Skip to main content
Log in

Characterisation of Emmental Cheeses Within Different Brand Products by Combining Infrared and Fluorescence Spectroscopies

  • Original Paper
  • Published:
Food and Bioprocess Technology Aims and scope Submit manuscript

Abstract

The potential of spectroscopic (i.e. mid-infrared and front-face fluorescence) and physicochemical methods combined with chemometric tools was investigated for discriminating Emmental cheeses produced in different regions of France. A total of 20 French Emmental cheeses belonging to different brand products were studied. When principal component analysis was applied separately to each used technique, the discrimination of cheeses was not satisfactory. Therefore, common components and specific weight analysis was applied to the whole data sets: the second common component (q 2), discriminating cheeses of producer C from the others, expressed 78 and 23 % of the inertia of the vitamin A and tryptophan, respectively. On the contrary, the third common component (q 3), discriminating cheeses as a function of their ripening time and/or their manufacturing process procedure, expressed 15, 30, and 16 % of the inertia of the 3,000–2,800, 1,700–1,500 and 1,500–900 cm−1 spectral region. The infrared and fluorescence spectral patterns allowed molecular interpretation and identification of Emmental cheeses according to their both manufacturing process and brand products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Berdagué, J. L., Grappin, R., Chaillet, B., & Clément, J. F. (1990). Caractérisation de l’Emmental "Grand-Cru" français. II. Analyses sensorielles. Le Lait, 70, 133–145.

    Article  Google Scholar 

  • Berdagué, J. L., Grappin, R., Delacroix-Buchet, A., & Chaillet, B. (1990). Caractérisation de l’Emmental "Grand-Cru" français. I. Composition physico-chimique. Le Lait, 70, 1–14.

    Article  Google Scholar 

  • Bertrand, D., & Scotter, C. N. G. (1992). Application of multivariate analyses to NIR spectra of gelatinized starch. Applied Spectroscopy, 46, 1420–1425.

    Article  CAS  Google Scholar 

  • Bouton, Y., Guyot, P., Dasen, A., & Grappin, R. (1994). Activité protéolytique de souches de lactobacilles thermophiles isolées de levain et de Comté. II—applications en sites industriels. Le Lait, 74, 33–46.

    Article  CAS  Google Scholar 

  • Chamba, J. F., & Cretin-Maintenaz, P. (1990). Les fromages à pâte cuite. In Luquet (Ed.), Laits et produits laitiers vaches, brebis, chèvres (pp. 232–250). Paris, France: Tec & Doc, Lavoisier.

    Google Scholar 

  • Dufour, E., Mazerolles, G., Devaux, M. F., Duboz, G., Duployer, M. H., & Mouhous Riou, N. (2000). Phase transition of triglycerides during semi-hard cheese ripening. International Dairy Journal, 10, 81–93.

    Article  CAS  Google Scholar 

  • Famelart, M. H., Le Gräet, Y., Michel, F., Richoux, R., & Riaublanc, A. (2002). Évaluation des méthodes d'appréciation des propriétés fonctionnelles des fromages d'Emmental de l'Ouest de la France. Le Lait, 82, 225–245.

    Article  CAS  Google Scholar 

  • Hammami, M., Rouissi, H., Salah, N., Selmi, H., Al-Otaibi, M., Blecker, C., & Karoui, R. (2010). Fluorescence spectroscopy coupled with factorial discriminant analysis technique to identify sheep milk from different feeding systems. Food Chemistry, 122, 1344–1350.

    Article  CAS  Google Scholar 

  • Karoui, R., & Blecker, C. (2011). Fluorescence and ultraviolet–visible (UV–vis) spectroscopies of intact food systems—a review. Food and Bioprocess Technology, 4, 364–386.

    Article  Google Scholar 

  • Karoui, R., & Dufour, E. (2003). Dynamic testing rheology and fluorescence spectroscopy investigations of surface to centre differences in ripened soft cheeses. International Dairy Journal, 13, 973–985.

    Article  CAS  Google Scholar 

  • Karoui, R., Dufour, E., Pillonel, L., Picque, D., Cattenoz, T., & Bosset, J. O. (2004a). Determining the geographic origin of Emmental cheeses produced during winter and summer using a technique based on the concatenation of MIR and fluorescence spectroscopic data. European Food Research and Technology, 219, 184–189.

