Skip to main content
SpringerLink
Log in

Selective Vanadium Separation from V-Bearing Roasted Ore

  • Technical Article
  • Published:
JOM Aims and scope Submit manuscript

Abstract

In this study, a cleaner process of water leaching was proposed to extract vanadium from V-bearing roasted ore with V2O5 content of 1.06 wt.%, and the main mineral compositions of the roasted ore were quartz, gypsum, misenite and munirite. The effects of water leaching parameters such as leaching temperature, leaching time, liquid-solid ratio, leaching agents, stirring intensity and material particle size on vanadium recovery were thoroughly researched in the experimental procedure, as well as the vanadium leaching kinetics in the water leaching process. The results show that V2O5 leaching efficiency can reach 91.29%, and V2O5 content of leaching residue decreased to 0.08 wt.% under the following conditions: roasted ore particle size of − 0.1 mm, leaching temperature of 333 K, leaching time of 150 min, (NH4)6Mo7O24·4H2O dosage of 6 wt.%, liquid-solid ratio of 5:1 mL/g and stirring intensity of 200 rpm. The main findings of vanadium leaching kinetics show that diffusion and chemical reaction control vanadium’s action mode in the water leaching process. According to the kinetic model, the apparent activation energy was 32.74 kJ/mol and the frequency factor A = 8.414 s− 1, which was consistent with standard kinetic theory and experimental results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. F. Gao, A.U. Olayiwola, B. Liu, S.N. Wang, H. Du, J.Z. Li, X.D. Wang, D.H. Chen, and Y. Zhang, Miner. Process. Extr. Metall. Rev. 43, 466 https://doi.org/10.1080/08827508.2021.1883013 (2022).

    Article  Google Scholar 

  2. M. Imtiaz, M.S. Rizwan, S.L. Xiong, H.L. Li, M. Ashraf, S.M. Shahzad, M. Shahzad, M. Rizwan, and S.X. Tu, Environ. Int. 80, 79 https://doi.org/10.1016/j.envint.2015.03.018 (2015).

    Article  Google Scholar 

  3. H. Peng, J. Environ. Chem. Eng. 7(5), 103313 https://doi.org/10.1016/j.jece.2019.103313 (2019).

    Article  Google Scholar 

  4. J.F. Wan, H. Du, F. Gao, S.N. Wang, M.L. Gao, B. Liu, and Y. Zhang, Miner. Process. Extr. Metall. Rev. 42, 257 https://doi.org/10.1080/08827508.2020.1762182 (2021).

    Article  Google Scholar 

  5. J. Wen, T. Jiang, Y.J. Liu, and X.X. Xue, Miner. Process. Extr. Metall. Rev. 40, 56 https://doi.org/10.1080/08827508.2018.1481059 (2019).

    Article  Google Scholar 

  6. R. Gilligan and A.N. Nikoloski, Miner. Eng. 146, 106106 https://doi.org/10.1016/j.mineng.2019.106106 (2020).

    Article  Google Scholar 

  7. J.H. Xiao, K. Zou, T. Chen, Y. Peng, W. Ding, J.H. Chen, B. Deng, H. Li, and Z. Wang, JOM. 73, 1836 https://doi.org/10.1007/s11837-021-04665-3 (2021).

    Article  Google Scholar 

  8. M. Li, S.L. Zheng, B. Liu, S.N. Wang, D.B. Dreisinger, Y. Zhang, H. Du, and Y. Zhang, Miner. Process. Extr. Metall. Rev. 38, 228 https://doi.org/10.1080/08827508.2017.1288117 (2017).

    Article  Google Scholar 

  9. R.R. Moskalyk and A.M. Alfantazi, Miner. Eng. 16(9), 793 https://doi.org/10.1016/S0892-6875(03)00213-9 (2003).

    Article  Google Scholar 

  10. M.R. Tavakoli and D.B. Dreisinger, Hydrometallurgy 141, 17 https://doi.org/10.1016/j.hydromet.2013.10.008 (2014).

    Article  Google Scholar 

  11. J.H. Zhang, W. Zhang, and Z.L. Xue, Miner. Process. Extr. Metall. Rev. 38(5), 265 https://doi.org/10.1080/08827508.2017.1289197 (2017).

    Article  MathSciNet  Google Scholar 

  12. B.J. Yan, D.Y. Wang, L.S. Wu, and Y.C. Dong, Miner. Eng. 125, 231 https://doi.org/10.1016/j.mineng.2018.06.005 (2018).

