Skip to main content
SpringerLink
Log in

Gd3+ doped Fe3O4 nanoparticles with proper magnetic and supercapacitive characteristics: A novel synthesis platform and characterization

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

A novel electrochemical procedure was developed for the facile preparation of Gd-doped iron oxide nanoparticles (GdIO-NPs). A simple galvanostatic deposition (i=10 mA cm-2) was done in an additive-free aqueous solution containing FeCl2·4H2O, Fe(NO3)3·9H2O and GdCl3·6H2O. The XRD, FE-SEM, EDS and TEM characterizations showed that the product is composed of 15% GdIO-NPs with 10 nm in size. VSM analysis proved that the GdIO-NPs are superparamagnetic. The cyclic voltammetry and charge-discharge tests showed that the prepared GdIO-NPs are capable to deliver specific capacity as high as 190.1 F g-1 at 0.5A g-1 and capacity retention of 95.1% after 2000 cycling. Based on the results, it was concluded that the developed electrochemical strategy acts as an efficient procedure for the preparation of lanthanide doped MNPs with proper magnetic and supercapacitive characters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Ulbrich, K. Hola, V. Subr, A. Bakandritsos, J. Tucek and R. Zboril, Chem. Rev., 116, 5338 (2016).

    Article  CAS  PubMed  Google Scholar 

  2. M. Aghazadeh, R. Ahmadi, D. Gharailou, M. R. Ganjali and P. Norouzi, J. Mater. Sci.: Mater. Electron., 27, 8623 (2016).

    CAS  Google Scholar 

  3. M. Aghazadeh, J. Appl. Electrochem., 42, 89 (2012).

    Article  CAS  Google Scholar 

  4. M. Aghazadeh, M. Hosseinifard, B. Sabour and S. Dalvand, Appl. Surf. Sci., 287, 187 (2013).

    Article  CAS  Google Scholar 

  5. N. Venugopal, W. S. Kim and T. Yu, Korean J. Chem. Eng., 33, 1500 (2016).

    Article  CAS  Google Scholar 

  6. M. G. Jeong, K. Zhuo, S. Cherevko and C. H. Chung, Korean J. Chem. Eng., 29, 1802 (2012).

    Article  CAS  Google Scholar 

  7. M. Aghazadeh and M. R. Ganjali, Ceram. Int., 44, 520 (2018).

    Article  CAS  Google Scholar 

  8. M. Aghazadeh, J. Mater. Sci.: Mater. Electron., 28, 3108 (2017).

    CAS  Google Scholar 

  9. A. Barani, M. Aghazadeh, M. R. Ganjali, B. Sabour, A. A. M. Barmi and S. Dalvand, Mater. Sci. Semiconduct. Process., 23, 85 (2014).

    Article  CAS  Google Scholar 

  10. M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 8144 (2017).

    CAS  Google Scholar 

  11. N. Madhukar Shinde, A. D. Jagadale, V. S. Kumbhar, T. R. Rana, J. H. Kim and C. D. Lokhande, Korean J. Chem. Eng., 32, 974 (2015).

    Article  CAS  Google Scholar 

  12. R. Poonguzhali, N. Shanmugam, R. Gobi, A. Senthilkumar, G. Viruthagiri and N. Kannadasan, J. Power Sources., 293, 790 (2015).

    Article  CAS  Google Scholar 

  13. M. Aghazadeh, A. Bahrami-Samani, D. Gharailou, M. Ghannadi Maragheh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 27, 11192 (2016).

    CAS  Google Scholar 

  14. M. Aghazadeh, M. R. Ganjali and P. Norouzi, J. Mater. Sci.: Mater. Electron., 27, 7707 (2016).

    CAS  Google Scholar 

  15. J. Tizfahm, M. Aghazadeh, M. G. Maragheh, M. R. Ganjali and P. Norouzi, Mater. Lett., 167, 153 (2016).

    Article  CAS  Google Scholar 

  16. X. Huang, M. Kim, H. Suh and I. Kim, Korean J. Chem. Eng., 33, 2228 (2016).

    Article  CAS  Google Scholar 

  17. M. Aghazadeh, M. Asadi, M. G. Maragheh, M. R. Ganjali and P. Norouzi, Appl. Surf. Sci., 364, 726 (2016).

    Article  CAS  Google Scholar 

  18. M. Aghazadeh, M. G. Maragheh, M. R. Ganjali, P. Norouzi and F. Faridbod, Appl. Surf. Sci., 364, 141 (2016).

    Article  CAS  Google Scholar 

  19. M. Aghazadeh, M. R. Ganjali and P. Noruzi, Thin Solid Films, 634, 24 (2017).

    Article  CAS  Google Scholar 

  20. E. M. Jin, H. J. Lee, H. B. Jun and S. Mun Jeong, Korean J. Chem. Eng., 34, 891 (2017).

    Google Scholar 

  21. M. Aghazadeh, A. A. Malek Barmi, D. Gharailou, M. H. Peyrovi, B. Sabour and F. Najafi, Appl. Surf. Sci., 283, 871 (2013).

