Abstract
Silicon fertilizer has been prepared by converting crystalline silica from ore into plant-available silicon using a roasting method. The results of roasting experiments showed that adding limestone as an additive ingredient and sodium hydroxide as a roasting fluxing agent significantly increased the conversion rate of plant-available silicon. Both the roasting temperature and fluxing agent are key factors in the production process of silicon fertilizer. The roasting mechanism was studied by thermogravimetry-differential scanning calorimetry (TG-DSC) and x-ray diffraction (XRD) analysis. The TG-DSC results indicated that, in the presence of the fluxing reagent, the decomposition temperature for limestone and the initial reaction temperature for the conversion were reduced by 22.1°C and 33.2°C, respectively. These results also revealed that plant-available silicon conversion is an endothermic reaction without flux but an exothermic reaction with flux. The XRD results showed that the effective components of the silicon fertilizer were CaSiO3, Ca2SiO4, and Ca3SiO5.
Similar content being viewed by others
References
Y. Guo, Z. Zhao, and F. Cheng, Hydrometallurgy 169, 4189 (2017). https://doi.org/10.1016/j.hydromet.2017.02.021.
K. Quast, Miner. Eng. 108, 12 (2017). https://doi.org/10.1016/j.mineng.2017.01.008.
Y. Liang, J. Integr. Agric. 17, 2137 (2018). https://doi.org/10.1016/S2095-3119(18)62081-7.
Richard J. Haynes, Adv. Agron. 146, 83 (2017). https://doi.org/10.1016/bs.agron.2017.06.001.
M. Zhang, Y. Liang, and G. Chu, Sci. Hortic. 225, 757 (2017). https://doi.org/10.1016/j.scienta.2017.08.019.
T. Klotzbücher, A. Marxen, D. Vetterlein, J. Schneiker, M. Türke, N. Van Sinh, N. HungManh, H. Chien, L. Marquez, S. Villareal, J. Victor Bustamante, and R. Jahn, Basic Appl. Ecol. 16, 665 (2015). https://doi.org/10.1016/j.baae.2014.08.002.
R.J. Haynes, Geoderma 337, 375 (2019). https://doi.org/10.1016/j.geoderma.2018.09.026.
J. Ma and N. Yamaji, Trends Plant Sci. 20, 435 (2015). https://doi.org/10.1016/j.tplants.2015.04.007.
K.A. Wijaya and K. Anom, Agric. Agric. Sci. Proc. 9, 158 (2016). https://doi.org/10.1016/j.aaspro.2016.02.111.
H. Marschner, J. Ecol. 76, 1250 (1995). https://doi.org/10.1016/B978-012473542-2/50019-5.
Z. Jarosz, J. Elementol. 18, 403 (2013). https://doi.org/10.5601/jelem.2013.18.3.05.
H. Liu, J. Li, G. Zheng, Q. Du, T. Pan, and Y. Chang, Acta Agric. Boreali-Occident. Sin. 23, 8 (2014). https://doi.org/10.7606/j.issn.1004-1389.2014.08.019.
S. Dehghani, C. Ghobadi, B. Baninasab, M. Gheysari, and S. Shirani Bidabadi, J. Plant Nutr. 39, 502 (2015). https://doi.org/10.1080/01904167.2015.1086789.
N.K. Savant, L.E. Datnoff, and G.H. Snyder, Commun. Soil Sci. Plant Anal. 28, 1245 (2008). https://doi.org/10.1080/00103629709369870.
S.A. Abro, R. Qureshi, F.M. Soomro, A.A. Mirbahar, and G.S. Jakhar, Pak. J. Bot. 41, 1385 (2009). https://doi.org/10.3417/2007082.
C.X. Xu, Y.P. Ma, and Y.L. Liu, S. Afr. J. Bot. 98, 26 (2015). https://doi.org/10.1016/j.sajb.2015.01.008.
F.J. Ma, Soil Sci. Plant Nutr. 50, 11 (2004). https://doi.org/10.1080/00380768.2004.10408447.
Y. Liang, W. Sun, Y.G. Zhu, and P. Christie, Environ. Pollut. 147, 422 (2007). https://doi.org/10.1016/j.envpol.2006.06.008.
C. Keller, M. Rizwan, J.C. Davidian, O. Pokrovsky, N. Bovet, P. Chaurand, and J.D. Meunier, Planta 241, 847 (2015). https://doi.org/10.1007/s00425-014-2220-1.
Y. Liang, M. Nikolic, R. Bélanger, H. Gong, and A. Song, Silicon in Agriculture (Amsterdam: Springer, 2015).
J. Ma, H. Cai, C. He, W. Zhang, and L. Wang, N. Phytol. 206, 1063 (2015). https://doi.org/10.1111/nph.13276.
J.W. Wu, S. Yu, Y.X. Zhu, Y.C. Wang, and H.J. Gong, Pedosphere 23, 815 (2013). https://doi.org/10.1016/S1002-0160(13)60073-9.