    Article  Google Scholar 

  13. Y.M. Zhang, S.X. Bao, T. Liu, T.J. Chen, and J. Huang, Hydrometallurgy 109, 116 https://doi.org/10.1016/j.hydromet.2011.06.002 (2011).

    Article  Google Scholar 

  14. W. Li, H.Y. Zheng, and F.M. Shen, JOM 71, 3190 https://doi.org/10.1007/s11837-019-03578-6 (2019).

    Article  Google Scholar 

  15. X.S. Li, B. Xie, G.G. Wang, and X.J. Li, Trans. Nonferrous Met. Soc. China. 21, 1860 https://doi.org/10.1016/S1003-6326(11)60942-4 (2011).

    Article  Google Scholar 

  16. H.Y. Gao, T. Jiang, M. Zhou, J. Wen, X. Li, Y. Wang, and X.X. Xue, Miner. Eng. 145, 106056 https://doi.org/10.1016/j.mineng.2019.106056 (2020).

    Article  Google Scholar 

  17. W.C. Song, H. Li, F.X. Zhu, K. Li, and Q. Zheng, Trans. Nonferrous Met. Soc. China. 24, 2687 https://doi.org/10.1016/S1003-6326(14)63399-9 (2014).

    Article  Google Scholar 

  18. M.Y. Wang, X.Y. Xiang, L.P. Zhang, and L.S. Xiao, Rare Met. 27, 112 https://doi.org/10.1016/S1001-0521(08)60097-2 (2008).

    Article  Google Scholar 

  19. X.Y. Chen, X.Z. Lan, Q.L. Zhang, and H.Z. Ma, J. Zhou. Trans. Nonferrous Met. Soc. China. 20, S123 https://doi.org/10.1016/s1003-6326(10)60025-8 (2010).

    Article  Google Scholar 

  20. S.M.J. Mirazimi, F. Rashchi, and M. Saba, Chem. Eng. Res. Des. 94, 131 https://doi.org/10.1016/j.cherd.2014.12.010 (2015).

    Article  Google Scholar 

  21. X.W. Wang, D.X. Gao, B.F. Chen, Y.Q. Meng, Z.B. Fu, and M.Y. Wang, Hydrometallurgy 181, 1 https://doi.org/10.1016/j.hydromet.2018.08.008 (2018).

    Article  Google Scholar 

  22. Y. Liu, C. Sun, W.J. Zhong, and Y.C. Zhai, Adv. Mater. Res. 402, 7 https://doi.org/10.4028/www.scientific.net/AMR.402.7 (2011).

    Article  Google Scholar 

  23. L. Wang, Y. Sun, S.Y. Wang, T.A. Zhang, and G.Z. Lü, Trans. Nonferrous Met. Soc. China. 33, 304 https://doi.org/10.1016/S1003-6326(22)66108-9 (2023).

    Article  Google Scholar 

  24. G.Z. Lu, T.A. Zhang, G.Q. Zhang, W.G. Zhang, Y. Zhang, Z.H. Dou, L. Wang, Y.X. Wang, and G. Xie, JOM. 71, 4600 https://doi.org/10.1007/s11837-019-03672-9 (2019).

    Article  Google Scholar 

  25. W. Ding, S.X. Bao, Y.M. Zhang, and J.H. Xiao, Miner. Process. Extr. Metall. Rev. 44, 304 https://doi.org/10.1080/08827508.2022.2047044 (2022).

    Article  Google Scholar 

  26. W.L. Liu, X.W. Wang, M.Y. Wang, J. Hu, and L.P. Zhang, Chin. J. Nonferrous Met. 19, 943 https://doi.org/10.19476/j.ysxb.1004.0609.2009.05.025 (2009).

    Article  Google Scholar 

  27. K. Zou, J.H. Xiao, G.J. Liang, W.X. Huang, and W.L. Xiong, Metals 11, 1342 https://doi.org/10.3390/met11091342 (2021).

    Article  Google Scholar 

  28. Y. Luo, X.K. Che, X.L. Cui, Q. Zheng, and L. Wang, Int. J. Min. Sci. Technol. 31, 507 https://doi.org/10.1016/j.ijmst.2021.02.002 (2021).

    Article  Google Scholar 

  29. W. Ding, S.X. Bao, Y.M. Zhang, and J.H. Xiao, Miner. Eng. 183, 107624 https://doi.org/10.1016/j.mineng.2022.107624 (2022).

