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Variability of ozone in the Eastern Mediterranean during a 7-year study

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Abstract

Ozone measurements have been performed in the period 2003–2009 at Akrotiri (suburban) and Finokalia (coastal) monitoring stations on the island of Crete, Greece. The main objectives were to investigate the concentration levels of ozone in the region of Crete, its spatial and temporal variability, the effect of air mass origin and local sources on ozone levels, and the frequency of exceedances of the EU limits for ozone concentrations in the area. The observed mean values for Akrotiri and Finokalia stations were 44.5 ± 8.5 and 49.1 ± 10.6 ppbv, respectively. Ozone concentrations were higher during the 8-month period between March and October (52.3 ± 6.8 and 53.0 ± 7.4 ppbv for Akrotiri and Finokalia station, respectively) whereas, in the period November–February, the concentrations were lower (37.7 ± 4.7 and 39.1 ± 6.9 ppbv, respectively). The above values indicate that there is not a west-east gradient of ozone concentration in the studied area. At both stations, AOT40 limit values were higher than the limit set by the European Union (Directive 2008/50/EC). Exceedances of the EU target value were encountered during 88 and 67 % of the time in Akrotiri and Finokalia stations, respectively. Differences on the diurnal patterns and daily ozone maxima between the two stations were attributed to the different characteristics of the two stations and to the effect of local pollution sources to Akrotiri station. The average value of the amplitude of the daily cycle (calculated as the difference between maximum and minimum values) in the case of Akrotiri was 8.3 ppbv, and it was about two times the corresponding value in Finokalia (4.7 ppbv), which is an indication of the effect of the anthropogenic emission produced in the city of Chania to the Aktotiri station environment. At Finokalia, the maximum values were observed 2–4 h later than those at Akrotiri. During springtime, the difference in the maximum values appearance was close to 4 h, with the maximum at Akrotiri at 16:00 (LT) and at Finokalia at about 20:00 (LT). This time difference supports the transfer of gaseous precursors and already formed ozone molecules toward Finokalia.

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References

  • Adame JA, Sole JG (2013) Surface ozone variations at a rural area in the northeast of the Iberian Peninsula. APR 4:130–141

    Article  CAS  Google Scholar 

  • Adame JA, Hernández-Ceballos MA, Bolívar JP, De la Morena B (2012) Assessment of an air pollution event in the southwestern Iberian Peninsula. Atmos Environ 55:245–256

    Article  CAS  Google Scholar 

  • Bonasoni P, Stohl A, Cristofanelli P, Calzolari F, Colombo T, Evangelisti F (2000) Background ozone variations at Mt. Cimone Station. Atmos Environ 34:5183–5189

    Article  CAS  Google Scholar 

  • Chang W, Heikes BG, Lee M (2004) Ozone deposition to the sea surface: chemical enhancement and wind speed dependence. Atmos Environ 38:1053–1059

    Article  CAS  Google Scholar 

  • Derwent RG, Simmonds PG, Manning AJ, Spain TG (2007) Trends over a 20–year period from 1987 to 2007 in surface ozone at the atmospheric research station, Mace Head, Ireland. Atmos Environ 41:9091–9098

    Article  CAS  Google Scholar 

  • ED (European Directive) (2002) Directive 2002/3/EC. 2002. Relating to ozone in ambient air. The European Parliament and of the Council of 12 February 2002

  • ED (European Directive) 2008 Directive 2008/50/EC. (2008) On ambient air quality and cleaner air for Europe. The European Parliament and of the Council of 21 May 2008

  • Fernández-Fernández MI, Gallego MC, García JA, Acero FJ (2011) A study of surface ozone variability over the Iberian Peninsula during the last fifty years. Atmos Environ 45:1946–1959

    Article  Google Scholar 

  • Gerasopoulos E, Kouvarakis G, Vrekoussis M, Kanakidou M, Mihalopoulos N (2005) Ozone variability in the marine boundary layer of the eastern Mediterranean based on 7-year observations. J Geophys Res 110(D15):1984–2012

    Article  Google Scholar 

  • Gerasopoulos E, Kouvarakis G, Vrekoussis M, Donoussis C, Mihalopoulos N, Kanakidou M (2006) Photochemical ozone production in the Eastern Mediterranean. Atmos Environ 40:3057–3069

