Skip to main content
Log in

Standard molar enthalpy of formation of morin studied by rotating-bomb combustion calorimetry

  • Published:
Wuhan University Journal of Natural Sciences

Abstract

Flavonols are plant pigments that are ubiquitous in nature. Morin and other related plant flavonols have come into recent prominence because of their usefulness as anticancer, anti-tumor, anti-AIDS, and other important therapeutic activities of significant potency and low systemic toxicity. The heat of combustion of morin (molecular formula, C15H10O7·H2O) in oxygen was measured by a rotating-bomb type combustion calorimeter, the standard molar enthalpy of combustion of morin at T = 298.15 K was determined to be Δc H m (C15H10O7·H2O, s) = −(5 937.99 ± 2.99) kJ · mol−1. The derived standard molar enthalpy of the formation of morin in solid powder state at T = 298.15 K, Δf H m (C15H10O7·H2O, s), was −(1 682.12 ± 3.58) kJ · mol−1, which provide an accurate data of the stability of morin to the pharmacy and pharmacology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Harbome J B, Williams C A. Advances in Flavonoid Research Since 1992[J]. Phytochemistry, 2000, 55:481–504.

    Article  Google Scholar 

  2. Kopacz M, Woźnicka E, Gruszecka J. Antibacterial Activity of Morin and its Complexes with La(III), Gd(III) and Lu(III) Ions[J]. Acta Pol Pharm, 2005, 62:65–67.

    Google Scholar 

  3. Arima H, Ashida H, Danno G I. Rutin-Enhanced Antibacterial Activities of Flavonoids Against Bacillus cereus and Salmonella enteritidis [J]. Biosci Biotechnol Biochem, 2002, 66: 1009–1014.

    Article  Google Scholar 

  4. Chung S Y, Sung M K, Kim N H, et al. Inhibition of P-Glycoprotein by Natural Products in Human Breast Cancer Cells[J]. Arch Pharm Res, 2005, 28: 823–828.

    Article  Google Scholar 

  5. Song Y, Kang J, Wang Z, et al. Study on the Interactions Between CuCl2 and Morin with DNA[J]. J Inorg Biochem, 2002, 91: 470–474.

    Article  Google Scholar 

  6. Song Y, Yang P, Yang M. Spectroscopic and Voltammetric Studies of the Cobalt (II) Complex of Morin Bound to Calf Thymus DNA[J]. Transition Met Chem, 2003, 28: 712–716.

    Article  Google Scholar 

  7. Alldrick A J, Flynn J, Rowland I R. Effects of Plant-Derived Flavonoids and Polyphenolic Acids on the Activity of Mutagens from Cooked Food[J]. Mutat Res, 1986, 163: 225–232.

    Google Scholar 

  8. Slater T F, Sawyer B C. The Stimulatory Effects of Carbon Tetrachloride and Other Halogenoalkanes on Peroxidative Reactions in Rat Liver Fractions in vitro[J]. Biochem J, 1971, 123: 805–814.

    Google Scholar 

  9. Zhang Q, Wang L F, Liu X, et al. Synthesis, Characterization and Antitumour Properties of Metal(II) Solid Complexes with Morin[J]. Transition Met Chem, 1996, 21: 23–27.

    Google Scholar 

  10. Qin shuqi. Thermodynamic Properties of the Morin Cobalt (II) Complex System[J]. J Wuhan Univ (Nat Sci Ed), 2005, 51(6): 687–690(Ch).

    Google Scholar 

  11. Bao H, Ren H, Endo H, et al. Effects of Heating and the Addition of Seasonings on the Anti-Mutagenic and Anti-Oxidative Activities of Polyphenols[J]. Food Chem, 2004, 86: 517–524.

    Article  Google Scholar 

  12. Maksimuk Y V, Sokolov V D, Serruk V M, et al. Standard Enthalpies of Formation for Some Semi-Products at the Synthesis of Poly(Ethylene) Terephthalate[J]. J Therm Anal Cal, 2001, 65: 965–970.

    Article  Google Scholar 

  13. Nagano Y. Standard Enthalpy of Formation of Platinum Hydrous Oxide[J]. J Therm Anal Cal, 2002, 69: 831–839.

    Article  Google Scholar 

  14. Xie G, Chen S, Jiao B, et al. Crystal Structure and the Standard Molar Enthalpy of Formation of a Coordination Polymer [Cu(nip)(phen)] n [J]. Thermochim Acta, 2006, 443: 53–55.

    Article  Google Scholar 

  15. Yang X W, Chen S P, Gao S L, et al. Construction of A Rotating-Bomb Combustion Calorimeter and Measurement of Thermal Effects[J]. Instrum Sci Technol, 2002, 30: 311–322.

    Article  Google Scholar 

  16. Dong J X, Li Q, Tan Z C, et al. The Standard Molar Enthalpy of Formation, Molar Heat Capacities, and Thermal Stability of Anhydrous Caffeine[J]. J Chem Thermodynamics, 2007, 39:108–114.

    Article  Google Scholar 

  17. Ren F, Yang X W, Gao S L, et al. Thermochemical Properties of Crown Ether Compounds[J]. Thermochim Acta, 2001, 375:85–91.

    Article  Google Scholar 

  18. Yu H G, Dong J X, Qin C Q, et al. Standard Enthalpy of Formation of 3, 4, 5-Trimethoxybenzoic Acid[J]. J Therm Anal Cal, 2004, 75: 807–813.

    Article  Google Scholar 

  19. Pinto S S, Diogo H P. Thermochemical Study of Two Anhydrous Polymorphs of Caffeine[J]. J Chem Thermodynaics, 2006, 38: 1515–1522.

    Article  Google Scholar 

  20. Coplen T B. Atonic Weights of the Elements 1999[J]. Pure Appl Chem, 2001, 73: 667–683.

    Article  Google Scholar 

  21. Treiner C, Tzias P. Thermodynamic Transfer Functions for Urea and Thiourea from Water to Water-Tetrahydrofuran Mixtures from Precise Vapor-Pressure Measurements[J]. J Solution Chem, 1975, 4: 471–483.

    Article  Google Scholar 

  22. Chou M, Seal R R. Determination of Goslarite-Bianchite Equilibria by the Humidity-Buffer Technique at 0.1 MPa[J]. Chem Geol, 2005, 215: 517–523.

    Article  Google Scholar 

  23. Liebman J F, SimÕes J A M, Slayden S W. The Enthalpy of Formation of Methyl Fluoride[J]. Struct Chem, 1995, 6: 65–69.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yi Liu.

Additional information

Foundation item: Supported by the National Natural Science Foundation of China (30570015, 20621502), the Natural Science Foundation of Hubei Province (2005ABC002) and the Research Foundation of Chinese Ministry of Education ([2006]8-IRT0543)

Biography: HOU Hanna(1956–), female, Visiting researcher, Associate professor of Hubei University of Education, research direction: thermochemistry.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hou, H., Dong, J. & Liu, Y. Standard molar enthalpy of formation of morin studied by rotating-bomb combustion calorimetry. Wuhan Univ. J. Nat. Sci. 13, 103–106 (2008). https://doi.org/10.1007/s11859-008-0120-6

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11859-008-0120-6

Key words

CLC number

Navigation