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Selective absorption of H2S and CO2 from simulated coke oven gas by aqueous blends of N-methyldiethanolamine and tetramethylammonium glycine

  • Environmental Engineering
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Abstract

Tetramethylammonium glycine ([N1111][Gly]) can be completely ionized into cation [N1111]+ and anion [Gly]- in aqueous solution. The anion contains an amino -NH2 and a carboxyl -COO-, both of which can react with hydrogen sulfide (H2S). Therefore, [N1111][Gly] was used to promote the selective absorption of H2S in coke oven gas (COG) by N-methyldiethanolamine (MDEA). The absorption performance and selectivity of H2S in the aqueous solution of MDEA-[N1111][Gly] were investigated. The effects of MDEA mass fraction, [N1111][Gly] mass fraction, temperature, H2S partial pressure and CO2 partial pressure on the absorption capacity and selectivity were clarified. The results showed that an aqueous solution of MDEA-[N1111][Gly] has good selectivity for H2S in COG. The absorption capacity was large and the mass fraction of the solute in the absorbent reached more than 0.55, thereby having outstanding advantages in the aspects of saving energy consumption and operating cost and having a good application potential.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51776072 and NO. 52106009), the Fundamental Research Funds for the Central Universities (No. 2022MS108) and the Natural Science Foundation of Hebei Province (No. E2021502024 and No.E2020502044).

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Authors and Affiliations

  1. Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding, 071003, P. R. China

    Pan Zhang, Yuetong Zhao, Xiangfeng Tian, Yanxi Ji, Yuxuan Shu, Kun Fu, Dong Fu & Lemeng Wang

  2. Longyuan (Beijing) Carbon Assets Management Technology Co., Ltd. Peking, 100037, P. R. China

    Xiangfeng Tian

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  1. Pan Zhang
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  2. Yuetong Zhao
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  3. Xiangfeng Tian
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  5. Yuxuan Shu
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  6. Kun Fu
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  7. Dong Fu
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  8. Lemeng Wang
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Correspondence to Lemeng Wang.

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The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Zhang, P., Zhao, Y., Tian, X. et al. Selective absorption of H2S and CO2 from simulated coke oven gas by aqueous blends of N-methyldiethanolamine and tetramethylammonium glycine. Korean J. Chem. Eng. 39, 3039–3047 (2022). https://doi.org/10.1007/s11814-022-1204-2

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  • DOI: https://doi.org/10.1007/s11814-022-1204-2

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