Skip to main content
Log in

Directly smelted lead-tin alloys: A historical perspective

  • Archaeotechnology / Feature
  • Published:
JOM Aims and scope Submit manuscript

Abstract

This paper discusses evidence related to the genesis and occurrence of mixed lead-tin ore deposit consisting of cassiterite and the secondary minerals formed from galena. These evidences belong to a very long time period ranging from pre-historic to as late as the nineteenth century a.d. This type of mixed ore deposits was smelted to prepare lead-tin alloys. The composition of the alloy depended on the composition of the starting ore mixture. A nineteenth century evidence for the production of directly smelted lead-tin alloys in southern Thailand is discussed. A unique and rather uncommon metallurgical terminology in Sanskrit language—Nāgaja—was introduced in India for the tin recovered from impure lead. This suggests that Indians developed a process for recovering tin from lead-tin alloys, which in all probability was based on the general principle of fire refining. It has been shown that in the context of India the possibility of connection between the word Nāgaja and the directly smelted lead-tin alloys cannot be ruled out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S.H. Abdullah and V.M. Chmyriov, editors, Geology and Mineral Resources of Afghanistan, Book 2 (Mineral Resources of Afghanistan) (London: British Geological Society, 2008), p. 149.

    Google Scholar 

  2. G.J. Orris and J.D. Bliss, Mines and Mineral Occurrences of Afghanistan, Open File Report 02-110 (Tucson, AZ: U.S. Geology Survey, 2002), p. 68.

    Google Scholar 

  3. G.J. Orris and J.D. Bliss, in Ref. 2, p. 64.

    Google Scholar 

  4. G.J. Orris and J.D. Bliss, in Ref. 2, p. 44.

    Google Scholar 

  5. Henry Louis, The Geographical Journal, 4(3) (1894), pp. 219–237.

    Article  Google Scholar 

  6. Ivan Kostov, Mineralogy, First English edition (London: Oliver and Boyd, 1968), p. 155.

    Google Scholar 

  7. Kate Wright, Ian H. Hillier, David J. Vaughan, and Mark A. Vincent, Chemical Physics Letters, 299 (1999), pp. 527–531.

    Article  CAS  ADS  Google Scholar 

  8. Extract from Report on the Tin Deposits of Taiping, Malay Peninsula, by Geologist to the Federated Malay States, 1904, in: Sydney Fawns, Tin Deposits of the World, II ed. (London: The Mining Journal, 1907), p. 75.

  9. F.A. Genth, Proceedings of the American Philosophical Society, 24(125), 1887, pp. 23–44.

    Google Scholar 

  10. T.M. Babu, Tin in India (Bangalore: Geological Society of India, 1994), p. 59.

    Google Scholar 

  11. S.M. Gandhi, Rampura-Agucha Zinc-Lead Deposit (Bangalore: Geological Society of India, 2003), p. 22.

    Google Scholar 

  12. Henri Louis, in Ref. 5, p. 236.

    Article  Google Scholar 

  13. F.A. Genth, in Ref. 9, pp. 25–26.

    Google Scholar 

  14. Hemacandrācārya, Abhidhāna Cintāmani, ed. Nemichandra Shastri and Hargovind Shastri (Varanasi, India: Chowkhamba Vidya Bhawan, 2003), p. 256.

    Google Scholar 

  15. Baladeva Upadhyaya, Sanskrit Sāstron Kā Itihāsa, II ed. (Varanasi, India: Sharda Mandir, 1983), p. 362.

    Google Scholar 

  16. O. Kubaschewski and C.B. Alcock, Metallurgical Thermochemistry, V ed. (Oxford: Pergamon Press, 1989).

    Google Scholar 

  17. Y.K. Rao, Stoichiometry and Thermodynamics of Metallurgical Processes (Cambridge: Cambridge University Press, 1985).

    Google Scholar 

  18. Brunei Pitis, http://en.wikipedia.org/wiki/Brunei_pitis .

  19. R.F Tylecote, Metallurgy in Archaeology (London: Edward Arnold, 1962), p. 69.

    Google Scholar 

  20. Christopher P. Thornton, C.C. Lamberg-Karlovsky, Marin Liezers, and Suzanne M.M. Young, J. of Archaeological Science, 29 (2002), pp. 1451–1460.

    Article  Google Scholar 

  21. Pliny, Natural History, Book VI, (tr.) H. Rackham, First published in 1942, Reprint ed. (Cambridge, MA: Harvard University Press, 1989), p. 397.

    Google Scholar 

  22. Bharat Singh Upadhyaya, Buddha Kālīna Bhūgola (Allahabad, India: Hindi Sahitya Sammelana, 1961), p. 62.

    Google Scholar 

  23. D.R. Bhandarkar, Lectures on the Ancient History of India on the period from 650 to 325 B.C., First published (Kolkata, India: University of Calcutta, 1919), Reprint ed. (New Delhi: Asian Educational Services, 1944), p. 54.

    Google Scholar 

  24. B.C. Law, Historical Geography of Ancient India, Second and revised edition with Avant-propos by Louis Renou (Paris: Société Asiatique de Paris, 1967), p. 158.

    Google Scholar 

  25. D.C. Sircar, Studies in the Geography of Ancient and Medieval India (New Delhi: Motilal Banarasidass, 1971), p. 236.

    Google Scholar 

  26. P.C. Prasad, Foreign Trade and Commerce in Ancient India (New Delhi: Abhinav Publications, 1977), p. 66.

    Google Scholar 

  27. R.K. Dube, Bulletin of the Metals Museum, 36 (2003), pp. 3–22.

    CAS  Google Scholar 

  28. Paul Wheatley, The Golden Khersonese (Kuala Lumpur, India: University of Malay Press, 1961).

    Google Scholar 

  29. R.C. Majumdar, Suvarnadvīpa: Ancient Indian Colonies in the Far East, First published in 1927, Reprint edition (New Delhi: Gian Publishing House, 1986).

    Google Scholar 

  30. Brian Harrison, South East Asia (London: McMillan & Co., 1964), p. 10.

    Google Scholar 

  31. H.G. Quartich Wales, J. of the Malayan Branch of the Royal Asiatic Society, 18 (1940), pp. 1–85, cited in: Buddha Prakash, India and the World (Hoshiarpur: V.V. Research Institute, 1964), p. 57.

    Google Scholar 

  32. Z. Ramli, N.H. Shuhaimi, and N.A. Rahman, European J. of Social Sciences, 10(4) (2009), p. 585.

    Google Scholar 

  33. A.S. Gupta, editor, Vāmana Purāna (Varanasi, India: All India Kasiraja Trust, 1968), p. 61.

    Google Scholar 

  34. Haribhadra Suri, Samaraiccakahā, Vol. 1, ed. Ramesh Chandra Jain (New Delhi: Bhartiya Gyanapith Publications, 1993), p. 398.

    Google Scholar 

  35. Somadeva, Kathāsaritsāgara, Vol. 3, (tr.) J.S. Jha and P.C. Ojha (Patna, India: Bihar Rashtra Bhasha Parishad, 1973), p. 1142.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. K. Dube.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dube, R.K. Directly smelted lead-tin alloys: A historical perspective. JOM 62, 13–18 (2010). https://doi.org/10.1007/s11837-010-0118-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-010-0118-3

Keywords

Navigation