Abstract
The distribution of Cr between water, total suspended matter (TSM) and sediments in the maine harbour in Egypt (Western Harbour), has been studied in two surveys. Dissolved Cr displayed a negative association with salinity, indicating land sources outlets as a major source of inputs for it. The Harbour presents higher Cr concentrations in dissolved form above the background (0.17 μg/L) concentration for total dissolved Cr. The most important factors controlling the distribution of particulate Cr in the Western Harbour are the depositional from several activities inside the Harbour, as well as different charges from several landbased sources along its southern edge. Chromium was associated in decreasing amount in the: residual >oxidizable-organic >acid reducible >exchangeable fractions of the analyzed sediments. Therefore, the results indicate that Cr in sediments from W.H is not available for exchange and/or release into the marine environment.
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Abdallah MAM (2003) The chemical changes in Lake Maryout after the construction of the two waste treatment plants, Ph.D. thesis, Alexandria University. pp.306
Abdallah MAM (2007) Speciation of trace metals in coastal sediments of El-Mex bay south Mediterranean Sea–West of Alexandria (Egypt). Environ Monit Assess 132:111–123
Abdallah MAM (2008) Trace metal behavior in Mediterranean-climate coastal bay: El-Mex Bay, Egypt and its coastal environment. Glob J Environ Res 2(1):23–29
Abdallah MAM, El Sayed NB, Saad MA (2007) Distribution and enrichment evaluation of heavy metals in El-Mex Bay using normalization models. Fresenius Environ Bull 16(7):710–719
Aboul Dahab O, Al-Madfaba H (1997) Chromium distribution in waters and sediments of the eastern side of The Qatari Peninsula. Sci Total Environ 196:I–11
Abu-Hilal AH (1993) Observations on heavy metal geochemical association in marine sediments of the Jordan Gulf of Aqaba. Mar Pollut Bull 26:85–90
APHA (1995) Standard methods for the examination of water and wastewater, 9th edn. American Public Health Association, New York
Badri MA, Aston SR (1983) Observation on heavy metal geochemical associations in polluted and nonpolluted estuarine sediments. Environ Pollut (Series B) 6:181
Barakat AO, Kim M, Qian Y, Wade TL (2002) Organochlorine pesticides and PCB residues in sediments of Alexandria harbour, Egypt. Mar Pollut Bull 44:1421–1434
Bortone G, Arevalo E, Deibel I, Detzner HD, de Propris L, Elskens F, Giordano A, Hakstege P, Hamer K, Harmsen J, Hauge A, Palumbo L, vanVeen J (2004) Sediment and dredged material treatment. J Soil Sediment 4:225–232
Boyle EA, Edmond JM, Sholkovitz ER (1977) The mechanism of iron removal in estuaries. Geochim Cosmochim Acta 41:1313–1324
Calmano W, Hong J, Forstner U (1993) Binding and mobilization of heavy metals in contaminated sediments affected by pH and redox potential. Water Sci Technol 28:223–235
Chen Z, Saito Y, Kanai Y, Wei T, Li L, Yao H, Wang Z (2004) Low concentration of heavy metals in the Yangtze estuarine sediments, China: a diluting setting. Estuar Coast Shelf Sci 60:91–100
El-Nady FE (1996) Heavy metal pollution problems in the southeastern Mediterranean waters of Alexandria, Egypt. Proceeding of the 6 international Conference on Environmental Protection is a Must. NIFO, VEA, ISA and SFD, Alexandria, Egypt, 21–32 May 1996, pp: 364–381
El-Sayed MK, El-Wakeel SK, Refaat AE (1988) Factor analysis of sediments in the Alexandria western Harbour. Egypt Oceanologica Acta 11:1–11
Fowler SW, Knauer GA (1986) Role of large particles in the transport of elements and organic compounds through the oceanic water column. Prog Ocean 16:147–194
Guerra-Garcia JM, Garcia-Gomez JC (2005) Assessing pollution levels in sediments of a Harbour with two opposing entrance. Environmental implications. J Environ Manag 77:1–11
Guevara-Riba A, Sahuquillo A, Rubio R, Rauret G (2004) Assessment of metal mobility in dredged harbour sediments from Barcelona. Spain Sci Total Environ 321:241–255
Håkanson L (1980) Ecological risk index for aquatic pollution control: a sedimentological approach. Water Res 14:975–1001
Huh CA, Finney BP, Stull JK (1992) Anthropogenic inputs of several heavy metals to nearshore basins off Los Angeles. Prog Oceanogr 30:335–351
Kermling K (1983) Determination of trace metals. In: Grasshoff K, Ehrhardt M, Kremling KL (eds) Methods of sea water analysis. Weinhem, Verlag Chemie, pp I46–I191
Khwaja AR, Singh R, Tandom SN (2001) Monitoring of Ganga water and sediments vis-á-vis tannery pollution at Kanpur (India): a case study. Environ Monit Assess 68:19–35
Loring DH, Rantala RTT (1992) Manual for geochemical analysis. Earth Sci Rev 32:235–283
