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Mullite Synthesis Kinetics from Polydispersed Vibration-Milled Wastes of Commercial Corundum in the Presence of High-Silica Melt: Experimental and Modelling Results

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Abstract

The experimental kinetic data of mullite synthesis using commercial regular corundum vibration-milled wastes and silica by isothermal heat treatment were studied. The principle of diffusion flux symmetry to a convex surface was applied to perform theoretical analysis of partially and fully immersed quasispherical polydispersed particle interaction with a liquid phase (PAFIQPP method) to further derive the kinetic equations of mullite synthesis in the range of conversion degrees 0 < α < 0.75–0.85 assuming corundum dissolution as a limiting stage in the molten silicate. The rate constants and activation energy of the process were calculated and adequately approximated by the PAFIQPP method experimental data: the rate constant growth from 3.3 × 10–8 cm s−1 to 9.2 × 10−8 cm s−1 was observed in the temperature range 1350–1500 °C; the activation energy was 160 kJ/mol.

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Acknowledgements

The authors gratefully acknowledge Tekhnohim Company (Zaporizhia, Ukraine) for financial support of this work.

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Authors and Affiliations

  1. Zaporizhzhia National University, Zaporizhzhia, Ukraine

    Dmytro Pruttskov

  2. Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    Vladimir Sokol’skii

  3. PJSC “Titanium Institute”, Zaporizhzhia, Ukraine

    Denys Bachurskyi

  4. PJSC “Zaporizhogneupor”, Zaporizhzhia, Ukraine

    Sergei Goman

  5. National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine

    Georgii Sokolsky

Authors
  1. Dmytro Pruttskov
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  2. Vladimir Sokol’skii
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  3. Denys Bachurskyi
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  4. Sergei Goman
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  5. Georgii Sokolsky
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Correspondence to Georgii Sokolsky.

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Pruttskov, D., Sokol’skii, V., Bachurskyi, D. et al. Mullite Synthesis Kinetics from Polydispersed Vibration-Milled Wastes of Commercial Corundum in the Presence of High-Silica Melt: Experimental and Modelling Results. JOM 73, 2225–2234 (2021). https://doi.org/10.1007/s11837-021-04710-1

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  • DOI: https://doi.org/10.1007/s11837-021-04710-1

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