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Mechanical Behavior of Castor-Oil-Based Advanced Polyurethane Functionalized with Glycidol and Siloxanes

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Abstract

Castor-oil-based polyurethane (PU), epoxy (glycidol) terminated polyurethane (EPU), and hydroxy terminated poly (dimethyl siloxane) (HTPDMS) modified EPU (EPDMS) were synthesized. The PU and EPU were synthesized with polyol:diisocyanate and polyol:diisocyanate:glycidol ratio of 1:1.2 and 1:3:3, respectively, whereas EPDMS was prepared by the incorporation of 5 wt.%, 10 wt.%, 20 wt.%, and 30 wt.% of HTPDMS into the EPU. The structural modification of EPDMS was confirmed by solid-state CP/MAS 13C and 29Si NMR spectroscopy. The results of a tensile test revealed that the EPDMS with 10 wt.% loading of HTPDMS (EPDMS10) exhibited considerable enhancement in the tensile strength and modulus. The scanning electron microscope analysis was performed to understand the increased phase heterogeneity of the samples.

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Authors and Affiliations

  1. Central Institute of Plastics Engineering & Technology, Guindy, Chennai, 600032, India

    Aiswarea Mathew & Sanjay K. Nayak

  2. Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology, Bhubaneswar, 751024, India

    Surendra Kurmvanshi, Smita Mohanty & Sanjay K. Nayak

Authors
  1. Aiswarea Mathew
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  2. Surendra Kurmvanshi
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  3. Smita Mohanty
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  4. Sanjay K. Nayak
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Correspondence to Aiswarea Mathew.

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Mathew, A., Kurmvanshi, S., Mohanty, S. et al. Mechanical Behavior of Castor-Oil-Based Advanced Polyurethane Functionalized with Glycidol and Siloxanes. JOM 69, 2501–2507 (2017). https://doi.org/10.1007/s11837-017-2572-7

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  • DOI: https://doi.org/10.1007/s11837-017-2572-7

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