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Developing thin film heterogeneous ion exchange membrane modified by 2-acrylamido-2-methylpropanesulfonic acid hydrogel-co-super activated carbon nanoparticles coating layer

  • Materials (Organic, Inorganic, Electronic, Thin Films)
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Abstract

Highly selective cation exchange membranes were prepared by coating a thin 2-acrylamido-2-methylpropanesulfonic acid based hydrogel layer and super activated carbon nanoparticles-co-hydrogel layer on polyvinyl chloride based cation exchange membranes. FTIR analysis proved hydrogel formation on membrane surface successfully. Scanning electron microscopy images and swelling ratio measurement were used to study the effect of super activated carbon nanoparticles on properties of formed hydrogel. The surface morphology, surface hydrophilicity and roughness analysis were also used in membrane characterization. Membrane water content was increased by formation of modified layer on the membranes surface. Modified membranes showed a remarkable improvement in potential, permselectivity and transport number compared to pristine type. Membrane ionic flux and permeability were improved initially by using modifier layer on membrane surface, and then showed decreasing trend at high nanoparticles loading ratios in hydrogel layer. Modified membranes showed lower electrical resistance compared to unmodified membrane.

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References

  1. H. M. Hegab, Y. Wimalasiri, M. Ginic-Markovic and L. Zou, Desalination, 365, 99 (2015).

    Article  CAS  Google Scholar 

  2. L. A. Nezam, A. El-Din, A. El-Gendi, N. Ismail, K. A. Abed and A. I. Ahmed, J. Ind. Eng. Chem., 26, 259 (2015).

    Article  Google Scholar 

  3. L. Zoua, I. Vidalis, D. Steele, A. Michelmore, S. P. Low and J. Q. J. C. Verberk, J. Membr. Sci., 369, 420 (2011).

  4. J. Yin and B. Deng, J. Membr. Sci., 479, 256 (2015).

  5. H. Farrokhzad, T. Kikhavani, F. Monnaie, S. N. Ashrafizadeh, G. Koeckelberghs, T. Van Gerven and B. Vander Bruggen, J. Membr. Sci., 474, 167 (2015).

    Article  CAS  Google Scholar 

  6. X. Zuo, W. Shi, Z. Tian, S. Yu, S. Wang and J. He, Desalination, 311, 150 (2013).

    Article  CAS  Google Scholar 

  7. X. Zuo, S. Yu and W. Shi, Desalination, 290, 83 (2012).

    Article  CAS  Google Scholar 

  8. M. Reig, H. Farrokhzad, B. Vander Bruggen, O. Gibert and J. L. Cortina, Desalination, 375, 1 (2015).

    Article  CAS  Google Scholar 

  9. H. Farrokhzad, S. Darvishmanesh, G. Genduso, T. Van Gerven and B. Vander Bruggen, Electrochim. Acta., 158, 64 (2015).

  10. F. Q. Mir and A. Shukla, Desalination, 372, 1 (2015).

    Article  CAS  Google Scholar 

  11. A. H. Galama, N. A. Hoog and D. R. Yntema, Desalination, 380, 1 (2016).

    Article  CAS  Google Scholar 

  12. S. Mikhaylin, V. Nikonenko, N. Pismenskaya, G. Pourcelly, S. Choi, H. J. Kwon, J. Han and L. Bazinet, Desalination, 393, 102 (2016).

    Article  CAS  Google Scholar 

  13. S. M. Hosseini, A. R. Hamidi, A. R. Moghadassi, F. Parvizian and S. S. Madaeni, Korean J. Chem. Eng., 32 (9), 1827 (2015).

