Abstract
Nanoporous activated garlic stem carbon (AGSC) was prepared from garlic stem waste and used to remove As(III)from synthetic water under complete batch experiments. Characterization studies of AGSC were performed by FTIR, SEM, EDX, BET, XPS and XRD techniques. Batch adsorption experiments were carried out to study the adsorption of As(III) onto AGSC. Maximum removal of 93.3% of As(III) was obtained at optimum condition of pH 6, the adsorbent dose 5 g/L, equilibrium time 150 min, initial As(III) concentration 400 µg/L and temperature 298 K. Both Langmuir and Temkin isotherm model fitted well to the experimental data as compared to Freundlich isotherm. Kinetics indicated that the adsorption of As(III) was more suitable for pseudo-second-order than pseudo-first-order and Elovich model. The mass transfer mechanism could be described by Weber-Morris and Boyd mass transfer model. The maximum adsorption capacity of AGSC for As(III) removal was found to be 192.30 µg/g. The negative enthalpy and free energy change indicated that the adsorption process of As(III) onto AGSC was exothermic and spontaneous. The negative value of entropy change suggested decreasing randomness at the AGSC-aqueous As(III) interface during As(III) adsorption.
Similar content being viewed by others
References
S. Ayoob, A. K. Gupta and V.T. Bhat, Crit. Rev. Environ. Sci. Technol., 38, 401 (2008).
Y. Wang and D. C. W Tsang, J. Environ. Sci., 25, 2291 (2013).
S. M. Cohen, L. L. Arnold, B. D. Beck, A. S. Lewis and M. Eldan, Crit. Rev. Toxicol, 43, 711 (2013).
World Health Organization (WHO)/UNICE, Progress on drinking-water and sanitation (2014).
M. Vithanage, I. Herath, S. Joseph, J. Bundschuh, N. Bolan, Y. S. Ok, M. B. Kirkham and J. Rinklebe, Carbon, 113, 219 (2017).
P. L. Smedley and D. G. Kinniburgh, Appl. Geochem., 17, 517 (2002).
A. Kumar, J. Pandey and S. Kumar, Korean J. Chem. Eng., 35(I), 456 (2018).
T. Nawaz, M. Iqbal, S. Zulfiqar and M. I. Sarwar, Korean J. Chem. Eng., 35(6), 860 (2018).
N. N. Greenwood and A. Earnshaw, Chemistry of the elements, 3thEd., Pergamon Press, Oxford, United Kingdom (1984).
World Health Organization (WHO), Guidelines for Drinking-water Quality, 4thEd. (2011).
P. B. Tchounwou, B. Wilson and A. Ishaque, Rev. Environ. Health, 14, 211 (1999).
J. E. Greenleaf, J. C. Lin and A. K. Sengupta, Environ. Prog., 25, 300 (2006).
J.W. Wang, D. Bejan and N.J. Bunce, Environ. Sci. Technol., 37, 4500 (2003).
V. Pallier, G. Feuillade-Cathalifaud, B. Serpaud and J. C. Bollinger, J. Colloid Interface Sci., 342, 26 (2011).
W. Wan, T.J. Pepping, T. Banerji, S. Chaudhari and D.E. Giammar, Water Res., 45, 384 (2011).
H. Park and H. Choi, Water Res., 45, 1933 (2011).
S. O. Lesmana, N. Febriana, F. E. Soetaredjo, J. Sunarso and S. Ismadji, Biochem. Eng. J., 44, 19 (2009).
M. Taheran, M. Naghdi, S. K. Brar, E. J. Knystautas, M. Verma, A. A. Ramirez, R. Y. Surampalli and J. R. Valero, Sci. Total Environ., 571, 772 (2016).
S. Liu, C. Ni, H. Su, H. Liu, R. Chen, P. Li and Y. Wei, RSC Adv., 6, 30840 (2016).
M. Thommes, K. Kaneko, A. V. Neimark, J. P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol and K. S. W. Sing, Pure Appl. Chem., 87, 1051 (2015).
L. Li, X.L. Liu, H.Y. Geng, B. Hu, G.W Song and Z.S. Xu, J. Mater. Chem. A, 1, 10292 (2013).
P. Mondal, C. B. Majumder and B. Mohanty, Ind. Eng. Chem. Res., 46, 2550 (2007).
B. H. Hameed and A. A. Ahmad, J. Hazard. Mater., 164, 870 (2009).
J. Xua, L. Chena, H. Qu, Y. Jiao, J. Xie and G. Xing, Appl. Surf. Sci., 320, 674 (2014).
M. S. Podder and C. B. Majumdar, J. Mol. Liq., 2, 382 (2015).
C. Saka, J. Anal. Appl. Pyrolysis, 95, 21 (2012).
A. Swiatkowski, M. Pakula, S. Biniak and M. Walczyk, Carbon, 42, 3057 (2004).
Y. Su, X. Sun, X. Zhou, C. Dai and Y. Zhang, J. Environ. Sci., 36, 1 (2015).
H. Trevino-Cordero, L. G. Juarez-Aguilar, D. I. Mendoza-Castillo, V. Hernandez-Montoya, A. Bonilla-Petriciolet and M. A. Montes-Moran, Ind. Crops Prod., 42, 315 (2013).
S. Biniak, G. Szymanski, J. Siedlewski and A. Swiatkowski, Carbon, 35, 1799 (1997).
J. H. Zhou, Z.J. Sui, J. Zhu, P. Li, D. Chen, Y.C. Dai and WK. Yuan, Carbon, 45, 785 (2007).
U. Shafique, A. Ijaz, M. Salman, W Zaman, N. Jamil and R. Rehman, J. Taiwan Inst. Chem. Eng., 43, 256 (2012).
Z. Gu, J. Fang and B. Deng, Environ. Sci. Technol., 39, 3833 (2005).
J. Youngran, F. Maohong, J. V. Leeuwen and J. F. Belczyk, J. Environ. Sci., 19, 910 (2007).
M. A. Alam, W. A. Shaikh, M. O. Alam, T. Bhattacharya, S. Chakraborty, B. Show and I. Saha, Appl. Water Sci., 8, 198 (2018).
