Abstract
This research presents the results of laboratory and pilot-scale tests conducted on the use of sintered red mud (RM)-based flux in the hot metal desulfurization (HMD) process. Al2O3/Na2O in RM can decrease the melting point of lime-based slag and can work as a flux in the HMD process. Good slag fluidity was observed throughout the process, and high desulfurization rates (~80%) with a low final S content (<0.02%) were experimentally obtained when the RM:CaO ratio was between 1.2:1 and 2.4:1. The pilot-scale test results indicated that a desulfurization rate as high as 91% and a S content <0.0099% could be acquired when RM:lime = 1:1, verifying the feasibility of using sintered RM-based flux in HMD. The data obtained provide important information for promoting the large-scale application of sintered RM in steelmaking.
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References
T.J. Yang and Z.K. Gao, Iron Steel 1, 1 (1999).
P.K. Iwamasa and R.J. Fruehan, Metall. Trans. B 28, 47 (1997).
K. Takahashi, K. Utagawa, H. Shibata, S.Y. Kitamura, N. Kikuchi, and Y. Kishimoto, ISIJ Int. 52, 10 (2012).
N. Kikuchi, S. Nabeshima, S. Takeuchi, T. Yamauchi, Y. Kitano, and S. Ogura, Tetsu to Hagane 90, 322 (2004).
W.H. Van Niekerk and R.J. Dippenaar, ISIJ Int. 33, 59 (1993).
C. Brunori, C. Cremisini, P. Massanisso, V. Pinto, and L. Torricelli, J. Hazard. Mater. 117, 55 (2005).
Q. Yue, Y. Zhao, Q. Li, W. Li, B. Gao, S. Han, Y. Qi, and H. Yu, J. Hazard. Mater. 176, 741 (2010).
J. Ye, X. Cong, and P. Zhang, Appl. Surf. Sci. 356, 128 (2015).
R. Inoue and H. Suito, Trans. Iron Steel Inst. Jpn. 22, 514 (1982).
A.H. Chan and R.J. Fruehan, Metall. Trans. B 20, 71 (1989).
M.K. Cho, J. Cheng, J.H. Park, and D.J. Min, ISIJ Int. 50, 215 (2010).
J. Diao, J. Iron Steel Res. 25, 9 (2013).
K. Yajima, H. Matsuura, and F. Tsukihashi, ISIJ Int. 50, 191 (2010).
J. Diao, B. Xie, Y. Wang, and X. Guo, ISIJ Int. 52, 955 (2012).
L. Wu, Basic research on recycling process for the high-iron red mud produced by aluminum industry [D]. Doctoral Dissertation of University of Science and Technology (Beijing, 2012), pp. 2–9
S. Wang, H.M. Ang, and M.O. Tadé, Chemosphere 72, 1621 (2008).
S. Wang, Y. Boyjoo, A. Choueib, and Z.H. Zhu, Water Res. 39, 129 (2005).
H. Yang, C. Chen, L. Pan, H. Lu, H. Sun, and X. Hu, J. Eur. Ceram. Soc. 29, 1887 (2009).
P.E. Tsakiridis, S. Agatzini-Leonardou, and P. Oustadakis, J. Hazard. Mater. B 116, 103 (2004).
C. Liu, Y. Li, Z. Luan, Z. Chen, Z. Zhang, and Z. Jia, J. Environ. Sci. 19, 1166 (2007).
J.F. Xu, J.Y. Zhang, D. Chen, M.Q. Sheng, W.P. Weng, and J. Cent, South Univ. 23, 3079 (2016).
R.W. Young, J.A. Duffy, G.J. Hassall, and Z. Xu, Ironmak. Steelmak. 19, 201 (1992).
J.D. Seo and S.H. Kim, Steel Res. 70, 203 (1999).
K. Kaersrud, Scand. J. Metall. 13, 144 (1984).
M.R. Kalyanram, T.G. Macfarlane, and H.B. Bell, J. Iron Steel Inst. 195, 58 (1960).
T. Xin and X. Chushao, ISIJ Int. 35, 367 (1995).
S.D. Brown, R.J. Roxburgh, I. Ghita, and H.B. Bell, Ironmak. Steelmak. 9, 163 (1982).
A. Danaei, Fundamental study of red mud based fluxes for desulphurization and dephosphorization of hot metal [D]. Doctoral Dissertation of Ryerson University (Toronto, 2015), p. 75
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The authors would like to thank the National Natural Science Foundation of China (No. 51474021) and the Aluminum Corporation of China Limited for financial support.
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Li, F., Zhang, Y. & Guo, Z. Experimental Study on Hot Metal Desulfurization Using Sintered Red Mud-Based Flux. JOM 69, 1632–1638 (2017). https://doi.org/10.1007/s11837-017-2454-z
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DOI: https://doi.org/10.1007/s11837-017-2454-z