    Article  CAS  Google Scholar 

  22. G. H. Jeong, H. M. Lee, H. Lee, C. K. Kim, Y. Piao, J. H. Lee, J. H. Kim and S. W. Kim, RSC Adv., 4, 51619 (2014).

    Article  CAS  Google Scholar 

  23. M. Aghazadeh and S. Dalvand, J. Electrochem. Soc., 161, D18 (2014).

    Article  CAS  Google Scholar 

  24. M. Aghazadeh, S. Dalvand and M. Hosseinifard, Ceram. Int., 40, 3485 (2014).

    Article  CAS  Google Scholar 

  25. M. Aghazadeh, H. Mohammad Shiri and A. A. Malek Barmi, Appl. Surf. Sci., 273, 237 (2013).

    Article  CAS  Google Scholar 

  26. M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 11406 (2017).

    CAS  Google Scholar 

  27. J. Talat Mehrabad, M. Aghazadeh, M. Ghannadi Maragheh and M. R. Ganjali, Mater. Lett., 184, 223 (2016).

    Article  CAS  Google Scholar 

  28. M. Aghazadeh, A. Rashidi and M. R. Ganjali, Electronic. Mater. Lett., 14, 37 (2018).

    Article  CAS  Google Scholar 

  29. J. Gou, S. Xie, Y. Liu and C. Liu, Electrochim. Acta, 210, 915 (2016).

    Article  CAS  Google Scholar 

  30. J. Tizfahm, B. Safibonab, M. Aghazadeh, A. Majdabadi, B. Sabour and S. Dalvand, Colloids Surf. A, 443, 544 (2014).

    Article  CAS  Google Scholar 

  31. M. Aghazadeh, M. Ghaemi, A. N. Golikand and A. Ahmadi, Mater. Lett., 65, 2545 (2011).

    Article  CAS  Google Scholar 

  32. M. Aghazadeh, M. Ghaemi, B. Sabour and S. Dalvand, J. Solid State Electrochem., 18, 1569 (2014).

    Article  CAS  Google Scholar 

  33. M. Aghazadeh, B. Sabour, M. R. Ganjali and S. Dalvand, Appl. Surf. Sci., 313, 581 (2014).

    Article  CAS  Google Scholar 

  34. A. A. Yadav, J. Mater. Sci.: Mater. Electron., 27, 12876 (2016).

    CAS  Google Scholar 

  35. M. Aghazadeh, I. Karimzadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 18121 (2017).

    CAS  Google Scholar 

  36. M. Zhang, J. Sha, X. Miao, E. Liu, C. Shi, J. Li, C. He, Q. Li and N. Zhao, J. Alloys Compd., 696, 956 (2017).

    Article  CAS  Google Scholar 

  37. E. Mitchell, R. K. Gupt, K. Mensah-Darkw, D. Kumar, K. Ramasamy, B. K. Gupta and P. Kahol, New J. Chem., 38, 4344 (2014).

    Article  CAS  Google Scholar 

  38. V. D. Nithya and N. Sabari Arul, J. Power Source, 327, 297 (2016).

    Article  CAS  Google Scholar 

  39. L. Wang, H. Ji, S. Wang, L. Kong, X. Jiang and G. Yang, Nanoscale, 5, 3793 (2013).

    Article  CAS  PubMed  Google Scholar 

  40. M. Aghazadeh, I. Karimzadeh and M. R. Ganjali, Mater. Lett., 209, 450 (2017).

    Article  CAS  Google Scholar 

  41. V. D. Nithya and N. Sabari Arul, J. Mater. Chem. A., 4, 10767 (2016).

    Article  CAS  Google Scholar 

  42. Z. Zhou, W. Xie, S. Li, X. Jiang, D. He, S. Peng and F. Ma, J. Solid State Electrochem., 19, 1211 (2015).

    Article  CAS  Google Scholar 

  43. Y. Yang, J. Li, D. Chen and J. Zhao, ACS Appl. Mater. Interfaces, 8, 26730 (2016).

    Article  CAS  PubMed  Google Scholar 

  44. S. Chen, R. Zhou, Y. Chen, Y. Fu, P. Li, Y. Song and L. Wang, J. Nanopart. Res., 19, 127 (2017).

    Article  CAS  Google Scholar 

  45. Y. Z. Wu, M. Chen, X. H. Yan, J. Ren, Y. Dai, J. J. Wang, J. M. Pan, Y. P. Wang and X. N. Cheng, Mater. Lett., 198, 114 (2017).

