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Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

As N-isopropyl-2-propanamine+alkanol (C1-C3) systems are potential absorbents for CO2 capture, we measured density (ρ), viscosity (η) and the ultrasonic speed data (u) for N-isopropyl-2-propanamine (DIPA) with alkanol (C1-C3) at T=(298.15 and 308.15) K and 0.1 MPa. The experimental density (ρ), viscosity (η) and ultrasonic speed (u) data were used to derive excess molar volume (V Em ), apparent, partial, and excess partial molar volume, deviation in viscosity and deviation in ultrasonic speed, excess isentropic compressibility (\(\kappa _s^E\)). We predicted the V Em values using the Prigogine-Flory-Patterson theory (PFP) and by Nakata and Sakurai model. An Ab initio approach was proposed for the excess isentropic compressibility \((\kappa _s^E)\) and Δη data which not only reproduces the experimental data but also gives important parameters that describe the extent of depolymerization on mixing and strength of intermolecular interactions.

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Acknowledgement

This work was supported by Netaji Subhas University of Technology, New Delhi and Inha University Research Grant.

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Author notes

  1. Both authors have same contribution.

Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Yonghyeon Campus, Incheon, 22212, Korea

    Sweety Verma & Yongjin Lee

  2. Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, 131 039, India

    Payal Bhagat

  3. Department of Applied Sciences and Humanities, Panipat Institute of Engineering and Technology, Samalkha, 132102, India

    Suman Gahlyan

  4. Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, 131 039, India

    Manju Rani

  5. Department of Chemistry, Maharshi Dayanand University, Rohtak, 124001, India

    Naveen Kumar & Rajesh Kumar Malik

  6. Department of Chemistry, Netaji Subhas University of Technology, New Delhi, 110078, India

    Sanjeev Maken

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  1. Sweety Verma
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  2. Payal Bhagat
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  3. Suman Gahlyan
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Correspondence to Yongjin Lee or Sanjeev Maken.

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Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture

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Verma, S., Bhagat, P., Gahlyan, S. et al. Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture. Korean J. Chem. Eng. 40, 2293–2302 (2023). https://doi.org/10.1007/s11814-023-1422-2

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  • DOI: https://doi.org/10.1007/s11814-023-1422-2

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