    Article  CAS  Google Scholar 

  • Jaffe DA, Wigder NL (2012) Review: Ozone production from wildfires: A critical review. Atmos Environ 51:1–10

    Article  CAS  Google Scholar 

  • Jaffe D, Price H, Parrish D, Goldstein A, Harris J (2003) Increasing background ozone during spring on the west coast of North America. Geophys Res Lett 30(12)

  • Jhun I, Coull BA, Zanobetti A, Koutrakis P (2014) The impact of nitrogen oxides concentration decreases on ozone trends in the USA. Air Qual Atmos Health 23:1–10

    Google Scholar 

  • Kalabokas PD, Mihalopoulos N, Ellul R, Kleanthous S, Repapis CC (2008) An investigation of the meteorological and photochemical factors influencing the background rural and marine surface ozone levels in the Central and Eastern Mediterranean. Atmos Environ 42:7894–7906

    Article  CAS  Google Scholar 

  • Kleanthous S, Vrekoussis M, Mihalopoulos N, Kalabokas P, Lelieveld J (2014) On the temporal and spatial variation of ozone in Cyprus. Sci Total Environ 476:677–687

    Article  Google Scholar 

  • Kopanakis I, Eleftheriadis K, Mihalopoulos N, Lydakis-Simantiris N, Katsivela E, Pentari D, Zarmpas P, Lazaridis M (2012) Physico-chemical characteristics of Particulate Matter in the Eastern Mediterranean. Atmos Res 106:93–107

    Article  CAS  Google Scholar 

  • Kouvarakis G, Vrekoussis M, Mihalopoulos N, Kourtidis K, Rappenglueck B, Gerasopoulos E, Zerefos C (2000) Spatial and temporal variability of tropospheric ozone (O3) in the boundary layer above the Aegean Sea (eastern Mediterranean). J Geophys Res 107(D18)

  • Lazaridis M, Dzumbova L, Kopanakis I, Ondracek J, Glytsos T, Aleksandropoulou V, Voulgarakis A, Katsivela E, Mihalopoulos N, Eleftheriadis K (2008) PM10 and PM2.5 levels in the Eastern Mediterranean (Akrotiri Research Station, Crete, Greece). Water, Air, Soil Pollut 189:85–101

    Article  CAS  Google Scholar 

  • Lin CH, Lai CH, Wu YL, Chen MJ (2010) Simple model for estimating dry deposition velocity of ozone and its destruction in a polluted nocturnal boundary layer. Atmos Environ 44:4364–4371

  • Millán MM, Mantilla E, Salvador R, Carratalá A, Sanz MJ, Alonso L, Gangoiti G, Navazo M (2000) Ozone Cycles in the Western Mediterranean Basin: Interpretation of Monitoring Data in Complex Coastal Terrain. J Appl Meteorol 39:487–508

    Article  Google Scholar 

  • Monks PS (2000) A review of the observations and origins of the spring ozone maximum. Atmos Environ 34:3545–3561

    Article  CAS  Google Scholar 

  • Monteiro A, Carvalho A, Ribeiro I, Scotto M, Barbosa S, Alonso A, Baldasano JM, Pay MT, Miranda AI, Borrego C (2012) Trends in ozone concentrations in the Iberian Peninsula by quantile regression and clustering. Atmos Environ 56:184–193

    Article  CAS  Google Scholar 

  • NOAA Air Resources Laboratory (2002) Archived backward trajectories on the: https://www.arl.noaa.gov/ready/sec/hysplit4.html

  • Nolle M, Ellul R, Heinrich G, Güsten H ( 2002) A long-term study of background ozone concentrations in the central Mediterranean – diurnal and seasonal variations on the island of Gozo. Atmos Environ 36:1391–1402

  • Notario A, Bravo I, Adame JA, Díaz-de-Mera Y, Aranda A, Rodríguez A, Rodríguez D (2012) Analysis of NO, NO2, NOx, O3 and oxidant (OX= O3+ NO2) levels measured in a metropolitan area in the southwest of Iberian Peninsula. Atmos Res 104:217–226

    Article  Google Scholar 

  • Oltmans S, Lefohn A, Harris J, Galbally I, Scheel H, Bodeker G, Brunke E, Claude H, Tarasick D, Johnson B, Simmonds P, Shadwick D, Anlauf K, Schmidlin F, Fujimoto T, Akagi K, Meyer C, Nichol S, Davies J, Redondas A, Cuevas E (2006) Long-term changes in tropospheric ozone. Atmos Environ 40:3156–3173

