Abstract
g/C3N4-ZnO composite catalysts were synthesized through surface hybridization of the delocalized conjugated-π structure of g/C3N4 with the closely contacted surface of ZnO via a successive and simultaneous calcination procedure, and two kinds of photocatalysts, g/C3N4-ZnO1 and g/C3N4-ZnO2, were obtained. Heterojunctions were formed between the two components, which promote the separation of photogenerated carriers efficiently, and then enhanced the degradation of 100 mg/L of AMX The degradation rate of g/C3N4-ZnO1 was 1.54, 11.33, and 2.52-fold that of g/C3N4-ZnO2, g/C3N4 and ZnO, respectively, at a 3.5-h reaction period, with the dosage of 0.3 g/L, and solution pH at 7.0±0.2. The recycle and reuse ability was excellent and 90.5% of AMX mitigation was achieved in the fifth cycle. For g/C3N4-ZnO1, electrons migrated from the conduction band of g/C3N4 to that of ZnO via the heterojunction. ·OH and h+ were the main active species for AMX degradation, compared to ·O −2 dominated for g/C3N4. Twelve intermediate products were identified, and two degradation pathways were inferred for g/C3N4-ZnO1 and g/C3N4-ZnO2, respectively. Finally, transformation products without lactam rings were achieved, which lost most of the antibacterial potencies, and the ecotoxicity was also dramatically decreased as indicated by the ECOSAR program.
Similar content being viewed by others
References
A. Timm, E. Borowska, M. Majewsky, S. Merel, C. Zwiener, S. Bräse and H. Horn, Sci. Total Environ., 651, 1605 (2019).
L. Yao, Y. Wang, L. Tong, Y. Deng, Y. Li, Y. Gan, W. Guo, C. Dong, Y. Duan and K. Zhao, Ecotoxicol. Environ. Saf., 135, 236 (2017).
W. Chen, J. Shen, Z. Wang, X. Liu, Y. Xu, H. Zhao and D. Astruc, Chem. Sci., 12(35), 11722 (2021).
N. Taoufik, W. Boumya, M. Achak, M. Sillanpää and N. Barka, J. Environ. Manage., 288, 112404 (2021).
B. Wei, C. Niu, G. Zhou, J. Sun, Q. Mei, Z. An, M. Li and M. He, Appl. Surf. Sci., 391, 72 (2017).
D. Zhu and Q. Zhou, Appl. Catal. B, 282, 119574 (2021).
N. Ghane, S. K. Sadrnezhaad and S. M. Hosseini H., Appl. Surf. Sci., 534, 147563 (2020).
C. B. Ong, L. Y. Ng and A. W. Mohammad, Renewable Sustainable Energy Rev., 81, 536 (2018).
N. Li, Y. Tian, J. Zhao, J. Zhang, W. Zuo, L. Kong and H. Cui, Chem. Eng. J., 352, 412 (2018).
Y. Liu, H. Liu, H. Zhou, T. Li and L. Zhang, Appl. Surf. Sci., 466, 133 (2019).
D. Shen, X. Li, C. Ma, Y. Zhou, L. Sun, S. Yin, P. Huo and H. Wang, New J. Chem., 44(38), 16390 (2020).
W. Li, D. Li, J. Wang, Y. Shao, J. You and F. Teng, J. Mol. Catal. A: Chem., 380, 10 (2013).
H. Yu, J. Huang, L. Jiang, Y. Shi, K. Yi, W. Zhang, J. Zhang, H. Chen and X. Yuan, Chem. Eng. J., 402, 126187 (2020).
E.-P. Bao, R. Dong, S. Zhang, H. Li, W. Zhang, J. Zou and Q. Xu, Catal. Lett., 151(12), 3437 (2021).
