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Preparation of Fe2O3/Mn3O4/C Composites as High Performances Anode Materials for Lithium-Ion Batteries

  • Mechanistic Interactions in Energy Storage
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Abstract

To improve the electrochemical performances of Mn3O4, combining heterojunction structure with the carbon fiber is a good method; the heterojunction structure presents good electron conductivity, and carbon fiber can alleviate particle aggregation, thus improving electrochemical performances. Herein, the mixed transition metal oxide Fe2O3/Mn3O4/C composites with heterojunction structure are designed through carbonization at high temperature after in situ growth on lignocellulose by simple hydrothermal method. The results of phase analysis show that the synthesis of target product is successful. At the same time, the morphology, element distribution and graphitization degree of the material are characterized, respectively. The analysis of morphology verifies the existence of the heterojunction structure, and the results of electrochemical performances show that Fe2O3/Mn3O4/C anode material has excellent performance. The specific capacity of Fe2O3/Mn3O4/1C can be maintained at 917.53 mAh g−1 at 100 mA g−1, and the capacity retention ratio can be maintained at 137.9% after 200 cycles.

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Acknowledgements

This work was financially supported by the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province (2022CL08), The Open Fund Project from Southwest Petroleum University (2021KSZ05007) and the Guangxi Key Laboratory of Information Materials (Guilin University of Electronic Technology), PR China (211019-K).

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Authors and Affiliations

  1. School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, People’s Republic of China

    Xiaoyan Zhang, Weibo Wu, Yuting Wang, Tao Yang, Xing Li, Shuliang Wang & Yi Zhang

  2. Chengdu Carbon Co., LTD, Chengdu, People’s Republic of China

    Ruijie Zhu

  3. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Dinghan Xiang

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  1. Xiaoyan Zhang
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  2. Weibo Wu
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Zhang, X., Wu, W., Wang, Y. et al. Preparation of Fe2O3/Mn3O4/C Composites as High Performances Anode Materials for Lithium-Ion Batteries. JOM 76, 1192–1202 (2024). https://doi.org/10.1007/s11837-023-05749-y

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