Skip to main content
Log in

Silver nanoparticle loaded silica adsorbent for wastewater treatment

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Our aim was to prepare silver nanoparticle loaded silica adsorbent for the removal of pollutants and pathogens in wastewater. The pathogens were inactivated by silver nanoparticles loaded with silica by wet impregnation method. Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and X-ray Diffraction studies confirmed the silver nanoparticle loaded on silica. Inductively coupled plasma atomic emission spectroscopy showed 0.6 mg/g silver nanoparticle in the prepared adsorbent. The prepared adsorbent has potential against Escherichia coli and was described through Chick, Chick-Watson and Homs inactivation kinetic models. Five-hundred (500) ppm concentration of the prepared adsorbent showed complete inhibition with the shouldering or lag curve of inactivation and the k′ values of 0.019 min−1. After treatment, tannery, dairy and canteen effluents showed significant COD reduction with maximum adsorption capacity of 145, 142 and 69 mg/g visa versa. Regeneration of the spent adsorbent used alkali washing and reused up to three cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Jaishree and T. I. Khan, Int. J. Scientific Res. Publication, 4 (3), 1 (2014).

    Google Scholar 

  2. H. Ozgun, M. E. Ersahin, S. Erdem, B. Atay, S. Sayili, E. Eren, P. Hoshan, D. Atay, M. Altinbas, C. Kinaci and I. Koyuncu, Clean - Soil, Air, Water, 41(12), 1175 (2013).

    Article  CAS  Google Scholar 

  3. F. Rahmawati, T. Kusumaningsih and A. Hastuti, Toxicological Environ. Chem., 93 (8), 1602 (2011).

    Article  CAS  Google Scholar 

  4. M. H. El Rafie, T. I. Shaheen, A. A. Mohamed and A. Hebeish, Carbohydr Polym., 90, 915 (2012).

    Article  CAS  Google Scholar 

  5. M. Rai and C. Posten, Green Biosynthesis of Nanoparticles Mechanisms and Applications, CABI Publishers, UK (2013).

    Book  Google Scholar 

  6. F. Okafor, A. Janen, T. Kukhtareva, V. Edwards and M. Curley, Int. J. Environ. Res. Public Health, 10, 5221 (2013).

    Article  Google Scholar 

  7. Y. Lv, H. Liu, Z. Wang, S. Liu, L. Hao, Y. Sang, D. Liu, J. Wang and R. I. Boughton, J. Memb. Sci., 331, 50 (2009).

    Article  CAS  Google Scholar 

  8. J. Pal, M. K. Deb, D. K. Deshmukh and D. Verma, Appl. Water Sci., 3, 367 (2013).

    Article  CAS  Google Scholar 

  9. K. Vimala, Y. M. Mohan, K. Varaprasad, N. Narayana Reddy, S. Ravindra, N. Sudhakar Naidu and K. M. Raju, J. Biomater. Nanobiotechnol., 2, 55 (2011).

  10. T. Q. Tuan, N. V. Son, H. T. K. Dung, N. H. Luong, B. T. Thuy, N. T. V. Anh, N. D. Hoa and N. H. Hai, J. Hazard. Mater., 192, 1321 (2011).

    Article  Google Scholar 

  11. N. R. Jana, C. Earhart and J. Y. Ying, Chem. Mater., 19, 5074 (2007).

    Article  CAS  Google Scholar 

  12. F. Li, P. Du, W. Chen and S. Zhang, Anal. Chim. Acta., 585, 211 (2007).

    Article  CAS  Google Scholar 

  13. G. Compagnini, M. E. Fragala, L. D. DUrso, C. Spinella and O. Puglisi, J. Mater. Res., 16, 2934 (2001).

  14. D. V. Quang, P. B. Sara Wade, A. Hilonga, S. D. Park, J. K. Kim and H. T. Kim, Appl. Surf. Sci., 257, 4250 (2011).

    Article  CAS  Google Scholar 

  15. V. Thamilselvi and K. V. Radha, Dig. J. Nanomater Bios., 8, 1101 (2013).

    Google Scholar 

  16. H. Chick, J. Hygiene, 8, 92 (1908).

  17. D. Eaton, L. S. Clesceri, A. E. Greenberg and M. A. H. Franson,. American Public Health Association, 19th Ed. Washington (1995) DC.

    Google Scholar 

  18. S. Aber and M. Sheydaei, Clean - Soil, Air, Water, 40(1), 87 (2012).

    Article  CAS  Google Scholar 

  19. Y. P. Teoh, M. A. Khan and T. S. Y. Choong, Chem. Engg. J., 217, 248 (2013).

    Article  CAS  Google Scholar 

  20. A. B. Dos Santos, F. J. Cervantes and J. B. Van Lier, Bioresour. Technol., 98 (12), 2369 (2007).

  21. E. Sumesh, M. S. Bootharaju and T. Pradeep, J. Hazard. Mater., 189, 450 (2011).

    Article  CAS  Google Scholar 

  22. S. K. Das, M. M. R. Khan, T. Parandhaman, F. Laffir, A. K. Guha, G. Sekarana and A. B. Mandal, Nanoscale, 5, 5549 (2014).

    Article  Google Scholar 

  23. W. R. Li, X. B. Xie, Q. S. Shi, H. Y. Zeng, Y. S. OU-Yang and Y. B. Chen, Appl. Microbiol. Biotechnol., 85, 1115 (2010).