    Article  CAS  Google Scholar 

  46. H. Fan, R. Niu, J. Duan, W. Liu and W. Shen, ACS Appl. Mater. Interfaces, 8, 19475 (2016).

    Article  CAS  PubMed  Google Scholar 

  47. X. Yang, J. Kan, F. Zhang, M. Zhu and Z. Li, J. Inorg. Org. Polym. Mater., 27, 542 (2017).

    Article  CAS  Google Scholar 

  48. X. Tang, R. Jia, T. Zhai and H. Xia, ACS Appl. Mater. Interfaces, 7, 27518 (2015).

    Article  CAS  PubMed  Google Scholar 

  49. T. Xia, X. Xu, J. Wang, C. Xu, F. Meng, Z. Shi, J. Lian and J. M. Bassat, Electrochim. Acta, 160, 114 (2015).

    Article  CAS  Google Scholar 

  50. W. M. Zhang, X. L. Wu, J. S. Hu, Y. G. Guo and L. J. Wan, Adv. Funct. Mater., 18, 3941 (2008).

    Article  CAS  Google Scholar 

  51. C. R. De Silva, S. Smith, I. Shim, J. Pyun, T. Gutu, J. Jiao and Z. Zheng, J. Am. Chem. Soc., 131, 6336 (2009).

    Article  CAS  PubMed  Google Scholar 

  52. J. C. Park, S. Yeo, M. Kim, G. T. Lee and J. H. Seo, Mater. Lett., 181, 272 (2016).

    Article  CAS  Google Scholar 

  53. H. Zhang, V. Malik, S. Mallapragada and M. Akinc, J. Magn. Magn. Mater., 423, 386 (2017).

    Article  CAS  Google Scholar 

  54. F. J. Douglas, D. A. MacLaren, N. Maclean, I. Andreu, F. J. Kettles and F. Tuna, RSC Adv., 6, 74500 (2016).

    Article  CAS  Google Scholar 

  55. I. Karimzadeh, M. Aghazadeh, M. R. Ganjali, P. Norouzi, T. Doroudi and P. H. Kolivand, Mater. Lett., 189, 290 (2017).

    Article  CAS  Google Scholar 

  56. I. Karimzadeh, M. Aghazadeh, M. R. Ganjali, P. Norouzi, S. Shirvani-Arani, T. Doroudi, P. H. Kolivand, S. A. Marashi and D. Gharailoud, Mater. Lett., 179, 5 (2016).

    Article  CAS  Google Scholar 

  57. M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 29, 4981 (2018).

    CAS  Google Scholar 

  58. I. Karimzadeh, M. Aghazadeh, M. R. Ganjali and T. Dourudi, Curr. Nanosci., 13, 167 (2017).

    Article  CAS  Google Scholar 

  59. I. Karimzadeh, H. Rezagholipour Dizaji and M. Aghazadeh, Mater. Res. Express, 3, 095022 (2016).

    Article  CAS  Google Scholar 

  60. M. Aghazadeh and M. R. Ganjali, J. Mater. Sci., 53, 295 (2018).

    Article  CAS  Google Scholar 

  61. Z. Bakhtiary, A. A. Saei, M. J. Hajipour, M. Raoufi, O. Vermesh and M. Mahmoudi, Nanomed., 12, 287 (2016).

    Article  CAS  Google Scholar 

  62. K. Ulbrich, K. Hola, V. Subr, A. Bakandritsos, J. Tucek and R. Zboril, Chem. Rev., 116, 5338 (2016).

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Materials and Nuclear Research School, NSTRI, P. O. Box 14395-834, Tehran, Iran

    Mustafa Aghazadeh & Mohammad Ghannadi Maragheh

  2. Department of Physics, Bonab Branch, Islamic Azad University, Bonab, Iran

    Isa Karimzadeh

  3. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran

    Mohammad Reza Ganjali

  4. Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

    Mohammad Reza Ganjali

Authors
  1. Mustafa Aghazadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Isa Karimzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mohammad Ghannadi Maragheh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mohammad Reza Ganjali
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mustafa Aghazadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aghazadeh, M., Karimzadeh, I., Maragheh, M.G. et al. Gd3+ doped Fe3O4 nanoparticles with proper magnetic and supercapacitive characteristics: A novel synthesis platform and characterization. Korean J. Chem. Eng. 35, 1341–1347 (2018). https://doi.org/10.1007/s11814-018-0027-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-018-0027-7

Keywords

Search

Navigation