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Liquid-liquid equilibrium and physical properties of aqueous mixtures of poly(vinyl pyrrolidone) with potassium phosphate at different pH: Experiments and modeling

  • Separation Technology, Thermodynamics
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Abstract

Liquid-liquid equilibrium data for poly vinyl pyrrolidone (PVP) K30+K2HPO4+H2O system were measured at 298.15 K and different pH values (7.54, 8.05, and 9.47). A binodal curve was fitted to the Merchuk equation and the tie line compositions were fitted to both the Othmer-Tobias and Bancroft equations. The refractive indices and densities of several homogeneous binary and ternary solutions used for calibration were also measured within a range of 0–30 mass% of PVP and 0–50 mass% of K2HPO4. Then, the viscosities, densities, electrical conductivities, and refractive indices of binary (PVP K30+water; potassium phosphate+water) and ternary (PVP K30+potassium phosphate+water) systems were measured and correlated at different pH values. The density data showed a linear variation of the polymer and salt mass fractions. The viscosity data of PVP K30 solutions were correlated as a function of the mass fractions by using a nonlinear equation. The effects of the tie line lengths on the densities and viscosities of the aqueous two-phase systems were represented. Also, the modified UNIFAC-NRF is used to calculate the phase equilibria of the mention system. The fitted binary interaction parameters of the model were reported.

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Authors and Affiliations

  1. Chemical Engineering Department, Faculty of Engineering, Shomal University, Amol, P. O. Box 731, Iran

    Abbas Rahmani, Abbas Ali Rostami & Mohsen Pirdashti

  2. Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

    Poorya Mobalegholeslam

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  1. Abbas Rahmani
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  2. Abbas Ali Rostami
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  3. Mohsen Pirdashti
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  4. Poorya Mobalegholeslam
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Correspondence to Mohsen Pirdashti.

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Rahmani, A., Rostami, A.A., Pirdashti, M. et al. Liquid-liquid equilibrium and physical properties of aqueous mixtures of poly(vinyl pyrrolidone) with potassium phosphate at different pH: Experiments and modeling. Korean J. Chem. Eng. 34, 1149–1158 (2017). https://doi.org/10.1007/s11814-016-0326-9

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  • DOI: https://doi.org/10.1007/s11814-016-0326-9

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