    Article  CAS  Google Scholar 

  14. S. Habibi, A. Nematollahzadeh and S. A. Mousavi, Chem. Eng. J., 267, 306 (2015).

    Article  CAS  Google Scholar 

  15. S. M. Hosseini, M. Nemati, F. Jeddi, E. Salehi, A. R. Khodabakhshi and S. S. Madaeni, Desalination, 359, 167 (2015).

    Article  CAS  Google Scholar 

  16. S. M. Hosseini, A. R. Hamidi, S. S. Madaeni and A. R. Moghadassi, Korean J. Chem. Eng., 32 (3), 429 (2015).

    Article  CAS  Google Scholar 

  17. M. Nemati, S. M. Hosseini, E. Bagheripour and S. S. Madaeni, Korean J. Chem. Eng., 33 (3), 1037 (2016).

    Article  CAS  Google Scholar 

  18. S. Yu, Z. Lü, Z. Chen, X. Liu, M. Liu and C. Gao, J. Membr. Sci., 371, 293 (2011).

    Article  CAS  Google Scholar 

  19. H. Z. Shafi, Z. Khan, R. Yang and K. Gleason, Desalination, 362, 93 (2015).

    Article  CAS  Google Scholar 

  20. H. Guo and M. Ulbricht, J. Membr. Sci., 349, 312 (2010).

    Article  CAS  Google Scholar 

  21. S. M. Hosseini, S. S. Madaeni, A. R. Khodabakhshi and A. Zen-dehnam, J. Membr. Sci., 365, 438 (2010).

    Article  CAS  Google Scholar 

  22. P. Daraei, S. S. Madaeni, N. Ghaemi, H. Ahmadi Monfared and M. A. Khadivi, Sep. Purif. Technol., 104, 32 (2013).

    Article  CAS  Google Scholar 

  23. Y. J. Choi, J. H. Song, M. S. Kang and B. K. Seo, Electrochim. Acta., 180, 71 (2015).

    Article  CAS  Google Scholar 

  24. M. Moochani, A. R. Moghadassi, S. M. Hosseini, E. Bagheripour and F. Parvizian, Korean J. Chem. Eng., 33 (9), 2674 (2016).

    Article  CAS  Google Scholar 

  25. Y. J. Choi, M. S. Kang, S. H. Kim, J. Cho and S. H Moon, J. Membr. Sci., 223, 201 (2003).

    Article  CAS  Google Scholar 

  26. N. Peng, Y. Wang, Q. Ye, L. Liang, Y. An, Q. Li and C. Chang, Carbohydr. Polym., 137, 59 (2016).

    Article  CAS  Google Scholar 

  27. Z. Du, Y. Hu, X. Gu, M. Hu and C. Wang, Colloid Surf., A. Physicochem. Eng. Asp., 489, 1 (2016).

    Article  CAS  Google Scholar 

  28. Y. Ma, T. Bai and F. Wang, Mater. Sci. Eng. C., 59, 948 (2016).

    Article  CAS  Google Scholar 

  29. S. M. Alshehri, A. Aldalbahi, A. B. Al-hajji, A. A. Chaudhary, M. Panhuis, N. Alhokbany and T. Ahamad, Carbohydr. Polym., 138, 229 (2016).

    Article  CAS  Google Scholar 

  30. M. R. Guilherme, A. V. Reis, A. T. Paulino, A. R. Fajardo, E. C. Muniz and E. B. Tambourgi, J. Appl. Polym. Sci., 105, 2903 (2007).