    Article  CAS  Google Scholar 

  • Karoui, R., Dufour, E., Pillonel, L., Picque, D., Cattenoz, T., & Bosset, J. O. (2004b). Fluorescence and infrared spectroscopies: a tool for the determination of the geographic origin of Emmental cheeses manufactured during summer. Le Lait, 84, 359–374.

    Article  Google Scholar 

  • Karoui, R., Bosset, J. O., Mazerolles, G., Kulmyrzaev, A., & Dufour, E. (2005a). Monitoring the geographic origin of both experimental French Jura hard cheeses and Swiss Gruyère and l'Etivaz PDO cheeses using mid-infrared and fluorescence spectroscopies. International Dairy Journal, 15, 275–286.

    Google Scholar 

  • Karoui, R., Dufour, E., Pillonel, L., Schaller, E., Picque, D., Cattenoz, T., & Bosset, J. O. (2005b). Determination of the geographic origin of Emmental cheeses by combining infrared and fluorescence spectroscopies. International Dairy Journal, 15, 287–298.

    Article  CAS  Google Scholar 

  • Karoui, R., Martin, B., & Dufour, E. (2005c). Potentiality of front face fluorescence spectroscopy to determine the geographic origin of milks from Haute-Loire department (France). Le Lait, 85, 223–236.

    Article  Google Scholar 

  • Karoui, R., Dufour, E., & De Baerdemaeker, J. (2006a). Common components and specific weights analysis: a tool for monitoring the molecular structure of semi-hard cheese throughout ripening. Analytica Chimica Acta, 572, 125–133.

    Google Scholar 

  • Karoui, R., Mouazen, A. M., Dufour, E., Pillonel, L., Schaller, E., De Baerdemaeker, J., & Bosset, J. O. (2006b). Chemical characterisation of European Emmental cheeses by near infrared spectroscopy using chemometric tools. International Dairy Journal, 16, 1211–1217.

    Article  CAS  Google Scholar 

  • Karoui, R., Mouazen, A. M., Dufour, E., Pillonel, L., Schaller, E., Picque, D., De Baerdemaeker, J., & Bosset, J. O. (2006c). A comparison and joint use of NIR and MIR spectroscopic methods for the determination of some parameters in European Emmental cheese. European Food Research and Technology, 223, 44–50.

    Article  CAS  Google Scholar 

  • Karoui, R., Mouazen, A. M., Ramon, H., Schoonheydt, R., & Baerdemaeker, J. D. (2006d). Feasibility study of discriminating the manufacturing process and sampling zone in ripened soft cheeses using attenuated total reflectance MIR and fiber optic diffuse reflectance VIS-NIR spectroscopy. Food Research International, 39, 588–597.

    Article  CAS  Google Scholar 

  • Karoui, R., Pillonel, L., Schaller, E., Bosset, J. O., & De Baerdemaeker, J. (2006e). Prediction of sensory attributes of European Emmental cheese using near-infrared spectroscopy: a feasibility study. Food Chemistry, 101, 1121–1129.

    Article  Google Scholar 

  • Karoui, R., Thomas, E., & Dufour, E. (2006f). Utilisation of a rapid technique based on front-face fluorescence spectroscopy for differentiating between fresh and frozen-thawed fish fillets. Food Research International, 39, 349–355.

    Article  CAS  Google Scholar 

  • Karoui, R., Dufour, E., Schoonheydt, R., & Baerdemaeker, J. D. (2007). Characterisation of soft cheese by front face fluorescence spectroscopy coupled with chemometric tools: effect of the manufacturing process and sampling zone. Food Chemistry, 100, 632–642.

    Google Scholar 

  • Kulmyrzaev, A., Dufour, E., Noël, Y., Hanafi, M., Karoui, R., Qannari, E. M., & Mazerolles, G. (2005). Investigation at the molecular level of soft cheese quality and ripening by infrared and fluorescence spectroscopies and chemometrics—relationships with rheology properties. International Dairy Journal, 15, 669–678.