X. Yuan, S. Qu, X. Huang, X. Xue, C. Yuan, S. Wang, L. Wei and P. Cai, Chem. Eng. J., 416, 129148 (2021).
N. Kumaresan, M. M. A. Sinthiya, M. Praveen Kumar, S. Ravichandra and R. Ramesh Babu, Arabian J. Chem., 13, 2826 (2020).
F. He, B. Zhu., B. Cheng, J. Yu, W. Ho and W. Macyk, Appl. Catal. B, 272, 119006 (2020).
Z. Li, N. Xiong and G. Gu, Dalton Trans., 48(1), 182 (2018).
C. A. Jaramillo-Páez, J. A. Navío, M. C. Hidalgo and M. Macías, Catal. Today, 313, 12 (2018).
C. Zhang, M. Jia, Z. Xu, W. Xiong, Z. Yang, J. Cao, H. Peng, H. Xu, Y. Xiang and Y. Jing, Chem. Eng. J., 430, 132652 (2022).
B. Liu, C. Bie, Y. Zhang, L. Wang, Y. Li and J. Yu, Langmuir, 37(48), 14114 (2021).
L. Shi, F. Wang, Y. Wang, D. Wang, B. Zhao, L. Zhang, D. Zhao and D. Shen, Sci. Rep., 6(1), 21135 (2016).
J. Wen, J. Xie, X. Chen and X. Li, Appl. Surf. Sci., 391, 72 (2017).
J. Qu, Y. Du, Y. Feng, J. Wang, B. He, M. Du, Y. Liu and N. Jiang, Mater. Sci. Semicond. Process, 112, 105023 (2020).
K. N. Van, H. T. Huu, V. N. Nguyen Thi, T. L. Le Thi, D. H. Truong, T. T. Truong, N. N. Dao, V. Vo, D. L. Tran and Y. Vasseghian, Chemosphere, 289, 133120 (2022).
Y. Nosaka, M. Nishikawa and A. Y. Nosaka, Molecules, 19(11), 18248 (2014).
Z. Diao, J. Jin, M. Zou, H. Liu, J. Qin, X. Zhou, W. Qia, P. Guo, L. Kong and W. Chu, Sep. Purif. Technol., 278, 119620 (2021).
A. G. Trovó, R. F. Pupo Nogueir, A. Agüera, A. R. Fernandez-Aba and S. Malato, Water Res., 45(3), 1394 (2011).
Y. Zhang, Y. Xu, Y. Zhang and L. Teik Thye, Chem. Eng. J., 372, 420 (2019).
I. Gozlan, A. Rotstei and D. Avisa, Chemosphere, 91(7), 985 (2013).
X. Zhang, Y. Guo, Y. Pan and X. Yang, Sci. Ecotechnol., 3, 100051 (2020).
H. Zeng, H. Zhan, L. Deng and Z. Shi, J. Water Process. Eng., 33, 101084 (2020).
B. Wei, C. Niu, G. Zhou, J. Sun, Q. Mei, Z. An, M. Li and M. He, Environ. Res., 207, 112623 (2022).
P. Chen, F. Wang, Z.-F. Chen, Q. Zhang, Y. Su, L. Shen, K. Yao, Y. Liu, Z. Ca, W. Lv and G. Liu, Appl. Catal. B, 204, 250 (2017).
Acknowledgements
This work; was supported by the National Natural Science Foundation of China (51978052) and Beijing Municipal Education Commission through the Innovative Transdisciplinary Program “Ecological Restoration Engineering (No. GJJXK210102)”.
Author information
Authors and Affiliations
Corresponding author
Additional information
Supporting Information
Additional information as noted in the text. This information is available via the Internet at http://www.springer.com/chemistry/journal/11814.
Supporting Information
11814_2022_1181_MOESM1_ESM.pdf
Construction of g/C3N4-ZnO composites with enhanced visible-light photocatalytic activity for degradation of amoxicillin
Rights and permissions
About this article
Cite this article
Sun, S., Li, S., Hao, Y. et al. Construction of g/C3N4-ZnO composites with enhanced visible-light photocatalytic activity for degradation of amoxicillin. Korean J. Chem. Eng. 39, 3377–3388 (2022). https://doi.org/10.1007/s11814-022-1181-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-022-1181-5