    Article  CAS  Google Scholar 

  31. C. Zhang, Z. Geng, M. Cai, J. Zhang, X. Liu, H. Xin and J. Ma, Int. J. Hydrogen Energy, 38, 9243 (2013).

    Article  CAS  Google Scholar 

  32. B. H. Kim, C. H. Kim and D. G. Lee, J. Electro. Chem., 760, 64 (2016).

    Article  CAS  Google Scholar 

  33. L. Zhou, Y. Zhou and Y. Sun, Int. J. Hydrogen Energy, 29, 475 (2004).

    Article  CAS  Google Scholar 

  34. R. Mukherjee and S. De, Sep. Purif. Technol., 157, 229 (2016).

    Article  CAS  Google Scholar 

  35. G. Skouteris, D. Saroj, P. Melidis, F. I. Hai and S. Ouki, Bioresour. Technol., 185, 399 (2015).

    Article  CAS  Google Scholar 

  36. F. Bonvin, L. Jost, L. Randin, E. Bonvin and T. Kohn, Water Res., 90, 90 (2016).

    Article  CAS  Google Scholar 

  37. A. Georgi, A. Schierz, K. Mackenzie and F. Dieter Kopinke, J. Contam. Hydrol., 179, 76 (2015).

    Article  CAS  Google Scholar 

  38. H. M. Hegab, Y. Wimalasiri, M. Ginic-Markovic and L. Zou, Desalination, 365, 99 (2015).

    Article  CAS  Google Scholar 

  39. T. Sata, Ion Exchange Membranes: Preparation, Characterization, Modification and Application, The Royal Society of Chemistry, Cambridge Publications, United Kingdom (2004).

    Google Scholar 

  40. R. K. Nagarale, G. S. Gohil, V. K. Shahi and R. Rangarajan, Colloid Surf., A. Physicochem. Eng. Asp., 251, 133 (2004).

    Article  CAS  Google Scholar 

  41. X. Li, Z. Wang, H. Lu, C. Zhao, H. Na and C. Zhao, J. Membr. Sci., 254, 147 (2005).

    Article  CAS  Google Scholar 

  42. Y. Tanaka, Ion Exchange Membranes: Fundamentals and Applications, Elsevier, Netherlands, 12 (2007).

    Google Scholar 

  43. R. K. Nagarale, V. K. Shahi, S. K. Thampy and R. Rangarajan, React. Funct. Polym., 61, 131 (2004).

    Article  CAS  Google Scholar 

  44. G. S. Gohil, V. V. Binsu and V. K. Shahi, J. Membr. Sci., 280, 210 (2006).

    Article  CAS  Google Scholar 

  45. J. Kerres, W. Cui, R. Disson and W. Neubrand, J. Membr. Sci., 139, 211 (1998).

    Article  CAS  Google Scholar 

  46. V. K. Shahi, S. K. Thampy and R. Rangarajan, J. Membr. Sci., 158, 77 (1999).

    Article  CAS  Google Scholar 

  47. R. K. Nagarale, V. K. Shahi and R. Rangarajan, J. Membr. Sci., 248, 37 (2005).

    Article  CAS  Google Scholar 

  48. S. M. Hosseini, A. Gholami, P. Koranian, M. Nemati, S. S. Madaeni and A. R. Moghadassi, J. Taiwan. Inst. Chem. Eng., 45, 1241 (2014).

  49. S. M. Hosseini, S. S. Madaeni, A. R. Heidari and A. R. Khodabakhshi, Desalination, 285, 253 (2012).

    Article  CAS  Google Scholar 

  50. N. Limparyoon, N. Seetapan and S. Kiatkamjornwong, Polym. Degrad. Stab., 96, 1054 (2011).

    Article  CAS  Google Scholar 

  51. A. Hebeish, M. Hashem, M. M. Abd El-Hady and S. Sharaf, Carbohydr. Polym., 92, 407 (2013).

    Article  CAS  Google Scholar 

  52. B. D. Mc Closkey, H. Bum Park, H. Ju, B. W. Rowe, D. J. Mille and B. D. Freeman, J. Membr. Sci., 413, 82 (2012).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak, 38156-8-8349, Iran

    Mahsa Nemati & Sayed Mohsen Hosseini

  2. Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute, Karaj, 31745-139, Iran

    Meisam Shabanian

Authors
  1. Mahsa Nemati
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  2. Sayed Mohsen Hosseini
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  3. Meisam Shabanian
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Correspondence to Sayed Mohsen Hosseini.

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Nemati, M., Hosseini, S.M. & Shabanian, M. Developing thin film heterogeneous ion exchange membrane modified by 2-acrylamido-2-methylpropanesulfonic acid hydrogel-co-super activated carbon nanoparticles coating layer. Korean J. Chem. Eng. 34, 1813–1821 (2017). https://doi.org/10.1007/s11814-017-0049-6

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  • DOI: https://doi.org/10.1007/s11814-017-0049-6

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