Abstract
Flavonols are plant pigments that are ubiquitous in nature. Morin and other related plant flavonols have come into recent prominence because of their usefulness as anticancer, anti-tumor, anti-AIDS, and other important therapeutic activities of significant potency and low systemic toxicity. The heat of combustion of morin (molecular formula, C15H10O7·H2O) in oxygen was measured by a rotating-bomb type combustion calorimeter, the standard molar enthalpy of combustion of morin at T = 298.15 K was determined to be Δc H ⦵m (C15H10O7·H2O, s) = −(5 937.99 ± 2.99) kJ · mol−1. The derived standard molar enthalpy of the formation of morin in solid powder state at T = 298.15 K, Δf H ⦵m (C15H10O7·H2O, s), was −(1 682.12 ± 3.58) kJ · mol−1, which provide an accurate data of the stability of morin to the pharmacy and pharmacology.
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References
Harbome J B, Williams C A. Advances in Flavonoid Research Since 1992[J]. Phytochemistry, 2000, 55:481–504.
Kopacz M, Woźnicka E, Gruszecka J. Antibacterial Activity of Morin and its Complexes with La(III), Gd(III) and Lu(III) Ions[J]. Acta Pol Pharm, 2005, 62:65–67.
Arima H, Ashida H, Danno G I. Rutin-Enhanced Antibacterial Activities of Flavonoids Against Bacillus cereus and Salmonella enteritidis [J]. Biosci Biotechnol Biochem, 2002, 66: 1009–1014.
Chung S Y, Sung M K, Kim N H, et al. Inhibition of P-Glycoprotein by Natural Products in Human Breast Cancer Cells[J]. Arch Pharm Res, 2005, 28: 823–828.
Song Y, Kang J, Wang Z, et al. Study on the Interactions Between CuCl2 and Morin with DNA[J]. J Inorg Biochem, 2002, 91: 470–474.
Song Y, Yang P, Yang M. Spectroscopic and Voltammetric Studies of the Cobalt (II) Complex of Morin Bound to Calf Thymus DNA[J]. Transition Met Chem, 2003, 28: 712–716.
Alldrick A J, Flynn J, Rowland I R. Effects of Plant-Derived Flavonoids and Polyphenolic Acids on the Activity of Mutagens from Cooked Food[J]. Mutat Res, 1986, 163: 225–232.
Slater T F, Sawyer B C. The Stimulatory Effects of Carbon Tetrachloride and Other Halogenoalkanes on Peroxidative Reactions in Rat Liver Fractions in vitro[J]. Biochem J, 1971, 123: 805–814.
Zhang Q, Wang L F, Liu X, et al. Synthesis, Characterization and Antitumour Properties of Metal(II) Solid Complexes with Morin[J]. Transition Met Chem, 1996, 21: 23–27.
Qin shuqi. Thermodynamic Properties of the Morin Cobalt (II) Complex System[J]. J Wuhan Univ (Nat Sci Ed), 2005, 51(6): 687–690(Ch).
Bao H, Ren H, Endo H, et al. Effects of Heating and the Addition of Seasonings on the Anti-Mutagenic and Anti-Oxidative Activities of Polyphenols[J]. Food Chem, 2004, 86: 517–524.
Maksimuk Y V, Sokolov V D, Serruk V M, et al. Standard Enthalpies of Formation for Some Semi-Products at the Synthesis of Poly(Ethylene) Terephthalate[J]. J Therm Anal Cal, 2001, 65: 965–970.
Nagano Y. Standard Enthalpy of Formation of Platinum Hydrous Oxide[J]. J Therm Anal Cal, 2002, 69: 831–839.
Xie G, Chen S, Jiao B, et al. Crystal Structure and the Standard Molar Enthalpy of Formation of a Coordination Polymer [Cu(nip)(phen)] n [J]. Thermochim Acta, 2006, 443: 53–55.
Yang X W, Chen S P, Gao S L, et al. Construction of A Rotating-Bomb Combustion Calorimeter and Measurement of Thermal Effects[J]. Instrum Sci Technol, 2002, 30: 311–322.
Dong J X, Li Q, Tan Z C, et al. The Standard Molar Enthalpy of Formation, Molar Heat Capacities, and Thermal Stability of Anhydrous Caffeine[J]. J Chem Thermodynamics, 2007, 39:108–114.
Ren F, Yang X W, Gao S L, et al. Thermochemical Properties of Crown Ether Compounds[J]. Thermochim Acta, 2001, 375:85–91.
Yu H G, Dong J X, Qin C Q, et al. Standard Enthalpy of Formation of 3, 4, 5-Trimethoxybenzoic Acid[J]. J Therm Anal Cal, 2004, 75: 807–813.
Pinto S S, Diogo H P. Thermochemical Study of Two Anhydrous Polymorphs of Caffeine[J]. J Chem Thermodynaics, 2006, 38: 1515–1522.
Coplen T B. Atonic Weights of the Elements 1999[J]. Pure Appl Chem, 2001, 73: 667–683.
Treiner C, Tzias P. Thermodynamic Transfer Functions for Urea and Thiourea from Water to Water-Tetrahydrofuran Mixtures from Precise Vapor-Pressure Measurements[J]. J Solution Chem, 1975, 4: 471–483.
Chou M, Seal R R. Determination of Goslarite-Bianchite Equilibria by the Humidity-Buffer Technique at 0.1 MPa[J]. Chem Geol, 2005, 215: 517–523.
Liebman J F, SimÕes J A M, Slayden S W. The Enthalpy of Formation of Methyl Fluoride[J]. Struct Chem, 1995, 6: 65–69.
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Foundation item: Supported by the National Natural Science Foundation of China (30570015, 20621502), the Natural Science Foundation of Hubei Province (2005ABC002) and the Research Foundation of Chinese Ministry of Education ([2006]8-IRT0543)
Biography: HOU Hanna(1956–), female, Visiting researcher, Associate professor of Hubei University of Education, research direction: thermochemistry.
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Hou, H., Dong, J. & Liu, Y. Standard molar enthalpy of formation of morin studied by rotating-bomb combustion calorimetry. Wuhan Univ. J. Nat. Sci. 13, 103–106 (2008). https://doi.org/10.1007/s11859-008-0120-6
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DOI: https://doi.org/10.1007/s11859-008-0120-6