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Cycloaddition of carbon dioxide with propylene oxide using zeolitic imidazolate framework ZIF-23 as a catalyst

  • The 11th Korea-China Clean Energy Workshop
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Abstract

Zeolitic imidazolate framework ZIF-23 was prepared and used as catalyst for the solventless synthesis of cyclic carbonate from CO2 and propylene oxide with or without TBAB co-catalyst. ZIF-23 catalysts were prepared by a solvothermal or microwave method and they were characterized by various physicochemical techniques such as XRD, FT-IR, BET, TGA, and FE-SEM. The effects of reaction parameters such as temperature, reaction time, CO2 pressure, and co-catalyst on the reactivity of catalyst were investigated. ZIF-23 was recyclable up to four times without any considerable loss of its initial activity. Reaction mechanism containing the role of ZIF-23 with TBAB co-catalyst was also proposed.

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Authors and Affiliations

  1. School of Chemical and Biomolecular Engineering, Pusan National University, Busan, 46241, Korea

    Hyeongseok Ryu, Roshith Roshan & Dae-Won Park

  2. Korea Research Institute of Chemical Technology, Ulsan, 44412, Korea

    Moon-Il Kim & Dong-Woo Kim

  3. Nanotechnology and Catalysis Research Center, University of Malaya, Kuala Lumpur, 50603, Malaysia

    Manickam Selvaraj

Authors
  1. Hyeongseok Ryu
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  2. Roshith Roshan
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  4. Dong-Woo Kim
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Correspondence to Dae-Won Park.

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Ryu, H., Roshan, R., Kim, MI. et al. Cycloaddition of carbon dioxide with propylene oxide using zeolitic imidazolate framework ZIF-23 as a catalyst. Korean J. Chem. Eng. 34, 928–934 (2017). https://doi.org/10.1007/s11814-016-0339-4

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  • DOI: https://doi.org/10.1007/s11814-016-0339-4

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