Abstract
This paper reports the fabrication of a lotus-effect coating by grafting epoxy (EP) resin on the surface of microsilica and nanosilica, respectively, and subsequent spraying. The coating shows the same structure and capability as lotus leaves, and shows a static contact angle as large as 165° and a sliding angle as small as 2.5°. SEM analysis shows that the hydrophobic capability depends on the surface structure of the coatings. This method may be suited for processing large scale or irregular surfaces.
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References
Feng, L, Jiang, L, “Super-Hydrophobic Surfaces: From Nature to Artificial.” Adv. Mater., 14 1857 (2002)
Sun, TL, Feng, L, Jiang, L, “Bioinspired Surfaces with Special Wetteability.” Acc. Chem. Res., 38 644 (2005)
Su, CH, Li, J, Geng, HB, Wang, QJ, Chen, QM, “Fabrication of an Optically Transparent Super-Hydrophobic Surface via Embedding Nano-Silica.” Appl. Surf. Sci., 253 2633 (2006)
Nakajima, A, Hashimoto, K, Watanable, T, “Recent Research Studies on Super-Hydrophobic Films.” Monatsheffe für Chemie, 132 31 (2001)
Xie, QD, Fan, GQ, Zhao, N, Guo, XL, Xu, J, Dong, JY, Zhang, LY, Zhang, YJ, Han, CC, “Facile Creation of a Bionic Super-Hydrophobic Block Copolymer Surface.” Adv. Mater., 16 1830 (2004)
Lu, XY, Zhang, JL, Zhang, CH, Han, YC, “Low-Density Polyethylene (LDPE) Surface with a Wettability Gradient by Tuning its Microstructure.” Macromol. Rapid Commun., 26 537 (2005)
Erbil, HY, Demirel, AL, Avci, Y, Mert, O, “Transformation of a Simple Plastic into a Superhydrophobic Surface.” Science, 299 1377 (2003)
Jiang, YG, Wang, ZQ, Yu, X, Jiang, L, “Self-Assembled Monolayers of Dendron Thiols for Electrodeposition of Gold Nanostructure: Toward Fabrication of Superhydrophobic/Superhydrophilic Surfaces and pH-Responsive Surfaces.” Langmuir, 21 1986 (2005)
Hiroshi, Y, Masafumi, T, Masaru, T, Masatsugu, S, “Superhydrophobic and Lipophobic Properties of Organized Honeycomb and Pincushion Structures.” Langmuir, 21 3235 (2005)
Li, WZ, Liang, CH, Zhou, WJ, “Preparation and Characterization of Multiwalled Carbon Nanotube-Supported Platinum Cathode Catalysts of Direct Methanol Fuel Cells.” J. Phys. Chem. B, 107 6292 (2003)
Li, WZ, Wang, X, Chen, ZG, Waji, M, Yan, Y, “Carbon Nanotube Film by Filtration as Cathode Catalyst Support for Proton-Exchange Membrance Fuel Cell.” Langmuir, 21 9386 (2005)
Sun, TL, Wang, GJ, Liu, HN, Feng, L, Jiang, L, Zhu, DB, “Control Over the Wettability of an Aligned Carbon Nanotube Film.” J. Am. Chem. Soc., 125 14996 (2003)
Wu, XD, Zheng, LJ, Wu, D, “Fabrication of Superhydrophobic Surfaces from Microstructured ZnO-Based Surfaces via a Wet-Chemical Route.” Langmuir, 21 2665 (2005)
Hosono, E, Fujihara, S, Honma, I, Zhou, HS, “Superhydrophobic Perpendicular Nano-Pin Film by the Bottom Up Process.” J. Am. Chem. Soc., 127 13458 (2005)
Zhao, N, Shi, F, Zhang, X, “Combining Layer-by-Layer Assembly with Electrodeposition of Silver Aggregates for Fabricating Superhydrophobic Surfaces.” Langmuir, 21 4713 (2005)
Liu, H, Feng, L, Zhai, J, Jiang, L, Zhu, DB, “Reversible Wettability of a Chemical Vapor Deposition Prepared ZnO Film Between Superhydrophobicity and Superhydrophilicity.” Langmuir, 20 5659 (2004)
Han, JT, Zheng, YL, Cho, JH, Xu, XR, Cho, K, “Stable Superhydrophobic Organic-Inorganic Hybrid Films by Electrostatic Self-Assembly.” J. Phys. Chem. B, 109 20773 (2005)
Singh, A, Steely, L, Allock, HR, “Poly[Bis(2,2,2-Triofluoreroethoxy)Phosphazene] Superhydrophobic Nanofibers.” Langmuir, 21 11604 (2005)
Ma, ML, Hill, MR, Lowery, JL, Fridrickh, VS, “Electrospun Poly(Styrene-Block-Dimethylsiloxane) Block Copolymer Fibers Exhibiting Superhydrophobicity.” Langmuir, 21 5549 (2005)
Shang, HM, Wang, Y, Takahashi, K, Cao, GZ, Li, D, Xia, YN, “Nanostructured Superhydrophobic Surfaces.” J. Mater. Sci., 40 3587 (2005)
Shirtcliffe, NJ, McHale, G, Newton, MI, “Intrinsically Superhtdrophobic Organosilica Sol-Gel Foams.” Langmuir, 19 5626 (2003)
Rao, AV, Kulkarni, MM, Amalnerkar, DP, Seth, T, “Superhydrophobic Silica Aerogels Based on Methyltrimethoxysilane Precursor.” J. Non-Cryst. Solid, 330 187 (2003)
Liu, YY, Chen, XQ, Xin, JH, “Super-Hydrophobic Surfaces from a Simple Coating Method: A Bionic Nanoengineering Approach.” Nanotechnology, 17 3259 (2006)
Guo, ZG, Zhou, F, Liu, WM, “Stable Biomimetic Super-Hydrophobic Engineering Materials.” J. Am. Chem. Soc., 127 15670 (2005)
Qian, BT, Shen, ZQ, “Fabrication of Superhydrophobic Surfaces by Dislocation-Selective Chemical Etching on Aluminum, Copper, and Zinc Substrates.” Langmuir, 21 9007 (2005)
Wenzel, RN, “Resistance of Solid Surface to Wetting by Water.” Ind. Eng. Chem., 28 988 (1936)
Cassie, ABD, Baxter, S, “Wetteability of Porous Surfaces.” Trans. Faraday Soc., 40 546 (1944)
Marmur, A, “The Lotus Effect: Superhydrophobicity and Metastability.” Langmuir, 20 3517 (2004)
Acknowledgments
The author is grateful to the School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, for static CA and SA measurement. The author is grateful to the Center of Analyses and Testing, Shandong University of Technology, for SEM and XPS measurement. This work was supported by the doctoral research fund of Shandong University of Technology (406040).
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Su, C. A simple and cost-effective method for fabricating lotus-effect composite coatings. J Coat Technol Res 9, 135–141 (2012). https://doi.org/10.1007/s11998-009-9230-0
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DOI: https://doi.org/10.1007/s11998-009-9230-0