Abstract
Phase equilibria of the Mg-Gd-Zn system at 320°C are important because it has been reported that the aging treatment is carried out at that temperature. The phase equilibria at 320°C for the Mg-Zn side (x(Gd) < 50 at.%) were investigated with equilibrated alloys using electron probe microanalysis and X-ray diffraction. The partial isothermal section (x(Gd) < 50 at.%) was constructed. Eight ternary phases, τ1 to τ8, were observed at 320°C. The W phase (Gd2Mg3Zn3) which was found at high temperatures in the literature was not observed at 320°C. The analysis of the present data also indicates that the icosahedral quasicrystalline (I phase) in the Mg-Gd-Zn system is not stable. One important solid transition was found in the present work: the three-phase equilibria (Mg) + GdMg3 + GdMg5 and (Mg) + GdMg3 + τ1 at 500°C transform to (Mg) + GdMg5 + τ1 and GdMg5 + τ1 + GdMg3 at 320°C, due to the invariant reaction of (Mg) + GdMg3 → GdMg5 + τ1.
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Acknowledgements
The financial supports from the China Hunan Provincial Science& Technology Department (Grant No 2020GK2051), Major Special Projects in Changsha Science and Technology Bureau (Grant No kh2103011), National key research and development program of China (2021YFB3502600) are greatly acknowledged.
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Xu, H., Zhou, T., Wang, P. et al. Solid-State Phase Equilibria at 320°C of the Mg-Gd-Zn System in the Region of Less Than 50 at.% Gd. JOM 75, 3025–3032 (2023). https://doi.org/10.1007/s11837-023-05737-2
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DOI: https://doi.org/10.1007/s11837-023-05737-2