Abstract
Since the introduction of the LixC/LiCoO2 cell, rechargeable lithium batteries have become the technology of choice for applications where volume or weight are a consideration (e.g., laptop computers and cell phones). The focus of current research in cathodeactive materials is on less-expensive or higher-performance materials than LiCoO2. This article illustrates how first-principles calculations can play a critical role in obtaining the understanding needed to design improved cathode oxides.
Similar content being viewed by others
References
U.S. Department of the Interior, Geological Survey Lithium (Washington, D.C.: U.S. Geological Survey, 1996).
H. Takeshita, Nomura Research Institute Ltd Report, Power 97 (consulting report 1997).
D. Linden, Handbook of Batteries (New York: McGraw-Hill, 1994).
W. Xing and J.R. Dahn, J. of the Electrochem. Soc., 144 (1997), pp. 1195–1201.
M.M. Thackeray, Prog. Solid. St. Chem., 25 (1997), pp. 1–71.
G.G. Amatucci et al., J. of Power Sources, 69 (1997), pp. 11–25.
Y. Gao and J.R. Dahn, Solid State Ionics, 84 (1996), pp. 33–40.
T. Ohzuku and U. Atsushi, Solid State Ionics, 69 (1994), pp. 201–211.
G.G. Amatucci, J.M. Tarascon, and L.C. Klein, J. Electrochem. Soc., 143 (1996), pp. 1114–1123.
D. de Fontaine, Solid State Physics, vol. 47, eds. H. Ehrenreich and D. Turnbull (New York: Academic Press, 1994), pp. 33–176.
G. Ceder et al., J. of Electroceramics, 1 (1997), pp. 15–26.
G. Ceder et al., J. of the Amer. Ceramics Soc., 81 (1998).
A. Van der Ven, M.K. Aydinol, and G. Ceder, Mat. Res. Soc. Proc. (in press).
M.K. Aydinol et al., Physical Review B, 56 (1997), pp. 1354–1365.
W.R. McKinnon, Solid State Electrochemistry, ed. P.G. Bruce (New York: Cambridge University Press, 1995), pp. 163–198.
G. Kresse and J. Furthmüller, Comput. Mat. Sci., 6 (1996), p. 15.
G. Ceder et al., Nature, 392 (1998), pp. 694–696.
B. Zachau-Christiansen et al., Solid State Ionics, Diffusion & Reactions, 40/41 (1990), pp. 580–584.
J.M. Tarascon et al., J. Electrochem. Soc., 138 (1991), pp. 2859–2864.
J.N. Reimers and J.R. Dahn, J. Electrochem. Soc., 139 (1992), pp. 2091–2097.
J.B. Goodenough et al., Revue de Chimie Minerale, 21 (1984), pp. 435–455.
T. Ohzuku and A. Ueda, J. Electr Soc., 141 (1994), pp. 2972–2977.
J. van Elp et al., Phys. Rev. B, 44 (1991), pp. 6090–6103.
J. Molenda, A. Stoklosa, and T. Bak, Solid State Ionics, Diffusion & Reactions, 36 (1989), pp. 53–58.
A. Van der Ven et al., Phys. Rev. B 58 (1998), pp 2975–2987.
H. Tukamoto and A.R. West, J. Electrochem. Soc., 144 (1997), pp. 3164–3168.
A. Van der Ven, M.K. Aydinol, and G. Ceder, J. of the Electrochem. Soc., 145 (1998), pp. 2149–2155.
G.G. Amatucci, J.M. Tarascon, and L.C. Klein, Solid State Ionics, 83 (1996), pp. 167–173.
J.M. Tarascon et al., J. Electrochem. Soc., 141 (1994), pp. 1421–1431.
D.H. Jang, Y.J. Shin, and S.M. Oh, J. of the Electrochem. Soc., 143 (1996), pp. 2204–2211.
A. Blyr et al., J. of the Electrochem. Soc., 145 (1998), pp. 194–209.
Additional information
Gerbrand Ceder earned his Ph.D. in materials science and mineral engineering at the University of California at Berkeley in 1991. He is currently an associate professor at Massachusetts Institute of Technology. Dr. Ceder is a member of TMS.
Anton Van der Ven earned his M.Eng. in materials science at Katholieke Universiteit Leuven in 1994. He is currently a research assistant at Massachusetts Institute of Technology.
Mehmet Kadri Aydinol earned his Ph.D. in metallurgical engineering at Middle East Technical University in 1994. He is currently an assistant professor at Massachusetts Institute of Technology.
Rights and permissions
About this article
Cite this article
Ceder, G., Van der Ven, A. & Aydinol, M.K. Lithium-intercalation oxides for rechargeable batteries. JOM 50, 35–40 (1998). https://doi.org/10.1007/s11837-998-0412-5
Issue Date:
DOI: https://doi.org/10.1007/s11837-998-0412-5