org. Coat., 76 (6) 985–992 (2013)

    Article  Google Scholar 

  43. 43.

    Tronche, C, Ubert, JC, Chawla, CP, “Evaluation of Some Parameters Influencing the Properties of UV Curable Coatings,” In: RadTech Conference, RadTech Europe DSM Desotech, USA, p. 7, 2001

  44. 44.

    Stevenson, P, “Finish Coatings System Adhesion and Test Methods,” In: Wood Digest’s Finishing, HighBeam Research: American Wood Finishing Institute, p. 18–20, 2003.

  45. 45.

    Mills, MR, The Science of Surface Coatings. Ernest Benn Limited, London, 1962

    Google Scholar 

  46. 46.

    Karakaya, C, Gündüz, G, Aras, L, Mecidoğlu, İA, “Synthesis of Oil Based Hyperbranched Resins and Their Modification with Melamine-Formaldehyde Resin.” Prog. Org. Coat., 59 (4) 265–273 (2007)

    Article  Google Scholar 

  47. 47.

    Xanthos, M, Young, MW, Karayanndis, GP, Bikiaris, DN, et al., “Reactive Modification of Polyethylene Terephthalate with Polyepoxides.” Polym. Eng. & Sci., 41 (4) 643–655 (2001)

    Article  Google Scholar 

  48. 48.

    Petrie, EM, Epoxy Adhesive Formulations, p. 535. McGraw-Hill, New York, 2006

    Google Scholar 

  49. 49.

    Weldon, DG, Failure Analysis of Paints and Coatings (Revised Edition), p. 362. Wiley, New York, 2009

  50. 50.

    Ratna, D, Epoxy Composites: Impact Resistance and Flame Retardancy, vol. 16, p. 128. Smithers Rapra Technology, 2007.

  51. 51.

    Athawale, VD, Raut, SS, “New Interpenetrating Polymer Networks Based on Uralkyd/Poly(glycidyl methacrylate).” European Polymer Journal, 38 (10) 2033–2040 (2002)

    Article  Google Scholar 

  52. 52.

    Vallo, CI, Schroeder, WF, “Properties of Acrylic Bone Cements Formulated with Bis-GMA.” J. Biomed. Mater. Res., 74 (2) 676–685 (2005)

    Article  Google Scholar 

  53. 53.

    Guo, Y, Mannari, V, Patel, P, Massingill, J, “Self-emulsifiable Soybean Oil Phosphate Ester Polyols for Low-VOC Corrosion Resistant Coatings.” J. Coat. Technol. Res., 3 (4) 327–331 (2006)

    Article  Google Scholar 

  54. 54.

    Soer, WJ, Ming, W, Koning, CE, Van Benthem, RATM, Mol, JMC, Terryn, H, “Barrier and Adhesion Properties of Anti-corrosion Coatings Based on Surfactant-Free Latexes from Anhydride-Containing Polymers.” Progress in Organic Coatings, 65 (1) 94–103 (2009)

    Article  Google Scholar 

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Correspondence to G. S. Tay.

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Rozman, H.D., Tai, N.L., Sua, P.R. et al. Preparation and characterization of ultraviolet (UV) radiation curable resin from palm oil. J Coat Technol Res 13, 1009–1019 (2016).

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  • Palm oil
  • Ultraviolet
  • Glycidyl methacrylate
  • Gel permeation chromatography