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Acrylic Acid-Functionalized Cellulose Diacrylate-Carbon Nanocomposite Thin Film: Preparation, Characterization, and Applications

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Abstract

Grafting of cellulose using acrylic acid, methyl methacrylate, and 2-ethyl hexyl acrylate has been achieved through a free radical polymerization process by using ammonium persulfate as a free radical facilitator and Lutensol-XL100 as an emulsifier. The grafted cellulose was made into a composite using carbon nanoparticles obtained from millet carbon soot. Grafted cellulose and its carbon nanocomposites were characterized by scanning electron microscopy, differential scanning calorimetry, thermogravimetric analysis and Fourier-transform infrared spectroscopy. Additionally, tensile strength, electrical conductivity, and biodegradation studies were carried out. A soil burial test revealed the biodegradation of cellulose grafted terpolymer nanocomposite. The controlled biodegradation of this composite may have potential applications as an advanced material in various fields.

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References

  1. W. Hussain, A. Badshah, R.A. Hussain, D. Imtiaz ud, M.A. Aleem, A. Bahadur, S. Iqbal, M.U. Farooq, and H. Ali, Mater. Chem. Phys. 194, 345 (2017).

    Article  Google Scholar 

  2. M.A. Qamar, S. Shahid, M. Javed, M. Sher, S. Iqbal, A. Bahadur, and D. Li, Colloids Surf. A 611, 125863 (2021).

    Article  Google Scholar 

  3. W. Hussain, H. Malik, A. Bahadur, R.A. Hussain, M. Shoaib, S. Iqbal, H. Hussain, I.R. Green, A. Badshah, and H. Li, Kinet. Catal. 59(6), 710 (2018).

    Article  Google Scholar 

  4. S. Iqbal, Appl. Catal. B 274, 119097 (2020).

    Article  Google Scholar 

  5. A. Bahadur, M. Shoaib, S. Iqbal, A. Saeed, M.S.U. Rahman, and P.A. Channar, React. Funct. Polym. 131, 134 (2018).

    Article  Google Scholar 

  6. M. Sajid, X. Zhao, and D. Liu, Green Chem. 20(24), 5427 (2018).

    Article  Google Scholar 

  7. A. Bahadur, A. Saeed, M. Shoaib, S. Iqbal, and S. Anwer, J. Appl. Polym. Sci. 136(13), 47253 (2019).

    Article  Google Scholar 

  8. J. Malinauskaite, H. Jouhara, D. Czajczyńska, P. Stanchev, E. Katsou, P. Rostkowski, R.J. Thorne, J. Colon, S. Ponsá, and F. Al-Mansour, Energy 2017, 141 (2013).

    Google Scholar 

  9. H.I. Abdel-Shafy, and M.S. Mansour, Egypt. J. Pet. 27(4), 1275 (2018).

    Article  Google Scholar 

  10. M. Saif Ur Rehman, I. Kim, N. Rashid, M. Adeel Umer, M. Sajid, and J.I. Han, Clean: Soil, Air, Water 44(1), 55 (2016).

    Google Scholar 

  11. S. Sharma, A.A. Singh, A. Majumdar, and B.S. Butola, Compos. Part B 188, 107845 (2020).

    Article  Google Scholar 

  12. R.A. Gross, and B. Kalra, Science 297(5582), 803 (2002).

    Article  Google Scholar 

  13. H. Kargarzadeh, J. Huang, N. Lin, I. Ahmad, M. Mariano, A. Dufresne, S. Thomas, and A. Gałęski, Prog. Polym. Sci. 87, 197 (2018).

    Article  Google Scholar 

  14. F.G. Torres, J.J. Arroyo, and O.P. Troncoso, Mater. Sci. Eng. C 98, 1277 (2019).

    Article  Google Scholar 

  15. M.I. Ahamad, J. Song, H. Sun, X. Wang, M.S. Mehmood, M. Sajid, P. Su, and A.J. Khan, Int. J. Environ. Res. Public Health 17(3), 1070 (2020).

