Abstract
Complete sample digestion is a prerequisite in achieving accurate and reproducible results in wet chemical analysis as well as effective element recovery in hydrometallurgical beneficiation processes. Inductively coupled plasma-optical emission spectroscopy was used to evaluate the efficiency of (NH4)2HPO4/(NH4)H2PO4, Na2HPO4/NaH2PO4·H2O (800°C), NH4F·HF flux (250°C), microwave dissolution using HCl and aqua regia acids (240°C) to dissolve and liberate the platinum group metals (PGE) in a Upper Group 2 (UG2) chromitite concentrate sample. Complete digestion of the UG2 chromitite ore was achieved using Na2HPO4/NaH2PO4·H2O and (NH4)2HPO4/(NH4)H2PO4 flux mixtures and average PGE (Ru, Os and Pt) yields of 1.90 g/kg (Ru), 0.88 g/kg (Os), 2.52 g/kg (Pt) were obtained using Sc as internal standard. Fusion with NH4F·HF yielded 0.85 g/kg (Ru), 0.72 g/kg (Os) and 0.95 g/kg (Pt) whilst microwave dissolution using HCl and aqua regia yielded an average of 0.77 g/kg (Ru), 0.08 g/kg (Os) and 0.35 g/kg (Pt). Sodium phosphate flux, however, introduced Na+ ions as easily ionised elements, which affected the emission intensities to yield slightly inflated PGE (Ru, Os and Pt) yields. The use of ammonium phosphate and sodium phosphate at 800°C (after the selective removal of Na+ ions) proved to better the fluxes and produced higher and consistent PGE yields. The use of ammonium phosphate flux was also shown to facilitate the isolation of a green chromium precipitate with a 98.9% purity, which may assist in a hydrometallurgical beneficiation process of the UG2 chromitite concentrate ore and may also have important implications for the ferro-chrome industry.
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References
K.S. Liddell, L.B. McRae, and R.C. Dunne, Mintek Rev. 4, 33 (1986).
C.H. McLaren, Met. Miner. Process. 19 (1978).
J.A. Kinnaird, F.J. Kruger, P.A.M. Nex, and R.G. Cawthorn, Trans. Inst. Min. Metall. 111, B23 (2002).
R.T. Jones, S. Afr. J. Sci. 95, 525 (1999).
Q.I. Wesseldijk, M.A. Reuter, D.J. Bradshaw, and P.J. Harris, Miner. Eng. 12, 1177 (1999).
S.C. Newman, Trans. Inst. Min. Metall. 82, A52 (1973).
J. Rademan and J. Wiese, S. Afr. Inst. Min. Metall. 1003 (2012).
C. Rule, J. S. Afr. Inst. Min. Metall. 71 (2010).
L. Maharaj, B.K. Loveday, and J. Pocock, S. Afr. J. Chem. Eng. 16, 1 (2011).
R.R. Barefoot and J.C. Van Loon, Talanta 49, 1 (1999).
T.T. Chiweshe, Quantification of iridium and other platinum group metals in the presence of naturally occurring contaminants in geological ore, PhD thesis, University of the Free State, Bloemfontein, 2014.
T.T. Chiweshe, W. Purcell, and J.A. Venter, Bull. Chem. Soc. Jpn. 88, 8 (2015).
W. Purcell, A. Roodt, S.S. Basson, and J.G. Leipoldt, Trans. Met. Chem. 16, 60 (1991).
http://www.simarsrl.com/Cataloghi/BAS%20Catalogo%20Outside%202014.pdf. Accessed 14 Jan 2016.
P.S. Parreira, C.R. Appoloni, R.M.L. Vieira, R.B. Scorzelli, L. LeCorre, and M.F. Guerra, ArcheoSciences 33, 313 (2009).
C.J. Penberthy, E.J. Oosthuyzen, and R.K.W. Merkle, Miner. Petrol. 68, 213 (2000).
L.J. Corrans, S. Afr. Inst. Min. Metall. 629 (1982).
J.A. Kinnaird, F.J. Kruger, P.A.M. Nex, and R.G. Cawthorn, Trans. Inst. Min. Metall. B 111, 23 (2002).
L.A. Cramer, J. Basson, and L.R. Nelson, J. S. Afr. Inst. Min. Metall. 517 (2004).
R.G. Cawthorn, Platin. Met. Rev. 54, 205 (2010).
J.L. Todoli, L. Gras, V. Hernandis, and J. Mora, J. Anal. At. Spectrom. 17, 142 (2002).
Y. Morishige and A. Kimura, SEI Tech. Rev. 66, 106 (2008).
P. Gaines, B. Brolin, and I.C.P. Operations, ICP operations, spectral interferences, types, avoidance and correction (2004).
H. Sereshti, N. Eskandarpour, S. Samadi, and G. Aliakbarzadeh, Int. J. Environ. Res. 8, 1075 (2014).
M.M. Cheatham, W.F. Sangrey, and W.M. White, Spectrochim. Acta Part B 48, 487 (1993).
A.R. Barnes and A.F. Newall, J. S. Afr. Inst. Min. Metall. 77 (2006).
T.T. Chiweshe, W. Purcell, and J. Venter, S. Afr. J. Chem. 66, 7 (2012).
W. Zhang, Z. Hu, Y. Liu, H. Chen, S. Gao, and R.M. Gaschning, Anal. Chem. 84, 10686 (2012).
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The authors thank the NRF, Research Fund of the University of the Free State and Inkaba yeAfrika for financial support.
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Chiweshe, T.T., Purcell, W. & Venter, J.A. Evaluation of PGE Liberation and Chromium Isolation in a Solid UG2 Chromitite Concentrates at Moderate Temperatures Using ICP-OES. JOM 68, 1691–1700 (2016). https://doi.org/10.1007/s11837-016-1811-7
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DOI: https://doi.org/10.1007/s11837-016-1811-7