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Solid-phase Relationships in the Tl2Te-Tl2Te3-TlTbTe2 System and Thermodynamic Properties of Thallium–Terbium Tellurides

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Abstract

This work presents new data on the solid-phase equilibria of the Tl-Tb-Te ternary system in the Tl2Te-Tl2Te3-TlTbTe2 composition region and the thermodynamic functions of the TlTbTe2, and Tl9TbTe6 ternary compounds. Studies were carried out by using the electromotive forces method (EFM) and the powder x-ray diffraction technique. From the EMF measurements of the concentration cells of the type (−) TbTe (s) | glycerol + KCl + TbCl3 | (Tb in Tl-Tb-Te alloys) (s) (+) in the 300-450 K temperature interval, the relative partial thermodynamic functions of TbTe and Tb in alloys of the Tl2Te3-TlTe-TlTbTe2, and TlTe-TlTbTe2-Tl9TbTe6 three-phase regions were determined. Based on the solid-phase equilibria diagram, the potential-forming reactions responsible for the indicated partial molar quantities were determined and the standard thermodynamic functions of formation and standard entropies of the TlTbTe2 and Tl9TbTe6 ternary compounds were calculated.

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Acknowledgements

The work has been carried out within the framework of the international joint research laboratory “Advanced Materials for Spintronics and Quantum Computing” (AMSQC) established between the Institute of Catalysis and Inorganic Chemistry of ANAS (Azerbaijan) and Donostia International Physics Center (Basque Country, Spain) and partially supported by the Science Development Foundation under the President of the Republic of Azerbaijan, a grant EİF/MQM/Elm-Tehsil-1-2016-1(26)-71/01/4-M-33.

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  1. Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Azerbaijan National Academy of Sciences, 1143, Baku, Azerbaijan

    Samira Z. Imamaliyeva, Dunya M. Babanly, Vagif A. Qasymov & Mahammad B. Babanly

  2. Azerbaijan State Oil and Industry University, French-Azerbaijani University (UFAZ), Baku, 1010, Azerbaijan

    Dunya M. Babanly

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  1. Samira Z. Imamaliyeva
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Imamaliyeva, S.Z., Babanly, D.M., Qasymov, V.A. et al. Solid-phase Relationships in the Tl2Te-Tl2Te3-TlTbTe2 System and Thermodynamic Properties of Thallium–Terbium Tellurides. JOM 73, 1503–1510 (2021). https://doi.org/10.1007/s11837-021-04623-z

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