M. Adrees, S. Ali, M. Rizwan, M. Zia-ur-Rehman, M. Ibrahim, F. Abbas, M. Farid, M.F. Qayyum, and M.K. Irshad, Ecotoxicol. Environ. Saf. 119, 186 (2015). https://doi.org/10.1016/j.ecoenv.2015.05.011.
F. Guntzer, C. Keller, and J.D. Meunier, Agron. Sustain. Dev. 32, 201 (2012). https://doi.org/10.1007/s13593-011-0039-8.
M. Wang, J.J. Wang, and X. Wang, Geoderma 321, 22 (2018). https://doi.org/10.1016/j.geoderma.2018.02.001.
E. Epstein, Proc. Natl. Acad. Sci. USA 91, 11 (1994). https://doi.org/10.2307/2363729.
J.T. Cornelis and B. Delvaux, Funct. Ecol. 30, 1111 (2016). https://doi.org/10.1111/1365-2435.12704.
E. Struyf, A. Smis, S. Van Demme, J. Garnier, G. Govers, B. Van Wesemael, D.J. Conley, O. Batelann, E. Frot, W. Clymans, F. Vandevenne, C. Lancelot, P. Goos, and P. Meire, Nat. Commun. 1, 129 (2010). https://doi.org/10.1038/ncomms1128.
F. Vandevenne, E. Struyf, W. Clymans, and P. Meire, Front. Ecol. Environ. 10, 243 (2012). https://doi.org/10.1890/110046.
T. Klotzbücher, A. Klotzbücher, K. Klaus, M. Ines, and M. Robert, Geoderma 331, 15 (2018). https://doi.org/10.1016/j.geoderma.2018.06.011.
A. Song, D. Ning, F. Fan, Z. Li, M. Provancebowley, and Y. Liang, Sci. Rep. 5, 17354 (2015). https://doi.org/10.1038/srep17354.
P. Hu, Y. Zhang, Y. Zhou, X. Ma, and P.K. Chu, Environ. Prog. Sustain. Energy 1, 1 (2017). https://doi.org/10.1002/ep.12776.
K. Thiagalingam, J.A. Silva, and R.L. Fox, Conference on Chemistry and Fertility of Tropical Soils 149 (1977)
D.L. Cai, Silicon Fertilizer and Its Application Technology (Beijing: Taihai Publishing House, 2001) (In Chinese).
R.J. Haynes, O.N. Belyaeva, and G. Kingston, J. Plant Nutr. Soil Sci. 176, 238 (2013). https://doi.org/10.1002/jpln.201200372.
K. Ito, K. Endoh, Y. Shiratori, and K. Inubushi, Soil Sci. Plant Nutr. (Abingdon, UK) 61, 835 (2015). https://doi.org/10.1080/00380768.2015.1064326.
W. J. Duan, Study on preparation of silicon fertilizer using wollastonite (2015) (In Chinese)
M. Vaculík, T. Landberg, M. Greger, M. Luxová, M. Stoláriková, and A. Lux, Sci. Rep. 110, 433 (2012). https://doi.org/10.1093/aob/mcs039.
L. Qian, B. Chen, and M. Chen, Sci. Rep. 6, 29346 (2016). https://doi.org/10.1038/srep29346.
S. Agarie, H. Uchida, W. Agata, F. Kubota, and P.B. Kaufman, Plant Prod. Sci. 1, 89 (1998). https://doi.org/10.1626/pps.1.89.
T. Hayasaka, H. Fujii, and K. Ishiguro, Phytopathology 98, 1038 (2008). https://doi.org/10.1094/phyto-98-9-1038.
F. Fauteux, W. Rémus-Borel, J.G. Menzies, and R.R. Bélanger, FEMS Microbiol. Lett. 249, 1 (2005). https://doi.org/10.1016/j.femsle.2005.06.034.
P.H. Seron, K.G. Henrique, V.A.D. Aquino, and C.M. de Sartori, Sci. Agric. 61, 522 (2004). https://doi.org/10.1590/s0103-90162004000500010.
G.G. Javier, C. Virgilio, R.V. Lorena, C.F. Elena, G.M. Rafael, and T. Laura, Ann. Acad. Bras. Cienc. 82, 267 (2010). https://doi.org/10.1590/S0001-37652010000200003.
J.F.P. Gomes and C.G. Pinto, Rev. Metal. 42, 409 (2006). https://doi.org/10.3989/revmetalm.2006.v42.i6.39.
J.M. Valverde and J. Manuel, Chem. Eng. Sci. 132, 169 (2015). https://doi.org/10.1016/j.ces.2015.04.027.
L.E. Datnoff, Crop Protect. 16, 525 (1997). https://doi.org/10.1016/S0261-2194(97)00033-1.
Acknowledgements
The authors would like to acknowledge the National Natural Science Foundation of China (No. 51764023) and the National Natural Science Foundation of China (No. 51464030) for financial support.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Rao, B., Gao, L., Dai, H. et al. An Efficient and Sustainable Approach for Preparing Silicon Fertilizer by Using Crystalline Silica from Ore. JOM 71, 3915–3922 (2019). https://doi.org/10.1007/s11837-019-03630-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11837-019-03630-5