    Article  Google Scholar 

  16. N. Ferronato, M.L. Nova Pinedo, and V. Torretta, Sustainability 12(12), 5055 (2020).

    Article  Google Scholar 

  17. L.A. Pfaltzgraff, E.C. Cooper, V. Budarin, and J.H. Clark, Green Chem. 15(2), 307 (2013).

    Article  Google Scholar 

  18. D. Zhang, and M.J.J. Dumont, J. Polym. Sci. Part A-1 Polym. Chem. 55(9), 1478 (2017).

    Article  Google Scholar 

  19. N. Yoshida, N. Kasuya, N. Haga, and K. Fukuda, Polym. J. 40(12), 1164 (2008).

    Article  Google Scholar 

  20. M. Sajid, Y. Bai, D. Liu, and X. Zhao, Waste Biomass Valor. 12, 3271 (2021).

    Article  Google Scholar 

  21. M. Sajid, Y. Bai, D. Liu, and X. Zhao, Arabian J. Chem. 13(10), 7430 (2020).

    Article  Google Scholar 

  22. A. Mellati, E. Hasanzadeh, M. Gholipourmalekabadi, and S.E. Enderami, Mater. Sci. Eng. C 131, 112489 (2021).

    Article  Google Scholar 

  23. R. Fang, A. Dhakshinamoorthy, Y. Li, and H. Garcia, Chem. Soc. Rev. 49(11), 3638 (2020).

    Article  Google Scholar 

  24. D. Klemm, B. Heublein, H.P. Fink, and A. Bohn, Angew. Chem. Int. Ed. 44(22), 3358 (2005).

    Article  Google Scholar 

  25. L. Yang, X. Li, G. Zhang, P. Cui, X. Wang, X. Jiang, J. Zhao, Y. Luo, and J. Jiang, Nat. Commun. 8, 16049 (2017).

    Article  Google Scholar 

  26. M. Tan, L. Ma, M.S.U. Rehman, M.A. Ahmed, M. Sajid, X. Xu, Y. Sun, P. Cui, and J. Xu, Renew. Energy 132, 950 (2019).

    Article  Google Scholar 

  27. S. Dutta, and S. Pal, Biomass Bioenergy 62, 182 (2014).

    Article  Google Scholar 

  28. A.P. Abbott, T.J. Bell, S. Handa, and B. Stoddart, Green Chem. 8(9), 784 (2006).

    Article  Google Scholar 

  29. Z. Li, K. Su, J. Ren, D. Yang, B. Cheng, C.K. Kim, and X. Yao, Green Chem. 20(4), 863 (2018).

    Article  Google Scholar 

  30. V. Castelvetro, M. Geppi, S. Giaiacopi, and G. Mollica, Biomacromol 8(2), 498 (2007).

    Article  Google Scholar 

  31. A. Bledzki, and J. Gassan, Prog. Polym. Sci. 24(2), 221 (1999).

    Article  Google Scholar 

  32. A. Kumar, S. Joseph, L. Tsechansky, K. Privat, I.J. Schreiter, C. Schüth, and E.R. Graber, Sci. Total Environ. 626, 953 (2018).

    Article  Google Scholar 

  33. V.V. Thakur, R.K. Jain, and R.M. Mathur, BioResources 7(2), 2220. (2012).

    Article  Google Scholar 

  34. Y. Zhou, C. Chen, S. Zhu, C. Sui, C. Wang, Y. Kuang, U. Ray, D. Liu, A. Brozena, and U.H. Leiste, Mater. Today 30, 17 (2019).

    Article  Google Scholar 

  35. G. Gürdağ, and S. Sarmad, Cellulose graft copolymers: synthesis, properties, and applications, in Polysaccharide based graft copolymers. (Springer, Berlin, Heidelberg, 2013), pp. 15–57.

    Chapter  Google Scholar 

  36. F. Wahid, X.-J. Zhao, S.-R. Jia, H. Bai, and C. Zhong, Compos. Part B 200, 108208 (2020).

    Article  Google Scholar 

  37. J. Li, J. Chen, J. Wu, H. Lei, Y. Tian, G. Yang, Z. Wang, and Z. Hua, Polym. Chem. 12(24), 3533 (2021).

    Article  Google Scholar 

  38. D.A. Gregory, L. Tripathi, A.T.R. Fricker, E. Asare, I. Orlando, V. Raghavendran, and I. Roy, Mater. Sci. Eng. R Rep. 145, 100623 (2021).

    Article  Google Scholar 

  39. P. Gunatillake, R. Mayadunne, and R. Adhikari, Biotechnol. Annu. Rev. 12, 301 (2006).

    Article  Google Scholar 

  40. L. Tamayo, M. Azócar, M. Kogan, A. Riveros, and M. Páez, Mater. Sci. Eng. C 69, 1391 (2016).

    Article  Google Scholar 

  41. H.M. Abd El Salam, S.M. Sayyh, and E.H.M. Kamal, Beni-Suef Univ. J. Basic Appl. Sci. 3(3), 193 (2014).

    Google Scholar 

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Acknowledgements

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for supporting this work through research groups program under grant number R.G.P.1/233/42. Hashem O. Alsaab would like to acknowledge Taif University Researchers Supporting Project number (TURSP-2020/67), Taif University, Taif, Saudi Arabia.

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Correspondence to Sohail Nadeem or Shahid Iqbal.

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Nadeem, S., Javed, M., Iqbal, S. et al. Acrylic Acid-Functionalized Cellulose Diacrylate-Carbon Nanocomposite Thin Film: Preparation, Characterization, and Applications. JOM 74, 2113–2119 (2022). https://doi.org/10.1007/s11837-022-05231-1

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  • DOI: https://doi.org/10.1007/s11837-022-05231-1

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