Y. Chammui, P. Sooksamiti, W. Naksata, S. Thiansem and O. Arqueropanyo, Chem. Eng. J., 240, 202 (2014).
A. E. Nemr, A. Khaled, O. Abdelwahab and A. El-Sikaily, J. Hazard. Mater., 152, 263 (2008).
M. D. Meitei and M. N. V Prasad, Ecol. Eng., 71, 308 (2014).
A. Goswami, P. K. Raul and M. K. Purkait, Chem. Eng. Res. Des., 90, 1287 (2012).
H. Li, G. Huang, C. An, J. Hu and S. Yang, Ind. Eng. Chem. Res., 52, 15923 (2013).
M. K. Mondal, G. Mishra and P. Kumar, J. Sustain. Dev. Energy Water Environ. Syst., 3, 405 (2015).
V. Vadivelan and K. V. Kumar, J. Colloid Interface Sci., 286, 90 (2005).
S. Azizian, J. Colloid Interface Sci., 276, 47 (2004).
S. Srivastava, S. B. Agrawal and M. K. Mondal, Korean J. Chem. Eng., 33, 567 (2016).
C. Aharoni and F. C. Tompkins, Adv. Catal., 21, 1 (1970).
R. Narayan, R. P. Meena, A. K. Patel, A. K. Prajapati, S. Srivastava and M. K. Mondal, Environ. Prog. Sustain. Energy, 35, 95 (2015).
Y.F. Lam, L.Y. Lee, S.J. Chua, C.S. Shee and S. Gan, Ecotoxicol. Environ. Saf., 127, 61 (2016).
R. Soni and D. P. Shukla, Chemosphere, 219, 504 (2019).
M. A. Malana, R. B. Qureshi and M. N. Ashiq, Chem. Eng. J., 172, 721 (2011).
O. S. Thirunavukkarasu, T. Viraraghavan and K. S. Subramanian, Water SA, 29, 161 (2003).
V. K. Gupta, V. K. Saini and N. Jain, J. Colloid Interface Sci, 288, 55 (2005).
T. Turk and I. Alp, J. Ind. Eng. Chem., 20, 732 (2014).
N. V Vinh, M. Zafar, S.K. Behera and H.S. Park, Inf. J. Environ. Sci. Technol., 12, 1283 (2015).
D. S. Tavares, C. B. Lopes, J. P. Coelho, M. E. Sanchez, A. I. Garcia, A. C. Duarte, M. Otero and E. Pereira, Water Air Soil Pollut., 223, 2311 (2012).
M. E. Lee, P. Jeon, J. Kim and K. Baek, Korean J. Chem. Eng., 35(7), 1409 (2018).
L. Lin, W Qiu, D. Wang, Q. Huang, Z. Song and H. W. Chau, Ecotox. Environ. Safe., 144, 514 (2017).
U. Maheshwari, B. Mathesan and S. Gupta, Process Saf. Environ. Prot., 98, 198 (2015).
W J. Weber and J. C. Morris, J. Sanit. Eng. Div., 89, 31 (1993).
A.B. Albadarina, C. Mangwandi, A.A.H. Al-Muhtaseb, G.M. Walker, S. J. Allena and M. N. M. Ahmad, Chem. Eng. J., 179, 193 (2012).
S. Srivastava, S. B. Agrawal and M. K. Mondal, Ecol. Eng., 85, 56 (2015).
R. Foroutan, R. Mohammadi and B. Ramavandi, Korean J. Chem. Eng., 35(1), 234 (2018).
T. Keleti, Biochem. J., 209, 277 (1983).
P. B. Bhaskar, A. K. Gupta, S. Ayoob and S. Kandu, Colloids Surf. A: Physicochemical. Eng. Aspects, 281, 237 (2006).
X. Yu, S. Tong, M. Ge, J. Zuo, C. Cao and W Song, J. Mater. Chem. A, 1, 959 (2013).
G. Zhang, J. Qu, H. Liu and R. Wu, Water Res., 41, 1921 (2007).
R. Prabhakar and S. R. Samadder, J. Mol. Liq., 250, 192 (2018).
S. Zhang, H. Niu, Y. Cai, X. Zhao and Y. Shi, Chem. Eng. J., 158, 599 (2010).
S. R. Chowdhury and E. K. Yanful, J. Environ. Manage., 91, 2238 (2010).
T. G. Asere, K. Verbeken, D. A. Tessema, F. Fufa, C. V. Stevens and G. D. Laing, Environ. Sci. Pollut. Res., 24, 20446 (2017).
Acknowledgements
Authors are grateful to Indian Institute of Technology (BHU), Varanasi, India, for providing the necessary facilities related to research work. The authors also express gratitude for the financial assistance provided by MHRD, India.
Author information
Authors and Affiliations
Corresponding author
Supporting Information
11814_2019_376_MOESM1_ESM.pdf
Hazardous As(III) removal using nanoporous activated carbon of waste garlic stem as adsorbent: Kinetic and mass transfer mechanisms
Rights and permissions
About this article
Cite this article
Prajapati, A.K., Mondal, M.K. Hazardous As(III) removal using nanoporous activated carbon of waste garlic stem as adsorbent: Kinetic and mass transfer mechanisms. Korean J. Chem. Eng. 36, 1900–1914 (2019). https://doi.org/10.1007/s11814-019-0376-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-019-0376-x