    Article  CAS  Google Scholar 

  24. P. Jain and T. Pradeep, Biotechnol. Bioeng., 90, 59 (2005).

    Article  CAS  Google Scholar 

  25. W. H. Jung, H. C. Koo, K. W. Kim, S. Shin, S. H. Kim and Y. H. Park, Appl. Environ. Microbiol., 74 (7), 2171 (2008).

    Article  CAS  Google Scholar 

  26. Y. J. Lee and S. H. Nam, J. Microbiol., 40, 119 (2002).

    CAS  Google Scholar 

  27. I. Sheet, H. Holail, Z. Olama, A. Kabbani and M. Hines, Int. J. Current Microbiol. Appl. Sci., 2 (4), 1 (2013).

    Google Scholar 

  28. S. B. Somani and N. W. Ingole, Int. J. Environ. Sci., 2, 1344 (2012).

    CAS  Google Scholar 

  29. L. T. Kist, C. Albrecht and E. L. Machado, Clean-soil, Air, Water, 36(9), 775 (2008).

    Article  CAS  Google Scholar 

  30. A. L. Jessen, ProQuest, Ann Arbor, USA (2006).

    Google Scholar 

  31. T. Calvete, E. C. Lima, N. F. Cardoso, S. L. P. Dias and E. S. Ribeir, Clean - Soil, Air, Water, 38, 521 (2010).

    Article  CAS  Google Scholar 

  32. L. W. Low, T. T. Teng, A. Ahmad, N. Morad and Y. S. Wong, Water Air Soil Pollution, 218, 293 (2011).

    Article  CAS  Google Scholar 

  33. D. Mohan, K. P. Singh and V. K. Singh, J. Hazard. Mater., 152 (3), 1045 (2008).

    Article  CAS  Google Scholar 

  34. A. A. Ahmad and B. H. Hameed, J. Hazard. Mater., 172, 1538 (2009).

    Article  CAS  Google Scholar 

  35. R. Liu, X. Shen, X. Yang, Q. Wang and F. Yang, J. Nanopart. Res., 15, 1679 (2013).

    Article  Google Scholar 

  36. L. Zheng, Z. Dang, X. Yi and H. Zhang, J. Hazard. Mater., 176, 650 (2010).

  37. M. H. El-Nass, S. Al-Zuhair and M. A. Ahaija, J. Hazard. Mater., 173, 1750 (2010).

    Google Scholar 

  38. D. Sivakumar, Global J. Environ. Sci. Manage., 1 (1), 27 (2015).

    CAS  Google Scholar 

  39. A. A. NurFatinah, N. Rajesh and M. Z. Masniroszaime, J. Eng. Sci. Technol., 1, 8 (2015).

    Google Scholar 

  40. J. M. Mendez-Conteras, J. Atenodoro, F. A. Champion, N. A. Vallejo-Cantu and A. Alvardo-Lassman, Water SA., 35 (4), 371 (2009).

    Google Scholar 

  41. S. M. Al-Hakami, A. B. Khalil, T. Laoui and M. Ali Atieh, Bioinorg Chem. Appl., 2013, 1 (2013).

  42. R. Ansari, A. Mohammad-khah and M. Nazmi, Current Chem. Lett., 2, 215 (2013).

    Article  CAS  Google Scholar 

  43. K. M. S. Surchi, Int. J. Chem., 3 (3), 103 (2011).

    Article  CAS  Google Scholar 

  44. H. E. Watson, J. Hygiene, 536, 536 (1908).

    Article  Google Scholar 

  45. L. W. Hom, Journal of the Sanitary Engineering Division, ASCE, 98, 183 (1972).

    Google Scholar 

  46. I. Langmuir, J. Am. Chem. Soc., 38 (11), 2221 (1916).

    Article  CAS  Google Scholar 

  47. H. M. F. Freundlich, J. Phys. Chem., 57, 385 (1906).

    CAS  Google Scholar 

  48. O. Redlich and D. L. Peterson, J. Phys. Chem., 63, 1024 (1959).

    Article  CAS  Google Scholar 

  49. R. Sips, J. Chem. Phys., 16, 490 (1948).

    Article  CAS  Google Scholar 

  50. A. S. Thajeel, Aqua. Sci. Technol., 1, 53 (2013).

    Google Scholar 

  51. S. Idris, J. Yisa, A. U. Itodo and K. A. Popoola, Resource and Environment, 2 (2), 51 (2012).

    Article  Google Scholar 

  52. A. H. Pakiari and Z. Jamshidi, J. Phys. Chem. A, 111 (20), 4391 (2007).

    Article  CAS  Google Scholar 

  53. F. X. Schmid, Biological Macromolecules:UV-visible Spectrophotometry, Macmillan Publishers Ltd., Nature Publishing Group, Germany (2001).

    Google Scholar 

  54. S. D. Solomon, M. Bahadory, A. V. Jeyarajasingam, S. A. Rutkowsky and C. Boritz, J. Chem. Ed., 84 (2), 322 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kuravappulam Vedhaiyan Radha.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Thamilselvi, V., Radha, K.V. Silver nanoparticle loaded silica adsorbent for wastewater treatment. Korean J. Chem. Eng. 34, 1801–1812 (2017). https://doi.org/10.1007/s11814-017-0075-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-017-0075-4

Keywords

Navigation