Abstract
The objective of this investigation was to determine whether hydroquinone (HQ) can form clathrate compounds with two sulfides (hydrogen sulfide (H2S) and carbonyl sulfide (COS)) at their diluted concentrations. Hydroquinone samples obtained at ambient temperature and at two pressures (40 and 80 bar) for binary gas mixtures consisting of H2S-N2 and COS-N2, were analyzed using solid-state 13C NMR and Raman spectroscopy. An elemental analyzer was also used to obtain quantitative information regarding the kind and amount of gas captured in the solid samples. Results show that H2S can be concentrated within the solid clathrate from H2S-containing gas, while COS is little captured after reaction with the COS-containing gas. This suggests that the HQ clathrate can be used to remove H2S, and that selective separation can be achieved when two sulfides of H2S and COS coexist. On the basis of the calculated cage occupancies of the gas components in the solid clathrate, the enclathration preference of the gas components used in this research was found to be the order of H2S>N2>COS.
Similar content being viewed by others
References
J.M. Beér, Prog. Energy Combust., 26, 301 (2000).
S. S. Chauk, R. Agnihotri, R. A. Jadhav, S. K. Misro and L.-S. Fan, AIChE J., 46, 1157 (2000).
H. An, W. M. Yang, S. K. Chou and K. J. Chua, Appl. Energy, 99, 363 (2012).
J.E.T. Liu, W.M. Yang, J. Li, J. Gong and Y. Deng, Energy Convers. Manage., 117, 410 (2016).
H. Liu, J.E.X. Ma and C. Xie, Dry Technol., 34, 1397 (2016).
A. Huhtala and P. Remes, Energy Policy, 105, 320 (2017).
V. Tola and A. Pettinau, Appl. Energy, 113, 1461 (2014).
S. L. Matson, C. S. Herrick and W. J. Ward, Ind. Eng. Chem. Process Des. Dev., 16, 370 (1977).
S. F. Watts, Atmos. Environ., 34, 761 (2000).
I. Rosso, C. Galletti, M. Bizzi, G. Saracco and V. Specchia, Ind. Eng. Chem. Res., 42, 1688 (2003).
R. Gupta, S. K. Gangwal and S. C. Jain, Energy Fuel, 6, 21 (1992).
K. Miura, K. Mae, T. Inoue, T. Yoshimi, H. Nakagawa and K. Hashimoto, Ind. Eng. Chem. Res., 31, 415 (1992).
G. Yan, H. Weng, J. Yang, W. Bao, Y. Gao and Y. Yin, Korean J. Chem. Eng., 33, 2359 (2016).
Y.C. Park, J.-S. Lee, J.-H. Moon, B.-M. Min, D.-M. Shim and H.-J. Sung, Korean J. Chem. Eng., 34, 921 (2017).
K. Sakanishi, Z. Wu, A. Matsumura, I. Saito, T. Hanaoka, T. Minowa, M. Tada and T. Iwasaki, Catal. Today, 104, 94 (2005).
J. Dou, Y. Zhao, A. Tahmasebi and J. Yu, Korean J. Chem. Eng., 33, 2849 (2016).
E.D. Sloan and C. A. Koh, Clathrate Hydrates of Natural Gases, 3rd Ed.; CRC Press, Boca Raton, FL (2008).
S.-P. Kang and H. Lee, Environ. Sci. Technol., 34, 4397 (2000).
C.-F. Ma, G.-J. Chen, F. Wang, C.-Y. Sun and T.-M. Guo, Fluid Phase Equilib., 191, 41 (2001).
J. Seol, J.-W. Lee, W.-C. Shin, D.-Y. Koh, J. Lee and H. Lee, J. Phys. Chem. C, 114, 17960 (2010).
S.-P. Kang and J.-W. Lee, Ind. Eng. Chem. Res., 52, 303 (2013).
J.-W. Lee, Y. Lee, S. Takeya, T. Kawamura, Y. Yamamoto, Y.-J. Lee and J.-H. Yoon, J. Phys. Chem. B, 114, 3254 (2010).
J.-W. Lee, K. J. Choi, Y. Lee and J.-H. Yoon, Chem. Phys. Lett., 528, 34 (2012).
J.-W. Lee, S.-P. Kang and J.-H. Yoon, J. Phys. Chem. C, 118, 6059 (2014).
J.-W. Lee, S.-P. Kang and J.-H. Yoon, J. Phys. Chem. C, 118, 7705 (2014).
A. H. Mohammadi and D. Richon, J. Chem. Eng. Data, 54, 2338 (2009).
S. Liang and P. G. Kusalik, J. Phys. Chem. B, 114, 9563 (2010).
H. Mohammadi-Manesh, S. Alavi, T. K. Woo and B. Najafi, Phys. Chem. Chem. Phys., 13, 2367 (2011).
J. L. Atwood, J. E.D. Davies and D.D. MacNicol, Inclusion Compounds, Academic Press, Florida (1984).
J.-W. Lee, J. Poudel, M. Cha, S. J. Yoon and J.-H. Yoon, Energy Fuel, 30, 7604 (2016).
J.A. Ripmeester, Chem. Phys. Lett., 74, 536 (1980).
M. J. Kubinyi and G. Keresztury, Mikrochim. Acta, 14, 525 (1997).
J.-W. Lee and J.-H. Yoon, J. Phys. Chem. C, 115, 22647 (2011).
A. Anderson, S. Demoor and R. C. Hanson, Chem. Phys. Lett., 140, 471 (1987).
A.G. Maki, J. S. Wells and J.B. Burkholder, J. Mol. Spectrosc., 147, 173 (1991).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Lee, JW., Lee, S.H., Yoon, S.J. et al. Spectroscopic investigation, cage occupancy, and gas storage capacity of hydroquinone clathrates formed with H2S-N2 and COS-N2 binary gas mixtures. Korean J. Chem. Eng. 34, 2710–2714 (2017). https://doi.org/10.1007/s11814-017-0184-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-017-0184-0