Abstract
In view of the scale up of a batch reactor for super absorbent polymer (SAP), a dynamic mathematical model of a commercial scale batch reactor was developed with mass balance, energy balance, and complex polymerization kinetics. The kinetic parameters of the polymerization were estimated on the basis of the established mathematical model and reference data. Simulation results were validated with less than 10% marginal error compared with reference data. A case study was executed in terms of dynamic simulation for eight different initial concentrations of initiator and monomer to analyze the influence of initial concentration and predict the operation condition for desired product. The results were compared with various reference data, and good agreement was achieved. From the results, we argue that the methodology and results from this study can be used for the scale up of a polymerization batch reactor from the early stage of design.
Similar content being viewed by others
References
S. Francis, M. Kumar and L. Varshney, Radiat. Phys. Chem., 69, 481 (2014).
S. C. Chang, J. S. Yoo, J. W. Woo and J. S. Choi, Korean J. Chem. Eng., 16, 581 (1999).
R. E. Sojka and J. A. Entry, Environ. Pollut., 108, 405 (2000).
J. Z. Mohammad and K. Kabiri, Iran. Polym. J., 17, 451 (2008).
M. Wisniewska, S. Chibowski and T. Urban, J. Ind. Eng. Chem., 21, 925 (2015).
G. Sodeifian, R. Daroughegi and J. Aalaie, Korean J. Chem. Eng., 32, 2484 (2015).
D. Chamovsk, M. Cvetkovska and T. Grchev, Croat. Chem. Acta, 81, 461 (2008).
A. Pourjavadi and G. R. Mahdavinia, Turk. J. Chem., 30, 595 (2006).
A. A. Oladipo, Synthesis and characterization of modified chitosanbased novel superabsorbent hydrogel: swelling and dye adsorption behavior, Master’s Thesis EMU (2011).
M. Sadeghi and H. Hosseinzadeh, Turk. J. Chem., 32, 375 (2008).
R. A. Scott and N. A. Peppas, AIChE J., 43, 135 (1996).
T. Ishige and A. E. Hamielec, J. Appl. Polym. Sci., 17, 1479 (1973).
A. Giz, H. C. Giz, A. Alb, J. L. Brousseau and W. F. Reed, Macromolecules, 34, 1180 (2001).
D. Hunkeler, Macromolecules, 24, 2160 (1991).
C. Preusser, A. Chovancova, I. Lacik and R. A. Hutchinson, Macromol. React. Eng., 10, 490 (2016).
Process Systems Enterprise Co., https://doi.org/www.psenterprise.com (2017).
N. D. Vo, M. Y. Jung, D. H. Oh, J. S. Park, I. Moon and M. Oh, Combust. Flame., 189, 12 (2018).
S. H. Kim, B. W. Nyande, H. S. Kim, J. S. Park, W. J. Lee and M. Oh, J. Hazard. Mater., 308, 120 (2016).
K. Venkatarao and M. Santappa, J. Polym. Sci., 8, 1785 (1970).
N. Y. Abu-Thabit, World J. Chem. Education, 5, 94 (2017).
A. Echtermeyer, Y. Amar, J. Zakrzewski and A. Lapkin, Beilstein. J. Org. Chem., 13, 150 (2017).
H. R. Lin, Eur. Polym. J., 37, 1507 (2001).
I. Rintoul and C. Wandrey, Lat. Am. Appl. Res., 40, 365 (2010).
S. C. Kang, Y. J. Choi, H. Z. Kim, J. B. Kyong and D. K. Kim, Macromol. Res., 12, 107 (2004).
P. Pladis, O. Kotrotsiou, C. Gkementzoglou and C. Kiparissides, A Comprehensive Kinetic Investigation of the Inverse Suspension Copolymerization of Acrylamide: Theoretical and Experimental Studies, 2015 10th Int. Conf. Panhellenic Scientific Conference in Chemical Engineering (2015).
Z. Abdollahi and V. G. Gomes, Synthesis and characterization of polyacrylamide with controlled molar weight, Chemeca 2011: Engineering a Better World (2011).
J. Xu, W. P. Zhao, C. X. Wang and Y. M. Wu, Express. Polym. Lett., 4, 275 (2010).
Sigma-aldrich Co., https://doi.org/www.sigmaaldrich.com/catalog/product/aldrich/767379?lang=ko®ion=KR&cm_sp=Insite-_-prodRec-Cold_xviews-_-prodRecCold10-1 (2018).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Lee, G.H., Vo, N.D., Jeon, R.Y. et al. Modeling and simulation for acrylamide polymerization of super absorbent polymer. Korean J. Chem. Eng. 35, 1791–1799 (2018). https://doi.org/10.1007/s11814-018-0093-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-018-0093-x