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Microemulsion synthesis and magnetic properies of BaAl4Fe8O19 powders

  • Magnetic Materials and Devices
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Abstract

Al-substituted M-type hexaferrite is a highly anisotropic ferromagnetic material. In the present study, we report the synthesis and the characterization of BaAl4Fe8O19 powder from two microemulsion systems of po1yoxyethylene octylphenol ether/1, 2-propylene glycol, or ethanol/cyclohexane/water and cetrimonium bromide/1, 2-propylene glycol/cyclohexane/water. Two microemulsion systems were found to give wide stable regions. The synthesized powders were characterized with x-ray diffraction, scanning electron microscopy, and vibrating sample magnetometer. The experiment results indicated that the surfactant, co-surfactant, and oil/water ratio remarkably affected the particle size, size distribution, anisotropy and magnetic property of the powders. The powder prepared with microemulsion of po1yoxyethylene octylphenol ether/1, 2-propylene glycol/cyclohexane/water exhibited best particle character, that is, uniform thin particle morphology, large shape anisotropy, small particle size, large coercivity of 8.73 kOe, and saturation magnetization of 20.821 emu·g−1.

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Correspondence to H. Y. He.

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He, H.Y., He, Z. & Shen, Q. Microemulsion synthesis and magnetic properies of BaAl4Fe8O19 powders. JOM 63, 34–36 (2011). https://doi.org/10.1007/s11837-011-0171-6

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  • DOI: https://doi.org/10.1007/s11837-011-0171-6

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