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Measurement and correlation of the isothermal VLE data for the binary mixtures of cyclopentene (CPEN)+cyclopentyl methyl ether (CPME)

  • Separation Technology, Thermodynamics
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Abstract

The isothermal vapor-liquid equilibrium data for the binary systems of cyclopentene (1)+cyclopentyl methyl ether (2) were measured at 313.15, 323.15, 333.15, 343.15 and 353.15 K using a dynamic-type equilibrium apparatus and online gas chromatography analysis. For all the measured VLE data consistency tests were performed for the verification of data using Barker’s method and the ASPEN PLUS Area Test method. All the resulting average absolute values of residuals [δ ln (γ 1/γ 2)] for Barker’s method and D values for the ASPEN PLUS area test method were comparatively small. So, the VLE data reported in this study are considered to be acceptable. This binary system shows negative deviation from Raoult’s law and does not exhibit azeotropic behavior at whole temperature ranges studied here. The measured data were correlated with the P-R EoS using the Wong-Sandler mixing rule. The overall average relative deviation of pressure (ARD-P (%)) between experimental and calculated values was 0.078% and that of vapor phase compositions (ARD-y (%)) was 0.452%.

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References

  1. W.H. Brown, C.S. Foote, B.L. Iverson and E. Anslyn, Organic Chemistry, Brooks (2009).

    Google Scholar 

  2. K. Watanabe, N. Yamagiwa and Y. Torisawa, Org. Process Res. Dev., 11, 251 (2007).

    Article  CAS  Google Scholar 

  3. M. C. Molina, R. Mariscal, M. Ojeda and M. L. Granados, Bioresour. Technol., 126, 321 (2012).

    Article  Google Scholar 

  4. T. Ooi, D. Sakai, M. Takeuchi, E. Tayama and K. Maruoka, Angew. Chem. Int. Ed., 42, 5868 (2003).

    Article  CAS  Google Scholar 

  5. S. Kobayashi, H. Kuroda, Y. Ohtsuka, T. Kashihara, A. Masuyama and K. Watanabe, Tetrahedron, 69, 2251 (2013).

    Article  CAS  Google Scholar 

  6. K. Watanabe, Molecules, 18, 3183 (2013).

    Article  CAS  Google Scholar 

  7. P. Maximiano, J.P. Mendes, P.V. Mendonca, C.M. Abreu, T. Guliashvili, A. C. Serra and J. F. Coelho, J. Polym. Sci. Pol. Chem., 53, 2722 (2015).

    Article  CAS  Google Scholar 

  8. R. K. Henderson, C. J. Gonzalez, D. J.C. Constable, S.R. Alston, G. G. A. Inglis, G. Fisher, J. Sherwood, S. P. Blinks and A.D. Curzons, Green Chem., 13, 854 (2011).

    Article  CAS  Google Scholar 

  9. V. Antonucci, J. Coleman, J.B. Ferry, N. Johnson, M. Mathe, J.P. Scott and J. Xu, Org. Process Res. Dev., 15, 939 (2011).

    Article  CAS  Google Scholar 

  10. H. Zhang, G. Liu, C. Li and L. Zhang, J. Chem. Eng. Data, 57, 2942 (2012).

    Article  CAS  Google Scholar 

  11. T. Oshima, I. Fujiwara and Y. Baba, Solvent Extr. Res. Dev., 22, 119 (2015).

    Article  CAS  Google Scholar 

  12. W. J. Jeong, H. K. Cho and J. S. Lim, Korean J. Chem. Eng., 33, 2961 (2016)

    Article  CAS  Google Scholar 

  13. D.Y. Peng and D.B. Robinson, Ind. Eng. Chem. Fundam., 15, 59 (1976).

    Article  CAS  Google Scholar 

  14. D. S. H. Wong and S. I. Sandler, AIChE J., 38, 671 (1992).

    Article  CAS  Google Scholar 

  15. D. S. Abrams and J. M. Prausnitz, AIChE J., 21, 116 (1975).

    Article  CAS  Google Scholar 

  16. H. Renon and J. M. Prausnitz, AIChE J., 14, 135 (1968).

    Article  CAS  Google Scholar 

  17. W. J. Jeong and J. S. Lim, Korean J. Chem. Eng., 33, 248 (2016).

    Article  CAS  Google Scholar 

  18. H. Cho, J. E. Kim and J. S. Lim, Fluid Phase Equilib., 379, 52 (2014).

    Article  CAS  Google Scholar 

  19. H. Cho, J. H. Yim and J. S. Lim, J. Supercrit. Fluids, 81, 7 (2013).

    Article  CAS  Google Scholar 

  20. M. H. Lee, J. H. Yim and J. S. Lim, Korean J. Chem. Eng., 29, 1418 (2012).

    Article  CAS  Google Scholar 

  21. S.A. Kim, J. H. Yim, H. S. Byun and J. S. Lim, Korean J. Chem. Eng., 28, 2324 (2011).

    Article  CAS  Google Scholar 

  22. M. Frenkel, R.D. Chirico, V. Diky, C.D. Muzny and A. F. Kazakov, NIST ThermoData Engine, NIST Standard Reference Database 103b-Pure Compounds, Binary Mixtures, and Chemical Reactions, Version 5.0, Standard Reference Data Program, National Institute of Standards and Technology, Gaithersburg, MD (2010).

    Google Scholar 

  23. J.M. Smith, H.C. Van Ness and M.M. Abbott, Introduction to Chemical Engineering Thermodynamics, 7th Ed., McGraw-Hill, New York (2005).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Sogang University, C.P.O. Box 1142, Seoul, 04107, Korea

    Wan Ju Jeong & Jong Sung Lim

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  1. Wan Ju Jeong
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  2. Jong Sung Lim
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Correspondence to Jong Sung Lim.

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Jeong, W.J., Lim, J.S. Measurement and correlation of the isothermal VLE data for the binary mixtures of cyclopentene (CPEN)+cyclopentyl methyl ether (CPME). Korean J. Chem. Eng. 34, 463–469 (2017). https://doi.org/10.1007/s11814-016-0265-5

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  • DOI: https://doi.org/10.1007/s11814-016-0265-5

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