Abstract
Intermetallic particle electrochemistry plays significant role in localized corrosion and stress-corrosion cracking of aluminum alloys. This article presents specific examples from recent and on-going studies of stress-corrosion cracking in Al-Mg alloys and localized corrosion in Al-Cu alloys. The common approach in these examples is an explicit accounting of the intermetallic particle-dissolution characteristics, which is developed by measuring the electrochemical behavior of bulk analog compounds. Findings from these types of measurements combined with results from new and advanced small-length scale measurements confirm some of the established ideas about localized corrosion in aluminum alloys, but also lead to new insights that are important for a thorough understanding of corrosion damage accumulation.
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R.H. Brown, W.L. Fink, and M.S. Hunter, Trans. AIME, 143 (1941), p. 115.
R.G. Buchheit, J. Electrochem. Soc., 142 (1995), p. 3394.
R.G. Buchheit et al., J. Electrochem. Soc., 144 (1998), p. 2621.
R.G. Buchheit et al., J. Electrochem. Soc., 146 (1999), p. 4424.
R.G. Buchheit, M.A. Martinez, and L.P. Montes, J. Electrochem. Soc., 147 (2000), p. 119.
G.O. Ilevbare, C.S. Jeffcoate, and J.R. Scully, “Mass Transport Limited Oxygen Reduction Kinetics on Chromate Conversion Coated Al-Cu, Al-Cu-Mg and Al-Cu-Mn-Fe Intermetallic Compounds,” Proc. of the Electrochem. Soc. PV 99-27 Passivity and Localized Corrosion (Pennington, NJ: Electrochem. Soc., 1999), p. 269.
K.-A. Son et al., “Growth and Oxidation of Thin Film Al2Cu,” Proc. of the Electrochem. Soc. PV 99-27 Passivity and Localized Corrosion (Pennington, NJ: Electrochem. Soc., 1999), pp. 75–83.
N.V. Dimitrov et al., “RDE and RRDE Investigation of Copper Redistribution During Corrosion of Al2024-T3” (Paper presented at the 198th Meeting of The Electrochemical Society, Phoenix, AZ, 2000).
D.O. Sprowls and R.H. Brown, “Stress Corrosion Mechanisms for Aluminum Alloys,” Fundamental Aspects of Stress Corrosion Cracking (Houston, TX: NACE, 1969), p. 46.
B. Mazurkiewicz, Corros. Sci., 23 (1986), p. 687.
J.L. Searles (M.S. Thesis, The Ohio State University, August 2000); and J.L. Searles and R.G. Buchheit, Metall. Trans. A (in review).
M.C. Carroll et al., Scripta Mater., 42 (1999), p. 335.
J.H. Auld and B.E. Williams, Acta Cryst., 21 (1966), p. 830.
J.S. Vetrano et al., Mater. Sci. and Eng. A, 238 (1997), p. 101.
M.C. Carroll, G.S. Daehn, and M.J. Mills, Corrosion and Corrosion Prevention in Light Metals and Alloys (Pennington, NJ: Electrochem. Soc., 2001).
M.C. Carroll, R.G. Buchheit, and M.J. Mills, work in progress (2001).
M.C. Carroll et al., Proc. from the ICSMA12 Conf. (Shannon, Ireland, Elsevier: Materials Science and Engineering A, in press).
J.R. Galvele and S.M. de Micheli, Corros. Sci., 10 (1970), p. 795.
K. Sugimoto et al., Corros. Sci., 15 (1975), p. 709.
I.L. Mueller and J.R. Galvele, Corros. Sci., 17 (1977), p. 179.
K. Urushino and K. Sugimoto, Corros. Sci., 19 (1979), p. 225.
F.D. Wall and G.E. Stoner, Corros. Sci., 39 (1997), p. 835.
T.J. Warner et al., Z. Metallkd., 86 (1995), p. 7.
J.R. Scully et al., Corros. Sci., 15 (1993), p. 709.
R.G. Buchheit, J.P. Moran, and G.E. Stoner, Corrosion, 50 (1994), p. 120.
N. Dimitrov and K. Sieradzki, J. Electrochem. Soc., 147 (2000), p. 3283.
K. Sieradzki and R.C. Newman, J. Phys. Chem. Solids, 48 (1987), p. 1101.
K. Sieradzki and N. Dimitrov, “Evolution of Localized Corrosion in Aluminum Alloys 2024-T3,” Proc. of the Research Topical Symp. on Localized Corrosion (Houston, TX: NACE, 2001), p. 293.
R.G. Buchheit and R.K. Boger, “Cu Redistribution and Surface Enrichment Due to Dissolution of Al-Cu Alloys,” Proc. of the Research Topical Symp. on Localized Corrosion (Houston, TX: NACE, 2001), p. 265.
R.K. Boger, “Copper Release from Corroding Al-Cu Alloys Measured Using a Rotating Ring-Disk Electrode” (M.S. Thesis, Ohio State University, December 2000); and R.K. Boger and R.G. Buchheit, “Copper Release from Corroding Al-Cu Alloys Measured Using a Rotating Ring-Disk Electrode,” Electrochem. Soc. Proc. of the Symp. on Seawater Corrosion, PV99-26 (Pennington, NJ: The Electrochem. Soc., Inc., 2000), p. 205.
L.F. Mondolfo, Aluminum Alloys: Structure and Properties (London: Butterworths, 1976), p. 499.
R.G. Buchheit et al., J. Electrochem. Soc., 144 (1997), p. 2621.
T. Suter and H. Boehni, Electrochim. Acta, 42 (1997), p. 3275.
T. Suter and H. Boehni, Electrochim. Acta, 43 (1998), p. 2843.
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For more information, contact R.G. Buchheit, The Ohio State University, Department of Materials Science and Engineering, 477 Watts Hall, 2041 College Road, Columbus, Ohio 43210; (614) 292-6085; fax (614) 292-9857; e-mail buchheit.8@osu.edu.
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Buchheit, R.G., Boger, R.K., Carroll, M.C. et al. The electrochemistry of intermetallic particles and localized corrosion in Al alloys. JOM 53, 29–33 (2001). https://doi.org/10.1007/s11837-001-0084-x
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DOI: https://doi.org/10.1007/s11837-001-0084-x