    Article  CAS  Google Scholar 

  • Maâmouri, O., Rouissi, H., Dridi, S., Kammoun, M., De Baerdemaeker, J., & Karoui, R. (2008). Mid infrared attenuated total reflection spectroscopy as a rapid tool to assess the quality of Sicilo-Sarde ewe’s milk during the lactation period after replacing soybean meal with scotch bean in the feed ration. Food Chemistry, 106, 361–368.

    Article  Google Scholar 

  • Mazerolles, G., Devaux, M. F., Duboz, G., Duployer, M. H., Mouhous Riou, N., & Dufour, E. (2001). Infrared and fluorescence spectroscopy for monitoring protein structure and interaction changes during cheese ripening. Le Lait, 81, 509–527.

    Article  CAS  Google Scholar 

  • Mazerolles, G., Devaux, M. F., Dufour, E., Qannari, E. M., & Courcoux, Ph. (2002). Chemometric methods for the coupling of spectroscopic techniques and for the extraction of the relevant information contained in the spectral data tables. Chemometrics and Intelligent Laboratory Systems, 63, 57–68.

    Article  CAS  Google Scholar 

  • Picque, D., Lefier, D., Grappin, R., & Corrieu, G. (1993). Monitoring of fermentation by infrared spectrometry—alcoholic and lactic fermentations. Analytical Chimica Acta, 279, 67–72.

    Article  CAS  Google Scholar 

  • Pillonel, L., Badertscher, R., Bütikofer, U., Casey, M., Dalla Torre, M., Lavanchy, P., Meyer, J., Tabacchi, R., & Bosset, J. (2002). Analytical methods for the determination of the geographic origin of Emmentaler cheese. Main framework of the project; chemical, biochemical, microbiological, colour and sensory analyses. European Food Research and Technology, 215, 260–267.

    Article  CAS  Google Scholar 

  • Pillonel, L., Luginbühl, W., Picque, D., Schaller, E., Tabacchi, R., & Bosset, J. O. (2003). Analytical methods for the determination of the geographic origin of Emmental cheese. Mid and near-infrared spectroscopy. European Food Research and Technology, 216, 179–183.

    CAS  Google Scholar 

  • Richoux, R., Roset, G., Famelart, M. H., & Kerjean, J. R. (2001). Diversité de quelques propriétés fonctionnelles à chaud de l’emmental français. Le Lait, 81, 547–559.

    Article  CAS  Google Scholar 

  • Rouissi, H., Dridi, S., Kammoun, M., De Baerdemaeker, J., & Karoui, R. (2008). Front face fluorescence spectroscopy: a rapid tool for determining the effect of replacing soybean meal with scotch bean in the ration on the quality of Sicilo-Sarde ewe’s milk during lactation period. European Food Research and Technology, 226, 1021–1030.

    Article  CAS  Google Scholar 

  • Ruoff, K., Karoui, R., Dufour, E., Luginbbühl, W., Bosset, J.-O., Bogdanov, S., & Amadò, R. (2005). Authentication of the botanical origin of honey by front-face fluorescence spectroscopy. A preliminary study. Journal of Agricultural and Food Chemistry, 53, 1343–1347.

    Article  CAS  Google Scholar 

  • SIGF. (2000). Statistique pâtes pressées cuites. Paris: SIGF.

    Google Scholar 

  • Thierry, A., Salvat-Brunaud, D., Madec, M. N., Michel, F., & Maubois, J. L. (1998). Affinage de l’emmental: dynamique des populations bactériennes et évolution de la composition de la phase aqueuse. Le Lait, 78, 521–542.

    Article  CAS  Google Scholar 

  • Zaïdi, F., Rouissi, H., Dridi, S., Kammoun, M., De Baerdemaeker, J., & Karoui, R. (2008). Front face fluorescence spectroscopy as a rapid and non-destructive tool for differentiating between Sicilo-Sarde and Comisana ewe’s milk during lactation period: a preliminary study. Food and Bioprocess Technology, 1, 143–151.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Romdhane Karoui.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Botosoa, E.P., Karoui, R. Characterisation of Emmental Cheeses Within Different Brand Products by Combining Infrared and Fluorescence Spectroscopies. Food Bioprocess Technol 6, 2365–2375 (2013). https://doi.org/10.1007/s11947-012-0875-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11947-012-0875-9

Keywords

Navigation