Morans B, Woods LW (1997) Cd, Cr, Cu, Ni and Pb in the water column and sediments of the Ob-Irtysh Rivers, Russia. Manta Poll Bull 35:270–279
Morillo J, Usero J, Gracia I (2004) Heavy metal distribution in marine sediments from the southwest coast of Spain. Chemosphere 55:431–442
Mostafa AR, Barakat AO, Qian Y, Wade TL (2003) Composition, distribution and sources of polycyclic aromatic hydrocarbons in sediments of the western harbour of Alexandria, Egypt. J Soils Sediments 3:173–179
Muniz P, Danulat E, Yannicelli B, García-Alonso J, Medina G, Bícego MC (2004) Assessment of contamination by heavy metals and petroleum hydrocarbons in sediments of Montevideo Harbour (Uruguay). Environ Int 29:1019–1028
Ohta A, Imai N, Teraashima S, Tachibana Y, Ikehara K, Nakajima T (2004) Geochemical mapping in Hokuriku, Japan: influence of surface geology, mineral occurrences and mass movement from terrestrial to marine environments. Appl Geochem 19:1453–1469
Pazos-Capeáns P, Barciela-Alonso MC, Herbello-Hermelo P, Bermejo-Barrera P (2010) Estuarine increase of chromium surface sediments: Distribution, transport and time evolution. Microchemical Journal 96:362–370
Pertsemli E, Voutsa D (2007) Distribution of heavy metals in Lakes Doirani and Kerkini, Northern Greece. J Hazard Mater 148:529–537
Rosa F, Tort L, Torres P (1990) Mediterranean aqua cultural. In: Horwood E (ed) New York, London Toronto, Sydney Tokyo, p 213
Saad MA, Beltagy AI, Mahmoud WM (2003) Total dissolved and particulate lead in the Western Harbour of Alexandria, a Mediterranean basin under stress. Mar Poll Bull 47:52–58
Salem AY, Sharkawi FM (1981) Industrial wastes released to the aquatic environment in Mex area, Aquat. Pollut. Project, EGY/73/058/A/01/13, Project Rep
Salomons W, de Rooij NM, Bril J (1987) Sediments as a source of contaminants. Hydrobiology 149:13–30
Samir AM, Badr El-Din A (2001) Benthic foraminiferal assemblages and morphological abnormalities as pollution proxies in two Egyptian bays. Mar Micropaleont 41:193–227
Sharaf El-Din SH, Farag MM (1981) Preliminary report on the hydrography structure and circulation pattern of El-Mex, West. Harbour Aquat. Poli ut. Project, EGY/73/058/A/01/13, Project Rep
Slooff W, Bont PFH, Janus JA, Loos B (1992) Exploratory report nickel and nickel compounds. RIVM report n. 710401 017
Smołka-Danielowska D (2006) Heavy metals in fly ash from a coal-fired power station in Poland. Polish J Environ Stud 15(6):943–946
Takarina ND, Browne DR, Risk MJ (2004) Speciation of heavy metals in coastal sediments of Semarang, Indonesia. Mar Pollut Bull 49:854–874
The Cuong D, Obbard JP (2006) Metal speciation in coastal marine sediments from Singapore using a modified BCR-sequential extraction procedure. Appl Geochem 21:1335–1346
UN ESCAP (2002) Commercial development of regional ports as logistics centres, transport and tourism division (TTD) Eds, vol ST/ESCAP/2194. United Nations, NewYork
Violintzis C, Arditsoglou A, Vou D (2009) Elemental composition of suspended particulate matter and sediments in the coastal environment of Thermaikos Bay, Greece: delineating the impact of inland waters and wastewaters. J Hazard Mater 166:1250–1260
WDOE, Sediment Management Standards (1995) Olympia, WA: Washington State Department of Ecology (Chapter 173-204-320) WAC
Yap CK, Ismail A, Tan SG, Omar H (2002) Concentrations of Cu and Pb in the offshore and intertidal sediments of the west coast of Peninsular Malaysia. Environ Int 28:467
Yuan C, Shi J, He B, Liu J, Liang L, Jiang G (2004) Speciation of heavy metals in marine sediments from the East China Sea by ICP-MS with sequential extraction. Environ Int 30:769–783
Zheng S, Wang P, Wang C, Hou J, Qian J (2012) Distribution of metals in water and suspended particulate matter during the resuspension processes in Taihu Lake sediment, China. Quaternary International pp 1–9
Zhou JL, Liu YP, Abrahams PW (2003) Trace metal behaviour in the Conwy estuary, North Wales. Chemosphere 51:429–440
Zwolsman JJG, van Eck GTM (1999) Geochemistry of major elements and trace metals in suspended matter of the Scheldt estuary, southwest Netherlands. Mar Chem 66:91–111
Acknowledgment
The author would like to thank Dr. Ahmed Radwan a lecturer in the physical oceanography lab, NIOF, for his assistant in collecting the samples. Also the thanks to the anonymous reviewer who constructive comments significantly improved this paper.
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Abdallah, M.A.M. Chromium geochemistry in coastal environment of the Western Harbour, Egypt: water column, suspended matter and sediments. J Coast Conserv 18, 1–10 (2014). https://doi.org/10.1007/s11852-013-0288-6
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DOI: https://doi.org/10.1007/s11852-013-0288-6