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Removal of Zn (II) by complexation-ultrafiltration using rotating disk membrane and the shear stability of PAA-Zn complex

  • Separation Technology, Thermodynamics
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Abstract

Polyacrylic acid sodium (PAAS) was applied to remove Zn (II) from aqueous solutions by complexation-ultrafiltration using a rotating disk membrane module. As important factors, solution pH and the mass ratio of polymer to metal ions (P/M) on the rejection of Zn (II) were investigated, and the rejection could reach to 95.3% at pH=7, P/M=25 and 500 rpm. In addition, a partition model was proposed to reveal instability mechanism of the PAA-Zn complex in the shear field for the first time. The critical rotating speeds at which PAA-Zn complexes begin to dissociate were 1,460, 1,390, 1,280 rpm at pH 7.0, 6.0, 5.0, respectively. The corresponding critical shear rates (γc), the smallest shear rates at which PAA-Zn complex begins to dissociate, were 1.58×105, 1.45×105 and 1.25×105 s-1 at pH 7.0, 6.0, 5.0, respectively. In addition, the relationship between the critical radii and the critical rotating speed was obtained.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China

    Shuyun Tang & Yunren Qiu

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  1. Shuyun Tang
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  2. Yunren Qiu
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Correspondence to Yunren Qiu.

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Tang, S., Qiu, Y. Removal of Zn (II) by complexation-ultrafiltration using rotating disk membrane and the shear stability of PAA-Zn complex. Korean J. Chem. Eng. 35, 2078–2085 (2018). https://doi.org/10.1007/s11814-018-0105-x

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  • DOI: https://doi.org/10.1007/s11814-018-0105-x

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