Skip to main content
SpringerLink
Log in

Strong, and recyclable thermosets cross-linked by MWCNT/poly(aryl ether ketone) containing furan based on Diels-Alder cycloaddition

  • Polymer, Industrial Chemistry
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Multi-walked carbon nanotube (MWCNT)/poly(aryl ether ketone) networks cross-linked by Diels-Alder cycloaddition possess outstanding mechanical and rheological properties. Poly(aryl ether ketone) containing pendant furan (PAEK-Fu) was synthesized, which had excellent thermal and mechanical properties, and a series of cross-linked materials with reversible covalent cross-linked crosslinking network were synthesized through a furan/MWCNTs Diels-Alder (D-A) reaction between PAEK-Fu and MWCNTs. Thermal and mechanical properties for MWCNT/PAEK-Fu composites were studied, and after crosslinking, MWCNT/PAEK-Fu composites exhibited good flexibility and resistance against organic solvents. After heating to 180 °C, the cross-linked MWCNT/PAEK-Fu composite membranes could be dissolved in NMP. This work demonstrates that the poly(aryl ether ketone)s can be made into recyclable thermoset materials using the concept of associative dynamic bonding. Given the dramatically increasing interest in environmentally sustainable materials, this MWCNT/poly(aryl ether ketone) interaction mode provides a robust approach to high performance engineering plastics with improved performance compared with the thermoplastic counterparts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Akiba and A. S. Hashim, Prog. Polym. Sci., 22, 475 (1997).

    Article  CAS  Google Scholar 

  2. S. H. Goodman and H. Dodiuk-Kenig Handbook of thermosetplastics, 3rd ed., Elsevier Science Ltd., New York (2013).

    Google Scholar 

  3. Z. A. Jin, Z. Y. Han, C. Chang, S. Z. Sun and H. Y. Fu. Compos. Sci. Technol., 228, 109660 (2022).

    Article  CAS  Google Scholar 

  4. S. M. Hosseini, M. S. Banijamali, S. K. Farahani and S. Bandehali, Korean J. Chem. Eng., 39, 2491 (2022).

    Article  CAS  Google Scholar 

  5. J. Zhang, V. S. Chevali, H. Wang and C. H. Wang, Compos. B. Eng., 193, 108053 (2020).

    Article  CAS  Google Scholar 

  6. T. E Long, Science, 344, 706 (2014).

    Article  CAS  PubMed  Google Scholar 

  7. L. Yue, V. S. Bonab, D. Yuan, A. Patel, V. Karimkhani and I. Manas-Zloczower, Global Challenges, 1800076 (2019).

  8. S. Q. Ma and D. C. Webster. Prog. Polym. Sci., 76, 65 (2018).

    Article  CAS  Google Scholar 

  9. K. Yu, Q. Shi, M. L. Dunn, T. Wang and H. J. Qi, Adv. Fund. Mater., 26, 6098 (2016).

    Article  CAS  Google Scholar 

  10. Y. Yuan, Y. Sun, S. Yan, J. Zhao, S. Liu, M. Zhang, X. Zheng and L. Jia, Nat. Commun., 8, 1 (2017).

    Article  Google Scholar 

  11. A. Simonyan and I. Gitsov, Langmuir, 24, 11431 (2008).

    Article  CAS  PubMed  Google Scholar 

  12. N. Zydziak, B. Yameen and C. Barner-Kowollik, Polym Chem-UK, 4, 4072 (2013).

    Article  CAS  Google Scholar 

  13. M. M. Bernal, M. Liras, R. Verdejo, M. A. López-Manchado, I. Quijada-Garrido and R. París, Polymer, 52, 5739 (2011).

    Article  CAS  Google Scholar 

  14. Y. L. Liu and Y. W. Chen. Macromol. Chem. Phys., 208, 224 (2007).

    Article  CAS  Google Scholar 

  15. C. M. Chang and Y. L. Liu, Carbon, 47, 3041 (2009).

    Article  CAS  Google Scholar 

  16. J. Bai and Z. X. Shi, ACS Appl. Mater. Inter., 9, 27213 (2017).

    Article  CAS  Google Scholar 

  17. G. M. R. Lima, F. Orozco, F. Picchioni, I. Moreno-Villoslada, A. Pucci, R. K. Bose and R. Araya-Hermosilla, Polymers, 11, 1885 (2019).

    Article  CAS  Google Scholar 

  18. Y. P. Wang, M. Z. Liu, T. Liu, D. Y. Lu, Y. Sun, H. B. Zhang and Z. H. Jiang, Compos. Sci. Technol., 143, 82 (2017).

    Article  CAS  Google Scholar 

  19. C. R. Rong, G. Ma, S. L. Zhang, L. Song, Z. Chen, G. B. Wang and P. M. Ajayan, Compos. Sci. Technol., 70, 380 (2010).

    Article  CAS  Google Scholar 

  20. P. Chen, H. Z. Wang, J. Su, Y. J. Tian, S. F. Wen, B. Su, C. Yang, B. L. Chen, K. Zhou, C. Z. Yan and Y. S. Shi, Adv. Mater., 34, 2200750 (2022).

    Article  CAS  Google Scholar 

  21. Y. Zhang, A. A. Broekhuis, M. C. Stuart, T. Fernandez Landaluce, D. Fausti, P. Rudolf and F. Picchioni, Macromolecules, 41, 6141 (2008).

    Article  CAS  Google Scholar 

  22. M. M. Guo, B. J. Liu, L. Li, C. Liu, L. F. Wang and Z.H. Jiang, J. Power. Sources, 195, 11 (2010).

    Article  CAS  Google Scholar 

  23. Y. P. Wang, M. Z. Liu, Y. Sun, Y. S. Shang, B. Jiang, H. B. Zhang and Z. H. Jiang, RSC Adv., 5, 100856 (2015).

    Article  CAS  Google Scholar 

  24. W. Z. Yuan, Y. Mao, H. Zhao, J. Z. Sun, H. P. Xu, J. K. Jin, Q. Zhang and B. Z. Tang, Macromolecules, 41, 701 (2008).

    Article  CAS  Google Scholar 

  25. G. Dhanaraju, B. S. Ben and R. K. Pittala, Polymer, 245, 124734 (2022).

    Article  CAS  Google Scholar 

  26. J. N. Xu, Z. Y. Li, B. Wang, F. Y. Liu, Y. D. Liu and F. Q. Liu, J. Appl. Polym. Sci., 136, 47352 (2019).

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by Jilin Province Science and Technology Department Project (20210508026RQ; 20220508026RC) and Jilin Province Development and Reform Commission Project (2022C040).

Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin, 132022, China

    Yongpeng Wang, Heng Wang, Qingwen Zhang, Yingyuan Zhang & Mengzhu Liu

  2. Sinodentex Co., Ltd, Changchun, China

    Pengtao Yan

  3. College of Chemistry, National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer, Jilin University, Changchun, 130012, China

    Mengzhu Liu & Haibo Zhang

Authors
  1. Yongpeng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Heng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Qingwen Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yingyuan Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Pengtao Yan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Mengzhu Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Haibo Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mengzhu Liu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, Y., Wang, H., Zhang, Q. et al. Strong, and recyclable thermosets cross-linked by MWCNT/poly(aryl ether ketone) containing furan based on Diels-Alder cycloaddition. Korean J. Chem. Eng. 40, 2026–2034 (2023). https://doi.org/10.1007/s11814-023-1481-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-023-1481-4

Keywords

Search

Navigation