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Iron-manganese-magnesium mixed oxides catalysts for selective catalytic reduction of NO x with NH3

  • The 11th Korea-China Clean Energy Workshop
  • Published:
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Abstract

SCR activity at low temperature over iron oxide catalyst was prominently optimized by adding manganese and magnesium. Fe0.7Mn0.15Mg0.15O z (n(Mn)/[n(Fe)+n(Mn)+n(Mg)])=0.15 and n(Mg)/[n(Fe)+n(Mn)+n(Mg)]=0.15) presented better performance in the low temperature SCR and NO x conversion of 90% could be achieved over 125 °C. Meanwhile, part of manganese and magnesium oxides were highly dispersed on the catalyst surface in an amorphous phase to react with iron oxide to form solid solution. Manganese and magnesium dopants could optimize the pore structure and distribution of γ-Fe2O3 to enhance the surface area and pore volume. Moreover, O2 participated in SCR reaction at a faster rate than NH3. In addition, the effect of SO2 was proved to be irreversible, whereas the inhibition of H2O could be rapidly removed after its removal.

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Authors and Affiliations

  1. School of Energy and Power Engineering, Shandong University, Jinan, 250061, China

    Kang Zhang, Liting Xu, Shengli Niu, Chunmei Lu & Qi Zhang

  2. School of Environment, Tsinghua University, Beijing, 100084, China

    Dong Wang

  3. School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100, China

    Jing Li

Authors
  1. Kang Zhang
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  2. Liting Xu
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  3. Shengli Niu
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  4. Chunmei Lu
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  5. Dong Wang
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  6. Qi Zhang
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  7. Jing Li
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Correspondence to Chunmei Lu.

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The paper will be reported in the 11th China-Korea Clean Energy Workshop.

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Zhang, K., Xu, L., Niu, S. et al. Iron-manganese-magnesium mixed oxides catalysts for selective catalytic reduction of NO x with NH3 . Korean J. Chem. Eng. 34, 1858–1866 (2017). https://doi.org/10.1007/s11814-017-0047-8

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  • DOI: https://doi.org/10.1007/s11814-017-0047-8

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