Abstract
Landfill leachate treated with combined process of “pretreatment +biological treatment +advanced treatment (NF)” to produce nanofiltration concentrate, which bio-chemical ratio (B/C) is less than 0.1 and CODcr concentration is 2 000–2 500 mg/L, high salt content. Which cannot be discharged under existing environmental standards. According to analysis based on electrochemical advanced oxidation mechanism, a two-step electrochemical technique was recommended. In the first step, a pulse electrochemical technique was adopted. With Fe as consumption electrode and current density of 10 mA/cm2, the pollutants were removed by means of Fenton reaction, electroflotation and electrocoagulation. In the second step, a double function electrode was used to perform electrocatalytic oxidation by means of titanium metallic oxidates. In the condition that current density being 12.5 mA/cm2, the pollutants were further removed by oxidation and electrolytic deposition. Result shows that the removing rate of CODcr, NH3-N and Cl- were 70%–85%, 90% and 25%, respectively; average value of B/C ratio increased from 0.09 to 0.38 and conductivity reduced by 10%.
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Biography: XIONG Changgui, male, Professor, Master, research direction: water and wastewater treatment on technical research, engineering consultation and design.
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Xiong, C., Li, G., Zhang, Z. et al. Technique for advanced electrochemical oxidation treatment of nanofiltration concentrate of landfill leachate. Wuhan Univ. J. Nat. Sci. 19, 355–360 (2014). https://doi.org/10.1007/s11859-014-1025-1
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DOI: https://doi.org/10.1007/s11859-014-1025-1
Key words
- nanofiltration concentrate of landfill leachate
- electrochemistry
- advanced oxidation
- pulse
- electrode
- pollutants