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Syntheses of novel photosensitive polysiloxanes and their effects on properties of UV-cured epoxy methacrylate coatings

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Abstract

Two UV-curable polysiloxanes—side methacryloxy group polysiloxanes (MAPS) —were successfully synthesized through a two-step reaction. Two series of various percentages of these synthesized MAPS were then cured with bisphenol-A epoxy methacrylate (BEMA) via UV radiation to obtain cured coatings. We found that the additive MAPS improved the thermal stability of the cured coatings. It not only reduced the surface energy of the coatings, but also significantly affected the other properties, including gloss, flexibility, and water resistance. Compared to the phase separation between BEMA and MAPS-1 with lower volume of methacryloxy groups, MAPS-2 with higher volume of methacryloxy groups dispersed uniformly in BEMA, thereby provding good performances for such coating materials.

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Acknowledgments

This work was supported by Scientific and Technological-type, Technology Innovation Fund Project of China, Science and Technology Ministry (06C26214401627). The authors are grateful for the financial support.

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Authors and Affiliations

  1. Chinese Academy of Sciences, Guangzhou Institute of Chemistry, Guangzhou, 510650, P.R. China

    Chunyi Tang & Weiqu Liu

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100049, P.R. China

    Chunyi Tang

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  1. Chunyi Tang
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  2. Weiqu Liu
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Correspondence to Weiqu Liu.

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Tang, C., Liu, W. Syntheses of novel photosensitive polysiloxanes and their effects on properties of UV-cured epoxy methacrylate coatings. J Coat Technol Res 7, 651–658 (2010). https://doi.org/10.1007/s11998-010-9247-4

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