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Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde

  • Polymer, Industrial Chemistry
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Abstract

We used a water-in-oil emulsification method to prepare particulate CO2 absorbents from branched poly(ethyleneimine) (PEI), utilizing 13C nuclear magnetic resonance spectroscopy to determine the amount of free PEI NH2 groups and thus calculate the required cross-linker amount. The functional groups and reactivity of branched PEI particles were characterized by Fourier transform infrared spectroscopy, and their CO2 absorption capacity was determined by thermogravimetric analysis. Dynamic light scattering measurements showed that the synthesized particles exhibited sizes of 0.2-2 μm and high surface areas, which resulted in high CO2 absorption capacities of up to 2.18 mmol CO2 per gram sorbent at 75 °C.

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References

  1. J. Wang, H. Chen, H. Zhou, X. Liu, W. Qiao, D. Long and L. Ling, J. Environ. Sci., 25, 124 (2013).

    Article  CAS  Google Scholar 

  2. H. Yang, Z. Xu, M. Fan, R. Gupta, R.B. Slimane, A. E. Bland and I. Wright, J. Environ. Sci., 20, 14 (2008).

    Article  CAS  Google Scholar 

  3. Y. Lin, Q. Yan, C. Kong and L. Chen, Sci. Rep., 3, 1859 (2013).

    Article  Google Scholar 

  4. S. Satyapal, T. Filburn, J. Trela and J. Strange, Energy Fuels, 15, 250 (2001).

    Article  CAS  Google Scholar 

  5. J. Liu, Y. Liu, Z. Wu, X. Chen, H. Wang and X. Weng, J. Colloid Interface Sci., 386, 392 (2012).

    Article  CAS  Google Scholar 

  6. E. P. Dilllon, C.A. Crouse and A.R. Barron, ACS Nano, 2, 156 (2008).

    Article  Google Scholar 

  7. B. Arstad, H. Fjellvåg, K.O. Kongshaug, O. Swang and R. Blom, Adsorption, 14, 755 (2008).

    Article  CAS  Google Scholar 

  8. R. Sanz, G. Calleja, A. Arencibia and E. S. Sanz-Pérez, Appl. Surf. Sci., 256, 5323 (2010).

    Article  CAS  Google Scholar 

  9. W.-J. Son, J.-S. Choi and W.-S. Ahn, Micropor. Mesopor. Mater., 113, 31 (2008).

    Article  CAS  Google Scholar 

  10. T. Zhu, S. Yang, D. K. Choi and K. H. Row, Korean J. Chem. Eng., 27, 1910 (2010).

    Article  CAS  Google Scholar 

  11. Y. Liu, Q. Ye, M. Shen, J. Shi, J. Chen, H. Pan and Y. Shi, Environ. Sci. Technol., 45, 5710 (2011).

    Article  CAS  Google Scholar 

  12. P. Kumar, S. Kim, J. Ida and V.V. Guliants, Ind. Eng. Chem. Res., 47, 201 (2008).

    Article  CAS  Google Scholar 

  13. J. C. Hicks, J. H. Drese, D. J. Fauth, M. L. Gray, G. Qi and C.W. Jones, J. Am. Chem. Soc., 130, 2902 (2008).

    Article  CAS  Google Scholar 

  14. S. Yang, L. Zhan, X. Xu, Y. Wang, L. Ling and X. Feng, Adv. Mater., 25, 2130 (2013).

    Article  CAS  Google Scholar 

  15. M.-S. Lee, S.-Y. Lee and S.-J. Park, Int. J. Hydrogen Energy, 40, 3415 (2015).

    Article  CAS  Google Scholar 

  16. H. Liu, Z. Shen, S.-E. Stiriba, Y. Chen, W. Zhang and L. Wei, J. Polym. Sci. Part A: Polym. Chem., 44, 4165 (2006).

    Article  CAS  Google Scholar 

  17. M.R. Park, K.O. Han, I.K. Han, M.H. Cho, J.W. Nah, Y. J. Choi and C. S. Cho, J. Control Release., 105, 367 (2005).

    Article  CAS  Google Scholar 

  18. H. Petersen, P. M. Fechner, D. Ficher and T. Kissel, Macromolecules, 35, 6867 (2002).

    Article  CAS  Google Scholar 

  19. L.Y. Qiu and Y. H. Bae, Biomaterials, 28, 4132 (2007).

    Article  CAS  Google Scholar 

  20. H. Pertersen, T. Merdan, K. Kunath, D. Fucher and T. Kissel, Bioconjugate Chemistry, 13, 812 (2002).

    Article  Google Scholar 

  21. H.R. Allcock and P. E. Austin, Macromolecules, 41, 1616 (1981).

    Article  Google Scholar 

  22. M. Kramer, J. F. Stumbe, G. Grimm, B. Kaufmann, U. Kruger, M. Weber and R. Haag, Chembiochem., 5, 1081 (2004).

    Article  Google Scholar 

  23. K. Kunath, J. Controlled Release, 89, 113 (2003).

    Article  CAS  Google Scholar 

  24. B. Xia, C. Dong, Y. Lu, M. Rong, Y.-z. Lv and J. Shi, Thin Solid Films, 520, 1120 (2011).

    Article  CAS  Google Scholar 

  25. M.K. Bhunia, S. K. Das, P. Pachfule, R. Banerjee and A. Bhaumik, Dalton Trans., 41, 1304 (2012).

    Article  CAS  Google Scholar 

  26. A.V. Pestov, A.V. Mehaev, M. I. Kodess, M. A. Ezhikova, Y.A. Azarova and S.Y. Bratskaya, Carbohydr. Polym., 138, 252 (2016).

    Article  CAS  Google Scholar 

  27. M.D. Rubianes and M.C. Strumia, Electroanalysis, 22, 1200 (2010).

    Article  CAS  Google Scholar 

  28. H.V. Adikane and G. J. Iyer, Appl. Biochem. Biotechnol., 169, 1026 (2013).

    Article  CAS  Google Scholar 

  29. A. Wnorowski and V.A. Yaylayan, J. Agricult. Food Chemistry, 51, 6537 (2003).

    Article  CAS  Google Scholar 

  30. M.M.M. Elnashar, M.A. Yassin and T. Kahil, J. Appl. Polym. Sci., 109, 4105 (2008).

    Article  CAS  Google Scholar 

  31. F. Wang, P. Liu, T. Nie, H. Wei and Z. Cui, Int. J. Mol. Sci., 14, 17 (2012).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Korea Institute of Industrial Technology, 89 Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan-si, Chungcheongnam-do, 31056, Korea

    Ki-Seob Hwang & Jun-Young Lee

  2. Department of Chemical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemoon-gu, Seoul, 03722, Korea

    Hee-Young Park & Jung-Hyun Kim

Authors
  1. Ki-Seob Hwang
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  2. Hee-Young Park
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  3. Jung-Hyun Kim
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  4. Jun-Young Lee
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Correspondence to Jun-Young Lee.

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Hwang, KS., Park, HY., Kim, JH. et al. Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde. Korean J. Chem. Eng. 35, 798–804 (2018). https://doi.org/10.1007/s11814-017-0330-8

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  • DOI: https://doi.org/10.1007/s11814-017-0330-8

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