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One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation

  • Catalysis, Reaction Engineering
  • Published:
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Abstract

We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

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Author notes

  1. These authors contributed equally to this work.

Authors and Affiliations

  1. Department of Chemical Engineering, Kyung Hee University, Yongin, 17104, Korea

    Xiangyun Xiao & Taekyung Yu

  2. Department of Material Science & engineering, Korea University, Seoul, 02841, Korea

    Tae-Uook Kang

  3. Advanced Analysis Center, Korea Institute of Science and Technology, Seoul, 02792, Korea

    Tae-Uook Kang & Jae-Pyung Ahn

  4. Materials Architecturing Research Center, Korea Institute of Science and Technology, Seoul, 02792, Korea

    Hyobin Nam & Seung Yong Lee

  5. Department of Nanomaterials Science and Engineering, Korea University of Science and Technology, Daejeon, 34113, Korea

    Hyobin Nam & Seung Yong Lee

  6. School of Chemical Engineering, Sungkyunkwan University, Suwon, 16419, Korea

    Suk Ho Bhang

Authors
  1. Xiangyun Xiao
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  2. Tae-Uook Kang
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  3. Hyobin Nam
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  4. Suk Ho Bhang
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  5. Seung Yong Lee
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  7. Taekyung Yu
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Corresponding authors

Correspondence to Seung Yong Lee, Jae-Pyung Ahn or Taekyung Yu.

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Xiao, X., Kang, TU., Nam, H. et al. One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation. Korean J. Chem. Eng. 35, 2379–2383 (2018). https://doi.org/10.1007/s11814-018-0164-z

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  • DOI: https://doi.org/10.1007/s11814-018-0164-z

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