    Article  Google Scholar 

  30. S. Mickevicius, V. Bondarenka, S. Grebinskij, H. Tvardauskas, M. Andriulevicius, S. Tamulevicius, and S. Kaciulis, Micron 40, 126 https://doi.org/10.1016/j.micron.2007.12.010 (2009).

    Article  Google Scholar 

  31. W.H. Xiao, X.H. Liu, and Z.W. Zhao, Hydrometallurgy 194, 105353 https://doi.org/10.1016/j.hydromet.2020.105353 (2020).

    Article  Google Scholar 

  32. H. Li, Y.X. Han, J.P. Jin, P. Gao, and Z.Y. Zhou, Int. J. Min. Sci. Technol. 33, 123 https://doi.org/10.1016/j.ijmst.2022.08.002 (2022).

    Article  Google Scholar 

  33. F.K. Crundwell, Hydrometallurgy 139, 132 https://doi.org/10.1016/j.hydromet.2013.08.003 (2013).

    Article  Google Scholar 

  34. J.F. Tan, G.F. Zhang, Y. Zhang, and Z.H. Zhang, Chin. J. Rare Met. 2, 304 https://doi.org/10.3969/j.issn.0258-7076.2012.02.024 (2012).

    Article  Google Scholar 

  35. G.I. Davila-Pulido, A. Salinas-Rodriguez, F.R. Carrillo-Pedroza, A.A. Gonzalez-Ibarra, J. Mendez-Nonell, and M. Garza-Garcia, Int. J. Chem. Kinet. 53, 379 https://doi.org/10.1002/kin.21450 (2021).

    Article  Google Scholar 

  36. B. Chen, S.X. Bao, Y.M. Zhang, and L.Y. Ren, J. Clean. Prod. 339, 130755 https://doi.org/10.1016/j.jclepro.2022.130755 (2022).

    Article  Google Scholar 

  37. J. Xiao, K. Zou, N. Zhong, and D. Gao, J. Rare Earths 41(7), 1099 https://doi.org/10.1016/j.jre.2022.06.003 (2023).

    Article  Google Scholar 

  38. Z.Q. Qiao, Y.Q. Yang, Q. He, H.Y. Yang, W.S. Li, Z.K. Li, W.Y. Wang, and Z.G. Shen, Hydrometallurgy 220, 106091 https://doi.org/10.1016/j.hydromet.2023.106091 (2023).

    Article  Google Scholar 

  39. Y.L. Chen, G.S. Huo, X.Y. Guo, and Q.M. Wang, Miner. Eng. 179, 107422 https://doi.org/10.1016/j.mineng.2022.107422 (2022).

    Article  Google Scholar 

  40. X.R. Zhu, X.H. Liu, and Z.W. Zhao, Hydrometallurgy 186, 83 https://doi.org/10.1016/j.hydromet.2019.04.004 (2019).

    Article  Google Scholar 

Download references

Acknowledgements

This study was funded by the Technology Innovation Center for Comprehensive Utilization of Strategic Mineral Resources, Ministry of Natural Resources (Grant No. 2023KFJJ006), the Central Government Guides Local Funds for Science and Technology Development (Grant Nos. 23ZYZYTS0403 and 223ZYZYTS0319) and the Sichuan Science and Technology Program (Grant Nos. 2022YFS0509, 2021YJ0057 and 2021YFG0268).

Author information

Authors and Affiliations

  1. Sichuan Provincial Engineering Lab of Non-Metallic Mineral Powder Modification and High-Value Utilization, Southwest University of Science and Technology, Mianyang, 621010, China

    Junhui Xiao & Nanlan Zhong

  2. Technology Innovation Center for Comprehensive Utilization of Strategic Mineral Resources, Ministry of Natural Resources, Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, 610041, China

    Kai Zou, Renju Cheng & Wenliang Xiong

  3. Dongfang Boiler Group Co., Ltd, Zigong, 643001, China

    Junhui Xiao

  4. Key Laboratory of Ministry of Education for Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Mianyang, 621010, China

    Junhui Xiao & Nanlan Zhong

Authors
  1. Junhui Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nanlan Zhong
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kai Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Renju Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wenliang Xiong
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Junhui Xiao.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could influence the work reported in this study.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (PDF 697 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xiao, J., Zhong, N., Zou, K. et al. Selective Vanadium Separation from V-Bearing Roasted Ore. JOM 75, 4376–4384 (2023). https://doi.org/10.1007/s11837-023-06060-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-023-06060-6

Search

Navigation