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Selective separation of gallium from various ions by polymer inclusion membranes based on CTA/PVC blend using TOPO as carrier

  • Separation Technology, Thermodynamics
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Abstract

Selective transport of gallium from HCl media containing other ions such as Zn, Co, and Ni, by polymer inclusion membranes (PIM), based on CTA/PVC blend using trioctylphosphine oxide (TOPO) as carrier and 2-nitrophenylpentyl ether (2-NPPE) as plasticizer is studied. The effect of various parameters such as the HCl concenration in the feed, HCl concenration in the stripping phase, carrier (TOPO) concentration, 2-NPPE concentration, the cellulose triacetate (CTA)/poly(vinyl chloride) (PVC) as the polymer-blend was experimentally studied and the optimum conditions were determined. It was possible to selectively extract gallium ions from the ions (Zn, Co, and Ni) in the acidic solutions. The separation factors of gallium over Zn, Co, and Ni, at the optimum conditions, were found to be of 963, 702, and 514, respectively, for the feed solution of 100 mg/dm3 Ga, 1,000 mg/dm3 Zn, 600 mg/dm3 Co, and 600 mg/dm3 Ni.

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Acknowledgement

The authors wish to thank the Kyrgyz-Turkish Manas University, Kyrgyzstan for providing facilities and financial support.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Kyrgyz-Turkish Manas University, 56, Tynchtyk Avenue, Djal, 770043, Bishkek, Kyrgyzstan

    Osman Tutkun & Kurmancan Kaparova

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  1. Osman Tutkun
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  2. Kurmancan Kaparova
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Correspondence to Osman Tutkun.

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The authors do not have any conflict of interest in the publication of the interest.

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Tutkun, O., Kaparova, K. Selective separation of gallium from various ions by polymer inclusion membranes based on CTA/PVC blend using TOPO as carrier. Korean J. Chem. Eng. 39, 1011–1019 (2022). https://doi.org/10.1007/s11814-021-0986-y

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  • DOI: https://doi.org/10.1007/s11814-021-0986-y

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