    Article  CAS  Google Scholar 

  • Oltmans SJ, Lefohn AS, Shadwick D, Harris JM, Scheel HE, Galbally I, Tarasick DW, Johnson BJ, Brunke E-G, Claude H, Zeng G, Nichol S, Schmidlin F, Davies J, Cuevas E, Redondas A, Naoe H, Nakano T, Kawasato T (2013) Recent tropospheric ozone changes - A pattern dominated by slow or no growth. Atmos Environ 67:331–351

    Article  CAS  Google Scholar 

  • Ou Yang CF, Lin NH, Sheu GR, Lee CT, Wang JL (2012) Seasonal and diurnal variations of ozone at a high-altitude mountain baseline station in East Asia. Atmos Environ 46:279–288

    Article  CAS  Google Scholar 

  • Peng RD, Samoli E, Pham L, Dominici F, Touloumi G, Ramsay T, Samet JM (2013) Acute effects of ambient ozone on mortality in Europe and North America: results from the APHENA study. Air Qual Atmos Health 6(2):445–453

    Article  CAS  Google Scholar 

  • Preisler HK, Zhong S, Esperanza A, Brown TJ, Bytnerowicz A, Tarnay L (2010) Estimating contribution of wildland fires to ambient ozone levels in National Parks in the Sierra Nevada, California. Environ Pollut 158:778–787

    Article  CAS  Google Scholar 

  • Reid N, Yap D, Bloxam R (2008) The potential role of background ozone on current and emerging air issues: An overview. Air Qual Atmos Health 1(1):19–29

    Article  CAS  Google Scholar 

  • Salmond JA, McKendry IG (2002) Secondary ozone maxima in a very stable nocturnal boundary layer: observations from the Lower Fraser Valley, BC. Atmos Environ 36:5771–5782

    Article  CAS  Google Scholar 

  • Sicard P, Dalstein-Richier L, Vas N (2011) Annual and seasonal trends of ambient ozone concentration and its impact on forest vegetation in Mercantour National Park (South-eastern France) over the 2000-2008 period. Environ Pollut 159:351–362

    Article  CAS  Google Scholar 

  • Szyszkowicz M, Porada E, Searles G, Rowe BH (2012) Ambient ozone and emergency department visits for skin conditions. Air Qual Atmos Health 5(3):303–309

    Article  CAS  Google Scholar 

  • Velchev K, Cavalli F, Hjorth J, Marmer E, Vignati E, Dentener F, Raes F (2011) Ozone over the Western Mediterranean Sea—results from two years of shipborne measurements. Atmos Chem Phys 11:675–688

    Article  CAS  Google Scholar 

  • Wang Y, Hu B, Tang G, Ji D, Zhang H, Bai J, Wang Y (2013) Characteristics of ozone and its precursors in Northern China: A comparative study of three sites. Atmos Res 132:450–459

    Article  Google Scholar 

  • Zanis P, Hadjinicolaou P, Pozzer A, Tyrlis E, Dafka S, Mihalopoulos N, Lelieveld J (2014) Summertime free tropospheric ozone pool over the Eastern Mediterranean/Middle East. Atmos Chem Phys 14:115–132

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. School of Environmental Engineering, Technical University of Crete, Chania, Greece

    I. Kopanakis, T. Glytsos & M. Lazaridis

  2. Department of Chemistry, University of Crete, Heraklion, Greece

    G. Kouvarakis & N. Mihalopoulos

  3. Institute for Environmental Research & Sustainable Development, National Observatory of Athens, Athens, Greece

    E. Gerasopoulos

  4. Navarino Environmental Observatory, Messenia, Greece

    E. Gerasopoulos

Authors
  1. I. Kopanakis
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  2. T. Glytsos
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  3. G. Kouvarakis
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  4. E. Gerasopoulos
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  5. N. Mihalopoulos
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  6. M. Lazaridis
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Correspondence to M. Lazaridis.

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Kopanakis, I., Glytsos, T., Kouvarakis, G. et al. Variability of ozone in the Eastern Mediterranean during a 7-year study. Air Qual Atmos Health 9, 461–470 (2016). https://doi.org/10.1007/s11869-015-0362-3

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  • DOI: https://doi.org/10.1007/s11869-015-0362-3

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