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Preparation of nano-sized Mg-doped copper silicate materials using coal gangue as the raw material and its characterization for CO2 adsorption

  • Separation Technology, Thermodynamics
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Abstract

This work presents a simple method for the preparation of the Mg-doped nanocomposite copper silicates (Mgx-Cu1−x-SiO3) (x=0.25, 0.5, 0.75 and 0.9) using coal gangue waste as the silicon source for CO2 capture at low temperature. The as-prepared Mgx-Cu1−x-SiO3 was systemically characterized by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller surface area analysis (BET). The results suggest that all Mgx-Cu1−x-SiO3 possess large surface areas, micropores and mesoporous structures composed of the agglomerates of small nanoparticles. They exhibit high CO2 adsorption capacity at 298.15 K under 1 bar, and that of Mg0.9-Cu0.1-SiO3 was the highest with the value of 16.73 cm3/g. The Freundlich isotherm model fits the CO2 adsorption isotherm well. Thermodynamic analysis indicates that the CO2 adsorption on Mg0.9-Cu0.1-SiO3 is exothermic (ΔH°<0), chaotic (ΔS°<0), and spontaneous (ΔG°<0). This work highlights the low-temperature adsorption behavior of silicate materials on CO2, which can provide some research basis for the utilization of silica in coal gangue.

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Acknowledgements

This work; was supported by the National Natural Science Foundation of China (Project No. 21466028), the Inner Mongolia Science and Technology Key Projects, the Program for Grassland Excellent Talents of Inner Mongolia Autonomous Region, and training plan of academic backbone in youth of Inner Mongolia University of Technology.

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Authors and Affiliations

  1. College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot, 010051, China

    Yu Wu, Zhaojun Wu, Kai Liu, Fu Li, Yujie Pang & Jianbin Zhang

  2. Inner Mongolia Engineering Research Center for CO2 Capture and Utilization, Hohhot, 010051, China

    Yu Wu, Zhaojun Wu, Kai Liu, Fu Li, Yujie Pang, Jianbin Zhang & Huayan Si

  3. School of Materials Science and Engineering, Hebei Provincial Key Laboratory of Traffic Engineering materials, Shijiazhuang Tiedao University, Shijiazhuang, 050043, China

    Huayan Si

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  1. Yu Wu
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Correspondence to Jianbin Zhang or Huayan Si.

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Preparation of nano-sized Mg-doped copper silicate materials using coal gangue as the raw material and its characterization for CO2 adsorption

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Wu, Y., Wu, Z., Liu, K. et al. Preparation of nano-sized Mg-doped copper silicate materials using coal gangue as the raw material and its characterization for CO2 adsorption. Korean J. Chem. Eng. 37, 1786–1794 (2020). https://doi.org/10.1007/s11814-020-0593-3

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